Reactions A n "E, K" H2+O2=>H+HO2 1.94E+14 0 29770 H+HO2=>H2+O2 2.39E+13 0.1 711 H2+O2=>O+H2O 3.00E+13 0 35000 H2+O2=>OH+OH 4.47E+11 0 17338 OH+OH=>H2+O2 1.70E+13 0 24100 H2+M=>H+H+M M=Ar 2.23E+14 0 48350 M=H2 3.46E+14 0 48350 M=O2 3.46E+14 0 48350 M=H2O 8.48E+19 -1.1 52530 H+H+M=>H2+M M=Ar 6.48E+17 -1 0 M=H2 9.72E+16 -0.6 0 M=H2O 1.00E+19 -1 0 M=H 3.20E+15 0 0 O2+M=>O+O+M M=Ar 1.50E+18 -1 59380 M=O2 9.80E+24 -2.5 59380 M=O 3.50E+25 -2.5 59380 " M=O3,H2O" 1.20E+19 -1 59380 O+O+M=>O2+M M=Ar 1.89E+13 0 -900 M=O2 1.50E+16 -0.41 0 M=O 5.34E+16 -0.41 0 M=O3 1.30E+14 0 -900 H2+O2+O2=>HO2+HO2 2.00E+17 0 13000 H2+OH=>H+H2O 2.53E+08 1.48 1700 H2O+H=>H2+OH 1.87E+14 0 10433 OH+OH=>H2O+O 1.50E+09 1.14 50 H2O+O=>OH+OH 5.75E+13 0 9052 O2+H=>OH+O 8.65E+14 -0.24 8200 OH+O=>H+O2 8.91E+12 0 -251 H2+O=>OH+H 5.10E+04 2.67 3160 OH+H=>O+H2 4.88E+03 2.8 1950 O2+O+M=>O3+M M=Ar 4.30E+12 0 -1050 M=O2 3.26E+19 -2.06 0 M=O 2.28E+15 -0.5 -700 M=O3 1.67E+15 -0.51 -700 O3+M=>O2+O+M M=Ar 2.48E+14 0 11430 M=O2 1.54E+14 0 11600 M=O 2.48E+15 0 11430 M=O3 4.40E+14 0 11600 O2+H+M=>HO2+M M=Ar 6.10E+17 -0.8 0 M=O2 2.70E+18 -1 0 M=H2 2.09E+18 -0.8 0 M=H2O 1.56E+18 -0.8 0 HO2+M=O2+H+M M=Ar 2.10E+15 0 23000 M=O2 2.80E+15 0 23000 H2O2+M=>OH+OH+M M=Ar 6.00E+16 0 22900 M=H2 3.20E+17 0 23820 M=H2O2 2.51E+18 0 24154 OH+OH+M=H2O2+M M=Ar 6.33E+23 -2.53 42 M=H2O 1.44E+18 0 0 H+OH+M=>H2O+M M=Ar 8.30E+21 -2 0 M=H2 2.00E+20 -1 0 M=OH 8.34E+15 0 0 M=H2O 1.40E+23 -2 0 H2O+M=H+OH+M M=Ar 4.00E+23 -2.2 59000 M=O2 3.50E+15 0 52920 M+H2O 1.60E+17 0 57491 H+O+M=>OH+M 4.71E+18 -1 0 OH+M=O+H+M " M=Ar,O2" 2.41E+15 0 50000 OH+O+M=>HO2+M M=Ar 8.00E+16 0 0 OH+H2O=>H2+HO2 7.90E+09 0.43 36100 O2+OH=>O+HO2 2.23E+13 0 26500 HO2+O=>OH+O2 1.75E+13 0 -200 HO2+H=>OH+OH 1.69E+14 0 440 OH+OH=>H+HO2 1.20E+13 0 20200 OH+HO2=>H2O+O2 2.85E+13 0 -250 H2O+O2 => OH+HO2 5.60E+13 0.17 36600 OH+O3=>O2+HO2 9.60E+11 0 