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cantera/test_problems/multiGasTransport/gri30.xml
Harry Moffat 6469863f62 Addition of basic test for multiTransport object. 
This just picks an arbitrary condition, calculates all of the
interfacial properties, and dumps it to an ascii file.
We want to ensure that the answer doesn't change over time.
2007-07-31 21:04:58 +00:00

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<ctml>
<validate reactions="yes" species="yes"/>
<!-- phase gri30_mix -->
<phase dim="3" id="gri30_mix">
<elementArray datasrc="elements.xml"> O H C N Ar </elementArray>
<speciesArray datasrc="#species_data">
H2 H O O2 OH H2O HO2 H2O2 C CH
CH2 CH2(S) CH3 CH4 CO CO2 HCO CH2O CH2OH CH3O
CH3OH C2H C2H2 C2H3 C2H4 C2H5 C2H6 HCCO CH2CO HCCOH
N NH NH2 NH3 NNH NO NO2 N2O HNO CN
HCN H2CN HCNN HCNO HOCN HNCO NCO N2 AR C3H7
C3H8 CH2CHO CH3CHO </speciesArray>
<reactionArray datasrc="#reaction_data"/>
<state>
<temperature units="K">300.0</temperature>
<pressure units="Pa">101325.0</pressure>
</state>
<thermo model="IdealGas"/>
<kinetics model="GRI30"/>
<transport model="Mix"/>
</phase>
<!-- species definitions -->
<speciesData id="species_data">
<!-- species H2 -->
<species name="H2">
<atomArray>H:2 </atomArray>
<note>TPIS78</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
2.344331120E+00, 7.980520750E-03, -1.947815100E-05, 2.015720940E-08,
-7.376117610E-12, -9.179351730E+02, 6.830102380E-01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
3.337279200E+00, -4.940247310E-05, 4.994567780E-07, -1.795663940E-10,
2.002553760E-14, -9.501589220E+02, -3.205023310E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 38.000</LJ_welldepth>
<LJ_diameter units="A"> 2.920</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.790</polarizability>
<rotRelax> 280.000</rotRelax>
</transport>
</species>
<!-- species H -->
<species name="H">
<atomArray>H:1 </atomArray>
<note>L 7/88</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
2.500000000E+00, 7.053328190E-13, -1.995919640E-15, 2.300816320E-18,
-9.277323320E-22, 2.547365990E+04, -4.466828530E-01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.500000010E+00, -2.308429730E-11, 1.615619480E-14, -4.735152350E-18,
4.981973570E-22, 2.547365990E+04, -4.466829140E-01</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">atom</string>
<LJ_welldepth units="K"> 145.000</LJ_welldepth>
<LJ_diameter units="A"> 2.050</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 0.000</rotRelax>
</transport>
</species>
<!-- species O -->
<species name="O">
<atomArray>O:1 </atomArray>
<note>L 1/90</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
3.168267100E+00, -3.279318840E-03, 6.643063960E-06, -6.128066240E-09,
2.112659710E-12, 2.912225920E+04, 2.051933460E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.569420780E+00, -8.597411370E-05, 4.194845890E-08, -1.001777990E-11,
1.228336910E-15, 2.921757910E+04, 4.784338640E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">atom</string>
<LJ_welldepth units="K"> 80.000</LJ_welldepth>
<LJ_diameter units="A"> 2.750</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 0.000</rotRelax>
</transport>
</species>
<!-- species O2 -->
<species name="O2">
<atomArray>O:2 </atomArray>
<note>TPIS89</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
3.782456360E+00, -2.996734160E-03, 9.847302010E-06, -9.681295090E-09,
3.243728370E-12, -1.063943560E+03, 3.657675730E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
3.282537840E+00, 1.483087540E-03, -7.579666690E-07, 2.094705550E-10,
-2.167177940E-14, -1.088457720E+03, 5.453231290E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 107.400</LJ_welldepth>
<LJ_diameter units="A"> 3.460</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 1.600</polarizability>
<rotRelax> 3.800</rotRelax>
</transport>
</species>
<!-- species OH -->
<species name="OH">
<atomArray>H:1 O:1 </atomArray>
<note>RUS 78</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
3.992015430E+00, -2.401317520E-03, 4.617938410E-06, -3.881133330E-09,
1.364114700E-12, 3.615080560E+03, -1.039254580E-01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
3.092887670E+00, 5.484297160E-04, 1.265052280E-07, -8.794615560E-11,
1.174123760E-14, 3.858657000E+03, 4.476696100E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 80.000</LJ_welldepth>
<LJ_diameter units="A"> 2.750</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 0.000</rotRelax>
</transport>
</species>
<!-- species H2O -->
<species name="H2O">
<atomArray>H:2 O:1 </atomArray>
<note>L 8/89</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
4.198640560E+00, -2.036434100E-03, 6.520402110E-06, -5.487970620E-09,
1.771978170E-12, -3.029372670E+04, -8.490322080E-01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
3.033992490E+00, 2.176918040E-03, -1.640725180E-07, -9.704198700E-11,
1.682009920E-14, -3.000429710E+04, 4.966770100E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 572.400</LJ_welldepth>
<LJ_diameter units="A"> 2.600</LJ_diameter>
<dipoleMoment units="Debye"> 1.840</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 4.000</rotRelax>
</transport>
</species>
<!-- species HO2 -->
<species name="HO2">
<atomArray>H:1 O:2 </atomArray>
<note>L 5/89</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
4.301798010E+00, -4.749120510E-03, 2.115828910E-05, -2.427638940E-08,
9.292251240E-12, 2.948080400E+02, 3.716662450E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
4.017210900E+00, 2.239820130E-03, -6.336581500E-07, 1.142463700E-10,
-1.079085350E-14, 1.118567130E+02, 3.785102150E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 107.400</LJ_welldepth>
<LJ_diameter units="A"> 3.460</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species H2O2 -->
<species name="H2O2">
<atomArray>H:2 O:2 </atomArray>
<note>L 7/88</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
4.276112690E+00, -5.428224170E-04, 1.673357010E-05, -2.157708130E-08,
8.624543630E-12, -1.770258210E+04, 3.435050740E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
4.165002850E+00, 4.908316940E-03, -1.901392250E-06, 3.711859860E-10,
-2.879083050E-14, -1.786178770E+04, 2.916156620E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 107.400</LJ_welldepth>
<LJ_diameter units="A"> 3.460</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 3.800</rotRelax>
</transport>
</species>
<!-- species C -->
<species name="C">
<atomArray>C:1 </atomArray>
<note>L11/88</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
2.554239550E+00, -3.215377240E-04, 7.337922450E-07, -7.322348890E-10,
2.665214460E-13, 8.544388320E+04, 4.531308480E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.492668880E+00, 4.798892840E-05, -7.243350200E-08, 3.742910290E-11,
-4.872778930E-15, 8.545129530E+04, 4.801503730E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">atom</string>
<LJ_welldepth units="K"> 71.400</LJ_welldepth>
<LJ_diameter units="A"> 3.300</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 0.000</rotRelax>
</transport>
</species>
<!-- species CH -->
<species name="CH">
<atomArray>H:1 C:1 </atomArray>
<note>TPIS79</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
3.489816650E+00, 3.238355410E-04, -1.688990650E-06, 3.162173270E-09,
-1.406090670E-12, 7.079729340E+04, 2.084011080E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.878464730E+00, 9.709136810E-04, 1.444456550E-07, -1.306878490E-10,
1.760793830E-14, 7.101243640E+04, 5.484979990E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 80.000</LJ_welldepth>
<LJ_diameter units="A"> 2.750</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 0.000</rotRelax>
</transport>
</species>
<!-- species CH2 -->
<species name="CH2">
<atomArray>H:2 C:1 </atomArray>
<note>L S/93</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
3.762678670E+00, 9.688721430E-04, 2.794898410E-06, -3.850911530E-09,
1.687417190E-12, 4.600404010E+04, 1.562531850E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.874101130E+00, 3.656392920E-03, -1.408945970E-06, 2.601795490E-10,
-1.877275670E-14, 4.626360400E+04, 6.171193240E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 144.000</LJ_welldepth>
<LJ_diameter units="A"> 3.800</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 0.000</rotRelax>
</transport>
</species>
<!-- species CH2(S) -->
<species name="CH2(S)">
<atomArray>H:2 C:1 </atomArray>
<note>L S/93</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
4.198604110E+00, -2.366614190E-03, 8.232962200E-06, -6.688159810E-09,
1.943147370E-12, 5.049681630E+04, -7.691189670E-01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.292038420E+00, 4.655886370E-03, -2.011919470E-06, 4.179060000E-10,
-3.397163650E-14, 5.092599970E+04, 8.626501690E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 144.000</LJ_welldepth>
<LJ_diameter units="A"> 3.800</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 0.000</rotRelax>
</transport>
</species>
<!-- species CH3 -->
<species name="CH3">
<atomArray>H:3 C:1 </atomArray>
<note>L11/89</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
3.673590400E+00, 2.010951750E-03, 5.730218560E-06, -6.871174250E-09,
2.543857340E-12, 1.644499880E+04, 1.604564330E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.285717720E+00, 7.239900370E-03, -2.987143480E-06, 5.956846440E-10,
-4.671543940E-14, 1.677558430E+04, 8.480071790E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 144.000</LJ_welldepth>
<LJ_diameter units="A"> 3.800</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 0.000</rotRelax>
</transport>
</species>
<!-- species CH4 -->
<species name="CH4">
<atomArray>H:4 C:1 </atomArray>
<note>L 8/88</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
5.149876130E+00, -1.367097880E-02, 4.918005990E-05, -4.847430260E-08,
1.666939560E-11, -1.024664760E+04, -4.641303760E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
7.485149500E-02, 1.339094670E-02, -5.732858090E-06, 1.222925350E-09,
-1.018152300E-13, -9.468344590E+03, 1.843731800E+01</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 141.400</LJ_welldepth>
<LJ_diameter units="A"> 3.750</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 2.600</polarizability>
<rotRelax> 13.000</rotRelax>
</transport>
</species>
<!-- species CO -->
<species name="CO">
<atomArray>C:1 O:1 </atomArray>
<note>TPIS79</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
3.579533470E+00, -6.103536800E-04, 1.016814330E-06, 9.070058840E-10,
-9.044244990E-13, -1.434408600E+04, 3.508409280E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.715185610E+00, 2.062527430E-03, -9.988257710E-07, 2.300530080E-10,
-2.036477160E-14, -1.415187240E+04, 7.818687720E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 98.100</LJ_welldepth>
<LJ_diameter units="A"> 3.650</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 1.950</polarizability>
<rotRelax> 1.800</rotRelax>
</transport>
</species>
<!-- species CO2 -->
<species name="CO2">
<atomArray>C:1 O:2 </atomArray>
<note>L 7/88</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
2.356773520E+00, 8.984596770E-03, -7.123562690E-06, 2.459190220E-09,
-1.436995480E-13, -4.837196970E+04, 9.901052220E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
3.857460290E+00, 4.414370260E-03, -2.214814040E-06, 5.234901880E-10,
-4.720841640E-14, -4.875916600E+04, 2.271638060E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 244.000</LJ_welldepth>
<LJ_diameter units="A"> 3.760</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 2.650</polarizability>
<rotRelax> 2.100</rotRelax>
</transport>
</species>
<!-- species HCO -->
<species name="HCO">
<atomArray>H:1 C:1 O:1 </atomArray>
<note>L12/89</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
4.221185840E+00, -3.243925320E-03, 1.377994460E-05, -1.331440930E-08,
4.337688650E-12, 3.839564960E+03, 3.394372430E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.772174380E+00, 4.956955260E-03, -2.484456130E-06, 5.891617780E-10,
-5.335087110E-14, 4.011918150E+03, 9.798344920E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 498.000</LJ_welldepth>
<LJ_diameter units="A"> 3.590</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 0.000</rotRelax>
</transport>
</species>