1000 O2+O2=>O3+O 1.20E+13 0 50500 O3+O=>O2+O2 4.82E+12 0 2060 O2+OH=>H+O3 4.40E+07 1.44 38600 O3+H=>OH+O2 6.87E+13 0 437 HO2+O3=>OH+O2+O2 1.66E+11 -0.284 1000 H2+HO2=>H2O2+H 3.01E+13 0 13100 H+H2O2=>HO2+H2 1.69E+12 0 1890 H2+H2O2=>H2O+OH+H 8.69E+12 0.5 18347 H2O2+O2=>HO2+HO2 5.42E+13 0 20000 HO2+HO2=>H2O2+O2 1.80E+12 0 0 H+H2O2=>H2O+OH 1.02E+13 0 1800 OH+H2O=>H+H2O2 2.40E+14 0 40500 H2O+HO2=>OH+H2O2 2.80E+13 0 16500 OH+H2O2=>H2O+HO2 4.46E+12 0 477 H2O+O2=>O+H2O2 3.40E+10 0.52 44800 O+H2O2=>H2O+O2 8.40E+11 0 2130 H2O2+O=>OH+HO2 1.08E+12 0 2000 Reactions A n "E, K" OH*+H2=>H2O+H 1.00E+14 0 276 OH*+M=>OH+M M=Ar 2.90E+09 0.5 0 " M=O2,H2 " 2.90E+11 0.5 0 M=H2O 2.90E+13 0.5 0 OH*=>OH+hν 1.40E+06 0 0 H2+HO2=>H2O+OH* 4.80E+19 -1.7 19000 O+H+M=>OH*+M M=Ar 3.00E+18 -1 0 " M=O2,H2" 3.00E+18 -1 0 M=OH 1.50E+19 -1 0 O*+H+M=>OH*+M M=Ar 1.50E+18 -1 0 " M=H2,O2" 4.77E+18 -1 0 OH*+ O2 => O3+H 2.30E+12 0.5 0 OH*+O2=>HO2+O 1.20E+12 0.5 0 OH*+H2O=>H2O2+H 7.50E+12 0 276 O2*+M=>O+O+M 2.60E+18 0 48188 O3+M=>O2*+O+M 1.30E+14 0 11400 O2*+O+M=>O3 +M 6.90E+12 0 -1050 HO2+M=>O2* +H+M 6.90E+14 0 23000 O2*+H+M=>HO2+M 1.50E+15 0 -500 O2*+M=>O2+M M=Ar 5.00E+03 0 0 M=H2 2.70E+06 0 0 M=O2 1.00E+06 0 0 " M=O,H" 4.20E+08 0 0 "M=OH,H2O,HO2,H2O2" 3.40E+06 0 0 H +HO2=>O2*+H2 4.80E+07 1.67 3162 O* +O2*=>O+O2 6.03E+12 0 0 O2* +O3=>O2+O2+O 3.13E+13 0 2840 O2* +H2=>H2O+O* 3.50E+13 0 20000 O2* +O2=>O3+O 1.20E+13 0 39604 O2* +H=>OH+O 1.10E+14 0 3188 OH+O => O2* +H 5.80E+12 0 6224 O2* +H2=>OH+OH 1.70E+15 0 17000 O2* +OH=>H+O3 4.40E+07 1.44 27225 O2* +OH=>O+HO2 1.30E+13 0 17000 O3 +OH=>HO2+O2* 4.80E+11 0 1000 O3+HO2=>OH+O2+O2* 1.00E+10 0 1000 HO2 +HO2=>H2O2+O2* 9.00E+12 0 500 O2 +O*=>O2* +O 1.20E+13 0 0 O* +H2=>OH +H 8.70E+13 0 -14 HO2 +H=>H2O+O* 1.70E+12 0.46 678 O*+M=>O+M M=Ar 3.00E+11 0 0 M=O2 1.93E+13 0 67 M=O 3.00E+12 0 0 O* +H2O=>OH+OH 1.30E+14 0 0 O* +O3=>O+O+O2 7.90E+13 0 0