<!-- species CH2O -->
<species name="CH2O">
<atomArray>H:2 C:1 O:1 </atomArray>
<note>L 8/88</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
4.793723150E+00, -9.908333690E-03, 3.732200080E-05, -3.792852610E-08,
1.317726520E-11, -1.430895670E+04, 6.028129000E-01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
1.760690080E+00, 9.200000820E-03, -4.422588130E-06, 1.006412120E-09,
-8.838556400E-14, -1.399583230E+04, 1.365632300E+01</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 498.000</LJ_welldepth>
<LJ_diameter units="A"> 3.590</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 2.000</rotRelax>
</transport>
</species>
<!-- species CH2OH -->
<species name="CH2OH">
<atomArray>H:3 C:1 O:1 </atomArray>
<note>GUNL93</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
3.863889180E+00, 5.596723040E-03, 5.932717910E-06, -1.045320120E-08,
4.369672780E-12, -3.193913670E+03, 5.473022430E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
3.692665690E+00, 8.645767970E-03, -3.751011200E-06, 7.872346360E-10,
-6.485542010E-14, -3.242506270E+03, 5.810432150E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 417.000</LJ_welldepth>
<LJ_diameter units="A"> 3.690</LJ_diameter>
<dipoleMoment units="Debye"> 1.700</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 2.000</rotRelax>
</transport>
</species>
<!-- species CH3O -->
<species name="CH3O">
<atomArray>H:3 C:1 O:1 </atomArray>
<note>121686</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="300.0">
<floatArray name="coeffs" size="7">
2.106204000E+00, 7.216595000E-03, 5.338472000E-06, -7.377636000E-09,
2.075610000E-12, 9.786011000E+02, 1.315217700E+01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
3.770799000E+00, 7.871497000E-03, -2.656384000E-06, 3.944431000E-10,
-2.112616000E-14, 1.278325200E+02, 2.929575000E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 417.000</LJ_welldepth>
<LJ_diameter units="A"> 3.690</LJ_diameter>
<dipoleMoment units="Debye"> 1.700</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 2.000</rotRelax>
</transport>
</species>
<!-- species CH3OH -->
<species name="CH3OH">
<atomArray>H:4 C:1 O:1 </atomArray>
<note>L 8/88</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
5.715395820E+00, -1.523091290E-02, 6.524411550E-05, -7.108068890E-08,
2.613526980E-11, -2.564276560E+04, -1.504098230E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
1.789707910E+00, 1.409382920E-02, -6.365008350E-06, 1.381710850E-09,
-1.170602200E-13, -2.537487470E+04, 1.450236230E+01</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 481.800</LJ_welldepth>
<LJ_diameter units="A"> 3.630</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species C2H -->
<species name="C2H">
<atomArray>H:1 C:2 </atomArray>
<note>L 1/91</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
2.889657330E+00, 1.340996110E-02, -2.847695010E-05, 2.947910450E-08,
-1.093315110E-11, 6.683939320E+04, 6.222964380E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
3.167806520E+00, 4.752219020E-03, -1.837870770E-06, 3.041902520E-10,
-1.772327700E-14, 6.712106500E+04, 6.635894750E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 209.000</LJ_welldepth>
<LJ_diameter units="A"> 4.100</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 2.500</rotRelax>
</transport>
</species>
<!-- species C2H2 -->
<species name="C2H2">
<atomArray>H:2 C:2 </atomArray>
<note>L 1/91</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
8.086810940E-01, 2.336156290E-02, -3.551718150E-05, 2.801524370E-08,
-8.500729740E-12, 2.642898070E+04, 1.393970510E+01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
4.147569640E+00, 5.961666640E-03, -2.372948520E-06, 4.674121710E-10,
-3.612352130E-14, 2.593599920E+04, -1.230281210E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 209.000</LJ_welldepth>
<LJ_diameter units="A"> 4.100</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 2.500</rotRelax>
</transport>
</species>
<!-- species C2H3 -->
<species name="C2H3">
<atomArray>H:3 C:2 </atomArray>
<note>L 2/92</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
3.212466450E+00, 1.514791620E-03, 2.592094120E-05, -3.576578470E-08,
1.471508730E-11, 3.485984680E+04, 8.510540250E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
3.016724000E+00, 1.033022920E-02, -4.680823490E-06, 1.017632880E-09,
-8.626070410E-14, 3.461287390E+04, 7.787323780E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 209.000</LJ_welldepth>
<LJ_diameter units="A"> 4.100</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species C2H4 -->
<species name="C2H4">
<atomArray>H:4 C:2 </atomArray>
<note>L 1/91</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
3.959201480E+00, -7.570522470E-03, 5.709902920E-05, -6.915887530E-08,
2.698843730E-11, 5.089775930E+03, 4.097330960E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.036111160E+00, 1.464541510E-02, -6.710779150E-06, 1.472229230E-09,
-1.257060610E-13, 4.939886140E+03, 1.030536930E+01</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 280.800</LJ_welldepth>
<LJ_diameter units="A"> 3.970</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.500</rotRelax>
</transport>
</species>
<!-- species C2H5 -->
<species name="C2H5">
<atomArray>H:5 C:2 </atomArray>
<note>L12/92</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
4.306465680E+00, -4.186588920E-03, 4.971428070E-05, -5.991266060E-08,
2.305090040E-11, 1.284162650E+04, 4.707209240E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
1.954656420E+00, 1.739727220E-02, -7.982066680E-06, 1.752176890E-09,
-1.496415760E-13, 1.285752000E+04, 1.346243430E+01</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 252.300</LJ_welldepth>
<LJ_diameter units="A"> 4.300</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.500</rotRelax>
</transport>
</species>
<!-- species C2H6 -->
<species name="C2H6">
<atomArray>H:6 C:2 </atomArray>
<note>L 8/88</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
4.291424920E+00, -5.501542700E-03, 5.994382880E-05, -7.084662850E-08,
2.686857710E-11, -1.152220550E+04, 2.666823160E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
1.071881500E+00, 2.168526770E-02, -1.002560670E-05, 2.214120010E-09,
-1.900028900E-13, -1.142639320E+04, 1.511561070E+01</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 252.300</LJ_welldepth>
<LJ_diameter units="A"> 4.300</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.500</rotRelax>
</transport>
</species>
<!-- species HCCO -->
<species name="HCCO">
<atomArray>H:1 C:2 O:1 </atomArray>
<note>SRIC91</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="300.0">
<floatArray name="coeffs" size="7">
2.251721400E+00, 1.765502100E-02, -2.372910100E-05, 1.727575900E-08,
-5.066481100E-12, 2.005944900E+04, 1.249041700E+01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="4000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
5.628205800E+00, 4.085340100E-03, -1.593454700E-06, 2.862605200E-10,
-1.940783200E-14, 1.932721500E+04, -3.930259500E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 150.000</LJ_welldepth>
<LJ_diameter units="A"> 2.500</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species CH2CO -->
<species name="CH2CO">
<atomArray>H:2 C:2 O:1 </atomArray>
<note>L 5/90</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
2.135836300E+00, 1.811887210E-02, -1.739474740E-05, 9.343975680E-09,
-2.014576150E-12, -7.042918040E+03, 1.221564800E+01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="3500.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
4.511297320E+00, 9.003597450E-03, -4.169396350E-06, 9.233458820E-10,
-7.948382010E-14, -7.551053110E+03, 6.322472050E-01</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 436.000</LJ_welldepth>
<LJ_diameter units="A"> 3.970</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 2.000</rotRelax>
</transport>
</species>
<!-- species HCCOH -->
<species name="HCCOH">
<atomArray>H:2 C:2 O:1 </atomArray>
<note>SRI91</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="300.0">
<floatArray name="coeffs" size="7">
1.242373300E+00, 3.107220100E-02, -5.086686400E-05, 4.313713100E-08,
-1.401459400E-11, 8.031614300E+03, 1.387431900E+01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="5000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
5.923829100E+00, 6.792360000E-03, -2.565856400E-06, 4.498784100E-10,
-2.994010100E-14, 7.264626000E+03, -7.601774200E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 436.000</LJ_welldepth>
<LJ_diameter units="A"> 3.970</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 2.000</rotRelax>
</transport>
</species>
<!-- species N -->
<species name="N">
<atomArray>N:1 </atomArray>
<note>L 6/88</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
2.500000000E+00, 0.000000000E+00, 0.000000000E+00, 0.000000000E+00,
0.000000000E+00, 5.610463700E+04, 4.193908700E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="6000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.415942900E+00, 1.748906500E-04, -1.190236900E-07, 3.022624500E-11,
-2.036098200E-15, 5.613377300E+04, 4.649609600E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">atom</string>
<LJ_welldepth units="K"> 71.400</LJ_welldepth>
<LJ_diameter units="A"> 3.300</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 0.000</rotRelax>
</transport>
</species>
<!-- species NH -->
<species name="NH">
<atomArray>H:1 N:1 </atomArray>
<note>And94</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
3.492908500E+00, 3.117919800E-04, -1.489048400E-06, 2.481644200E-09,
-1.035696700E-12, 4.188062900E+04, 1.848327800E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="6000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.783692800E+00, 1.329843000E-03, -4.247804700E-07, 7.834850100E-11,
-5.504447000E-15, 4.212084800E+04, 5.740779900E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 80.000</LJ_welldepth>
<LJ_diameter units="A"> 2.650</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 4.000</rotRelax>
</transport>
</species>
<!-- species NH2 -->
<species name="NH2">
<atomArray>H:2 N:1 </atomArray>
<note>And89</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
4.204002900E+00, -2.106138500E-03, 7.106834800E-06, -5.611519700E-09,
1.644071700E-12, 2.188591000E+04, -1.418424800E-01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="6000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.834742100E+00, 3.207308200E-03, -9.339080400E-07, 1.370295300E-10,
-7.920614400E-15, 2.217195700E+04, 6.520416300E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 80.000</LJ_welldepth>
<LJ_diameter units="A"> 2.650</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 2.260</polarizability>
<rotRelax> 4.000</rotRelax>
</transport>
</species>
<!-- species NH3 -->
<species name="NH3">
<atomArray>H:3 N:1 </atomArray>
<note>J 6/77</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
4.286027400E+00, -4.660523000E-03, 2.171851300E-05, -2.280888700E-08,
8.263804600E-12, -6.741728500E+03, -6.253727700E-01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="6000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.634452100E+00, 5.666256000E-03, -1.727867600E-06, 2.386716100E-10,
-1.257878600E-14, -6.544695800E+03, 6.566292800E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 481.000</LJ_welldepth>
<LJ_diameter units="A"> 2.920</LJ_diameter>
<dipoleMoment units="Debye"> 1.470</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 10.000</rotRelax>
</transport>
</species>
<!-- species NNH -->
<species name="NNH">
<atomArray>H:1 N:2 </atomArray>
<note>T07/93</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
4.344692700E+00, -4.849707200E-03, 2.005945900E-05, -2.172646400E-08,
7.946953900E-12, 2.879197300E+04, 2.977941000E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="6000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
3.766754400E+00, 2.891508200E-03, -1.041662000E-06, 1.684259400E-10,
-1.009189600E-14, 2.865069700E+04, 4.470506700E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 71.400</LJ_welldepth>
<LJ_diameter units="A"> 3.800</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species NO -->
<species name="NO">
<atomArray>O:1 N:1 </atomArray>
<note>RUS 78</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
4.218476300E+00, -4.638976000E-03, 1.104102200E-05, -9.336135400E-09,
2.803577000E-12, 9.844623000E+03, 2.280846400E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="6000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
3.260605600E+00, 1.191104300E-03, -4.291704800E-07, 6.945766900E-11,
-4.033609900E-15, 9.920974600E+03, 6.369302700E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 97.530</LJ_welldepth>
<LJ_diameter units="A"> 3.620</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 1.760</polarizability>
<rotRelax> 4.000</rotRelax>
</transport>
</species>
<!-- species NO2 -->
<species name="NO2">
<atomArray>O:2 N:1 </atomArray>
<note>L 7/88</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
3.944031200E+00, -1.585429000E-03, 1.665781200E-05, -2.047542600E-08,
7.835056400E-12, 2.896617900E+03, 6.311991700E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="6000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
4.884754200E+00, 2.172395600E-03, -8.280690600E-07, 1.574751000E-10,
-1.051089500E-14, 2.316498300E+03, -1.174169500E-01</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 200.000</LJ_welldepth>
<LJ_diameter units="A"> 3.500</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species N2O -->
<species name="N2O">
<atomArray>O:1 N:2 </atomArray>
<note>L 7/88</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
2.257150200E+00, 1.130472800E-02, -1.367131900E-05, 9.681980600E-09,
-2.930718200E-12, 8.741774400E+03, 1.075799200E+01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="6000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
4.823072900E+00, 2.627025100E-03, -9.585087400E-07, 1.600071200E-10,
-9.775230300E-15, 8.073404800E+03, -2.201720700E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 232.400</LJ_welldepth>
<LJ_diameter units="A"> 3.830</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species HNO -->
<species name="HNO">
<atomArray>H:1 O:1 N:1 </atomArray>
<note>And93</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
4.533491600E+00, -5.669617100E-03, 1.847320700E-05, -1.713709400E-08,
5.545457300E-12, 1.154829700E+04, 1.749841700E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="6000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.979250900E+00, 3.494405900E-03, -7.854977800E-07, 5.747959400E-11,
-1.933591600E-16, 1.175058200E+04, 8.606372800E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 116.700</LJ_welldepth>
<LJ_diameter units="A"> 3.490</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species CN -->
<species name="CN">
<atomArray>C:1 N:1 </atomArray>
<note>HBH92</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
3.612935100E+00, -9.555132700E-04, 2.144297700E-06, -3.151632300E-10,
-4.643035600E-13, 5.170834000E+04, 3.980499500E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="6000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
3.745980500E+00, 4.345077500E-05, 2.970598400E-07, -6.865180600E-11,
4.413417300E-15, 5.153618800E+04, 2.786760100E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 75.000</LJ_welldepth>
<LJ_diameter units="A"> 3.860</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species HCN -->
<species name="HCN">
<atomArray>H:1 C:1 N:1 </atomArray>
<note>GRI/98</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
2.258988600E+00, 1.005117000E-02, -1.335176300E-05, 1.009234900E-08,
-3.008902800E-12, 1.471263300E+04, 8.916441900E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="6000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
3.802239200E+00, 3.146422800E-03, -1.063218500E-06, 1.661975700E-10,
-9.799757000E-15, 1.440729200E+04, 1.575460100E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 569.000</LJ_welldepth>
<LJ_diameter units="A"> 3.630</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species H2CN -->
<species name="H2CN">
<atomArray>H:2 C:1 N:1 </atomArray>
<note>41687</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="300.0">
<floatArray name="coeffs" size="7">
2.851661000E+00, 5.695233100E-03, 1.071140000E-06, -1.622612000E-09,
-2.351108100E-13, 2.863782000E+04, 8.992751100E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="4000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
5.209703000E+00, 2.969291100E-03, -2.855589100E-07, -1.635550000E-10,
3.043258900E-14, 2.767710900E+04, -4.444478000E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 569.000</LJ_welldepth>
<LJ_diameter units="A"> 3.630</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species HCNN -->
<species name="HCNN">
<atomArray>H:1 C:1 N:2 </atomArray>
<note>SRI/94</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="300.0">
<floatArray name="coeffs" size="7">
2.524319400E+00, 1.596061900E-02, -1.881635400E-05, 1.212554000E-08,
-3.235737800E-12, 5.426198400E+04, 1.167587000E+01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="5000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
5.894636200E+00, 3.989595900E-03, -1.598238000E-06, 2.924939500E-10,
-2.009468600E-14, 5.345294100E+04, -5.103050200E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 150.000</LJ_welldepth>
<LJ_diameter units="A"> 2.500</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species HCNO -->
<species name="HCNO">
<atomArray>H:1 C:1 O:1 N:1 </atomArray>
<note>BDEA94</note>
<thermo>
<NASA P0="100000.0" Tmax="1382.0" Tmin="300.0">
<floatArray name="coeffs" size="7">
2.647279890E+00, 1.275053420E-02, -1.047942360E-05, 4.414328360E-09,
-7.575214660E-13, 1.929902520E+04, 1.073329720E+01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="5000.0" Tmin="1382.0">
<floatArray name="coeffs" size="7">
6.598604560E+00, 3.027786260E-03, -1.077043460E-06, 1.716665280E-10,
-1.014393910E-14, 1.796613390E+04, -1.033065990E+01</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 232.400</LJ_welldepth>
<LJ_diameter units="A"> 3.830</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species HOCN -->
<species name="HOCN">
<atomArray>H:1 C:1 O:1 N:1 </atomArray>
<note>BDEA94</note>
<thermo>
<NASA P0="100000.0" Tmax="1368.0" Tmin="300.0">
<floatArray name="coeffs" size="7">
3.786049520E+00, 6.886679220E-03, -3.214878640E-06, 5.171957670E-10,
1.193607880E-14, -2.826984000E+03, 5.632921620E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="5000.0" Tmin="1368.0">
<floatArray name="coeffs" size="7">
5.897848850E+00, 3.167893930E-03, -1.118010640E-06, 1.772431440E-10,
-1.043391770E-14, -3.706533310E+03, -6.181678250E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 232.400</LJ_welldepth>
<LJ_diameter units="A"> 3.830</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species HNCO -->
<species name="HNCO">
<atomArray>H:1 C:1 O:1 N:1 </atomArray>
<note>BDEA94</note>
<thermo>
<NASA P0="100000.0" Tmax="1478.0" Tmin="300.0">
<floatArray name="coeffs" size="7">
3.630963170E+00, 7.302823570E-03, -2.280500030E-06, -6.612712980E-10,
3.622357520E-13, -1.558736360E+04, 6.194577270E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="5000.0" Tmin="1478.0">
<floatArray name="coeffs" size="7">
6.223951340E+00, 3.178640040E-03, -1.093787550E-06, 1.707351630E-10,
-9.950219550E-15, -1.665993440E+04, -8.382247410E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 232.400</LJ_welldepth>
<LJ_diameter units="A"> 3.830</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species NCO -->
<species name="NCO">
<atomArray>C:1 O:1 N:1 </atomArray>
<note>EA 93</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
2.826930800E+00, 8.805168800E-03, -8.386613400E-06, 4.801696400E-09,
-1.331359500E-12, 1.468247700E+04, 9.550464600E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="6000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
5.152184500E+00, 2.305176100E-03, -8.803315300E-07, 1.478909800E-10,
-9.097799600E-15, 1.400412300E+04, -2.544266000E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 232.400</LJ_welldepth>
<LJ_diameter units="A"> 3.830</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species N2 -->
<species name="N2">
<atomArray>N:2 </atomArray>
<note>121286</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="300.0">
<floatArray name="coeffs" size="7">
3.298677000E+00, 1.408240400E-03, -3.963222000E-06, 5.641515000E-09,
-2.444854000E-12, -1.020899900E+03, 3.950372000E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="5000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.926640000E+00, 1.487976800E-03, -5.684760000E-07, 1.009703800E-10,
-6.753351000E-15, -9.227977000E+02, 5.980528000E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">linear</string>
<LJ_welldepth units="K"> 97.530</LJ_welldepth>
<LJ_diameter units="A"> 3.620</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 1.760</polarizability>
<rotRelax> 4.000</rotRelax>
</transport>
</species>
<!-- species AR -->
<species name="AR">
<atomArray>Ar:1 </atomArray>
<note>120186</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="300.0">
<floatArray name="coeffs" size="7">
2.500000000E+00, 0.000000000E+00, 0.000000000E+00, 0.000000000E+00,
0.000000000E+00, -7.453750000E+02, 4.366000000E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="5000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
2.500000000E+00, 0.000000000E+00, 0.000000000E+00, 0.000000000E+00,
0.000000000E+00, -7.453750000E+02, 4.366000000E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">atom</string>
<LJ_welldepth units="K"> 136.500</LJ_welldepth>
<LJ_diameter units="A"> 3.330</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 0.000</rotRelax>
</transport>
</species>
<!-- species C3H7 -->
<species name="C3H7">
<atomArray>H:7 C:3 </atomArray>
<note>L 9/84</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="300.0">
<floatArray name="coeffs" size="7">
1.051551800E+00, 2.599198000E-02, 2.380054000E-06, -1.960956900E-08,
9.373247000E-12, 1.063186300E+04, 2.112255900E+01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="5000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
7.702698700E+00, 1.604420300E-02, -5.283322000E-06, 7.629859000E-10,
-3.939228400E-14, 8.298433600E+03, -1.548018000E+01</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 266.800</LJ_welldepth>
<LJ_diameter units="A"> 4.980</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species C3H8 -->
<species name="C3H8">
<atomArray>H:8 C:3 </atomArray>
<note>L 4/85</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="300.0">
<floatArray name="coeffs" size="7">
9.335538100E-01, 2.642457900E-02, 6.105972700E-06, -2.197749900E-08,
9.514925300E-12, -1.395852000E+04, 1.920169100E+01</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="5000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
7.534136800E+00, 1.887223900E-02, -6.271849100E-06, 9.147564900E-10,
-4.783806900E-14, -1.646751600E+04, -1.789234900E+01</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 266.800</LJ_welldepth>
<LJ_diameter units="A"> 4.980</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 1.000</rotRelax>
</transport>
</species>
<!-- species CH2CHO -->
<species name="CH2CHO">
<atomArray>H:3 C:2 O:1 </atomArray>
<note>SAND86</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="300.0">
<floatArray name="coeffs" size="7">
3.409062000E+00, 1.073857400E-02, 1.891492000E-06, -7.158583000E-09,
2.867385000E-12, 1.521476600E+03, 9.558290000E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="5000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
5.975670000E+00, 8.130591000E-03, -2.743624000E-06, 4.070304000E-10,
-2.176017000E-14, 4.903218000E+02, -5.045251000E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 436.000</LJ_welldepth>
<LJ_diameter units="A"> 3.970</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 2.000</rotRelax>
</transport>
</species>
<!-- species CH3CHO -->
<species name="CH3CHO">
<atomArray>H:4 C:2 O:1 </atomArray>
<note>L 8/88</note>
<thermo>
<NASA P0="100000.0" Tmax="1000.0" Tmin="200.0">
<floatArray name="coeffs" size="7">
4.729459500E+00, -3.193285800E-03, 4.753492100E-05, -5.745861100E-08,
2.193111200E-11, -2.157287800E+04, 4.103015900E+00</floatArray>
</NASA>
<NASA P0="100000.0" Tmax="6000.0" Tmin="1000.0">
<floatArray name="coeffs" size="7">
5.404110800E+00, 1.172305900E-02, -4.226313700E-06, 6.837245100E-10,
-4.098486300E-14, -2.259312200E+04, -3.480791700E+00</floatArray>
</NASA>
</thermo>
<transport model="gas_transport">
<string title="geometry">nonlinear</string>
<LJ_welldepth units="K"> 436.000</LJ_welldepth>
<LJ_diameter units="A"> 3.970</LJ_diameter>
<dipoleMoment units="Debye"> 0.000</dipoleMoment>
<polarizability units="A3"> 0.000</polarizability>
<rotRelax> 2.000</rotRelax>
</transport>
</species>
</speciesData>
<reactionData id="reaction_data">
<!-- reaction 0001 -->
<reaction id="0001" reversible="yes" type="threeBody">
<equation>2 O + M [=] O2 + M</equation>
<rateCoeff>
<Arrhenius>
<A> 1.200000E+11</A>
<b>-1</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.83 C2H6:3 CH4:2 CO:1.75 CO2:3.6 H2:2.4 H2O:15.4 </efficiencies>
</rateCoeff>
<reactants>O:2</reactants>
<products>O2:1</products>
</reaction>
<!-- reaction 0002 -->
<reaction id="0002" reversible="yes" type="threeBody">
<equation>O + H + M [=] OH + M</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+11</A>
<b>-1</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
</rateCoeff>
<reactants>H:1 O:1</reactants>
<products>OH:1</products>
</reaction>
<!-- reaction 0003 -->
<reaction id="0003" reversible="yes">
<equation>O + H2 [=] H + OH</equation>
<rateCoeff>
<Arrhenius>
<A> 3.870000E+01</A>
<b>2.7000000000000002</b>
<E units="cal/mol">6260.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H2:1 O:1</reactants>
<products>H:1 OH:1</products>
</reaction>
<!-- reaction 0004 -->
<reaction id="0004" reversible="yes">
<equation>O + HO2 [=] OH + O2</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HO2:1 O:1</reactants>
<products>O2:1 OH:1</products>
</reaction>
<!-- reaction 0005 -->
<reaction id="0005" reversible="yes">
<equation>O + H2O2 [=] OH + HO2</equation>
<rateCoeff>
<Arrhenius>
<A> 9.630000E+03</A>
<b>2</b>
<E units="cal/mol">4000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H2O2:1 O:1</reactants>
<products>HO2:1 OH:1</products>
</reaction>
<!-- reaction 0006 -->
<reaction id="0006" reversible="yes">
<equation>O + CH [=] H + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 5.700000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH:1 O:1</reactants>
<products>H:1 CO:1</products>
</reaction>
<!-- reaction 0007 -->
<reaction id="0007" reversible="yes">
<equation>O + CH2 [=] H + HCO</equation>
<rateCoeff>
<Arrhenius>
<A> 8.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:1 O:1</reactants>
<products>H:1 HCO:1</products>
</reaction>
<!-- reaction 0008 -->
<reaction id="0008" reversible="yes">
<equation>O + CH2(S) [=] H2 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.500000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 O:1</reactants>
<products>H2:1 CO:1</products>
</reaction>
<!-- reaction 0009 -->
<reaction id="0009" reversible="yes">
<equation>O + CH2(S) [=] H + HCO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.500000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 O:1</reactants>
<products>H:1 HCO:1</products>
</reaction>
<!-- reaction 0010 -->
<reaction id="0010" reversible="yes">
<equation>O + CH3 [=] H + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 5.060000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 O:1</reactants>
<products>CH2O:1 H:1</products>
</reaction>
<!-- reaction 0011 -->
<reaction id="0011" reversible="yes">
<equation>O + CH4 [=] OH + CH3</equation>
<rateCoeff>
<Arrhenius>
<A> 1.020000E+06</A>
<b>1.5</b>
<E units="cal/mol">8600.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH4:1 O:1</reactants>
<products>CH3:1 OH:1</products>
</reaction>
<!-- reaction 0012 -->
<reaction id="0012" reversible="yes" type="falloff">
<equation>O + CO (+ M) [=] CO2 (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 1.800000E+07</A>
<b>0</b>
<E units="cal/mol">2385.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 6.020000E+08</A>
<b>0</b>
<E units="cal/mol">3000.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.5 C2H6:3 CH4:2 CO:1.5 CO2:3.5 H2:2 H2O:6 O2:6 </efficiencies>
<falloff type="Lindemann"/>
</rateCoeff>
<reactants>CO:1 O:1</reactants>
<products>CO2:1</products>
</reaction>
<!-- reaction 0013 -->
<reaction id="0013" reversible="yes">
<equation>O + HCO [=] OH + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 3.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HCO:1 O:1</reactants>
<products>CO:1 OH:1</products>
</reaction>
<!-- reaction 0014 -->
<reaction id="0014" reversible="yes">
<equation>O + HCO [=] H + CO2</equation>
<rateCoeff>
<Arrhenius>
<A> 3.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HCO:1 O:1</reactants>
<products>H:1 CO2:1</products>
</reaction>
<!-- reaction 0015 -->
<reaction id="0015" reversible="yes">
<equation>O + CH2O [=] OH + HCO</equation>
<rateCoeff>
<Arrhenius>
<A> 3.900000E+10</A>
<b>0</b>
<E units="cal/mol">3540.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2O:1 O:1</reactants>
<products>HCO:1 OH:1</products>
</reaction>
<!-- reaction 0016 -->
<reaction id="0016" reversible="yes">
<equation>O + CH2OH [=] OH + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2OH:1 O:1</reactants>
<products>CH2O:1 OH:1</products>
</reaction>
<!-- reaction 0017 -->
<reaction id="0017" reversible="yes">
<equation>O + CH3O [=] OH + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3O:1 O:1</reactants>
<products>CH2O:1 OH:1</products>
</reaction>
<!-- reaction 0018 -->
<reaction id="0018" reversible="yes">
<equation>O + CH3OH [=] OH + CH2OH</equation>
<rateCoeff>
<Arrhenius>
<A> 3.880000E+02</A>
<b>2.5</b>
<E units="cal/mol">3100.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3OH:1 O:1</reactants>
<products>CH2OH:1 OH:1</products>
</reaction>
<!-- reaction 0019 -->
<reaction id="0019" reversible="yes">
<equation>O + CH3OH [=] OH + CH3O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.300000E+02</A>
<b>2.5</b>
<E units="cal/mol">5000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3OH:1 O:1</reactants>
<products>CH3O:1 OH:1</products>
</reaction>
<!-- reaction 0020 -->
<reaction id="0020" reversible="yes">
<equation>O + C2H [=] CH + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H:1 O:1</reactants>
<products>CH:1 CO:1</products>
</reaction>
<!-- reaction 0021 -->
<reaction id="0021" reversible="yes">
<equation>O + C2H2 [=] H + HCCO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.350000E+04</A>
<b>2</b>
<E units="cal/mol">1900.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H2:1 O:1</reactants>
<products>H:1 HCCO:1</products>
</reaction>
<!-- reaction 0022 -->
<reaction id="0022" reversible="yes">
<equation>O + C2H2 [=] OH + C2H</equation>
<rateCoeff>
<Arrhenius>
<A> 4.600000E+16</A>
<b>-1.4099999999999999</b>
<E units="cal/mol">28950.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H2:1 O:1</reactants>
<products>C2H:1 OH:1</products>
</reaction>
<!-- reaction 0023 -->
<reaction id="0023" reversible="yes">
<equation>O + C2H2 [=] CO + CH2</equation>
<rateCoeff>
<Arrhenius>
<A> 6.940000E+03</A>
<b>2</b>
<E units="cal/mol">1900.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H2:1 O:1</reactants>
<products>CH2:1 CO:1</products>
</reaction>
<!-- reaction 0024 -->
<reaction id="0024" reversible="yes">
<equation>O + C2H3 [=] H + CH2CO</equation>
<rateCoeff>
<Arrhenius>
<A> 3.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H3:1 O:1</reactants>
<products>H:1 CH2CO:1</products>
</reaction>
<!-- reaction 0025 -->
<reaction id="0025" reversible="yes">
<equation>O + C2H4 [=] CH3 + HCO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.250000E+04</A>
<b>1.8300000000000001</b>
<E units="cal/mol">220.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H4:1 O:1</reactants>
<products>CH3:1 HCO:1</products>
</reaction>
<!-- reaction 0026 -->
<reaction id="0026" reversible="yes">
<equation>O + C2H5 [=] CH3 + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 2.240000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H5:1 O:1</reactants>
<products>CH2O:1 CH3:1</products>
</reaction>
<!-- reaction 0027 -->
<reaction id="0027" reversible="yes">
<equation>O + C2H6 [=] OH + C2H5</equation>
<rateCoeff>
<Arrhenius>
<A> 8.980000E+04</A>
<b>1.9199999999999999</b>
<E units="cal/mol">5690.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H6:1 O:1</reactants>
<products>C2H5:1 OH:1</products>
</reaction>
<!-- reaction 0028 -->
<reaction id="0028" reversible="yes">
<equation>O + HCCO [=] H + 2 CO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+11</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HCCO:1 O:1</reactants>
<products>H:1 CO:2</products>
</reaction>
<!-- reaction 0029 -->
<reaction id="0029" reversible="yes">
<equation>O + CH2CO [=] OH + HCCO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+10</A>
<b>0</b>
<E units="cal/mol">8000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2CO:1 O:1</reactants>
<products>HCCO:1 OH:1</products>
</reaction>
<!-- reaction 0030 -->
<reaction id="0030" reversible="yes">
<equation>O + CH2CO [=] CH2 + CO2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.750000E+09</A>
<b>0</b>
<E units="cal/mol">1350.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2CO:1 O:1</reactants>
<products>CH2:1 CO2:1</products>
</reaction>
<!-- reaction 0031 -->
<reaction id="0031" reversible="yes">
<equation>O2 + CO [=] O + CO2</equation>
<rateCoeff>
<Arrhenius>
<A> 2.500000E+09</A>
<b>0</b>
<E units="cal/mol">47800.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CO:1 O2:1</reactants>
<products>CO2:1 O:1</products>
</reaction>
<!-- reaction 0032 -->
<reaction id="0032" reversible="yes">
<equation>O2 + CH2O [=] HO2 + HCO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+11</A>
<b>0</b>
<E units="cal/mol">40000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2O:1 O2:1</reactants>
<products>HO2:1 HCO:1</products>
</reaction>
<!-- reaction 0033 -->
<reaction id="0033" reversible="yes" type="threeBody">
<equation>H + O2 + M [=] HO2 + M</equation>
<rateCoeff>
<Arrhenius>
<A> 2.800000E+12</A>
<b>-0.85999999999999999</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0 C2H6:1.5 CO:0.75 CO2:1.5 H2O:0 N2:0 O2:0 </efficiencies>
</rateCoeff>
<reactants>H:1 O2:1</reactants>
<products>HO2:1</products>
</reaction>
<!-- reaction 0034 -->
<reaction id="0034" reversible="yes">
<equation>H + 2 O2 [=] HO2 + O2</equation>
<rateCoeff>
<Arrhenius>
<A> 2.080000E+13</A>
<b>-1.24</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 O2:2</reactants>
<products>HO2:1 O2:1</products>
</reaction>
<!-- reaction 0035 -->
<reaction id="0035" reversible="yes">
<equation>H + O2 + H2O [=] HO2 + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.126000E+13</A>
<b>-0.76000000000000001</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 H2O:1 O2:1</reactants>
<products>H2O:1 HO2:1</products>
</reaction>
<!-- reaction 0036 -->
<reaction id="0036" reversible="yes">
<equation>H + O2 + N2 [=] HO2 + N2</equation>
<rateCoeff>
<Arrhenius>
<A> 2.600000E+13</A>
<b>-1.24</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 N2:1 O2:1</reactants>
<products>N2:1 HO2:1</products>
</reaction>
<!-- reaction 0037 -->
<reaction id="0037" reversible="yes">
<equation>H + O2 + AR [=] HO2 + AR</equation>
<rateCoeff>
<Arrhenius>
<A> 7.000000E+11</A>
<b>-0.80000000000000004</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 AR:1 O2:1</reactants>
<products>AR:1 HO2:1</products>
</reaction>
<!-- reaction 0038 -->
<reaction id="0038" reversible="yes">
<equation>H + O2 [=] O + OH</equation>
<rateCoeff>
<Arrhenius>
<A> 2.650000E+13</A>
<b>-0.67069999999999996</b>
<E units="cal/mol">17041.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 O2:1</reactants>
<products>O:1 OH:1</products>
</reaction>
<!-- reaction 0039 -->
<reaction id="0039" reversible="yes" type="threeBody">
<equation>2 H + M [=] H2 + M</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+12</A>
<b>-1</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.63 C2H6:3 CH4:2 CO2:0 H2:0 H2O:0 </efficiencies>
</rateCoeff>
<reactants>H:2</reactants>
<products>H2:1</products>
</reaction>
<!-- reaction 0040 -->
<reaction id="0040" reversible="yes">
<equation>2 H + H2 [=] 2 H2</equation>
<rateCoeff>
<Arrhenius>
<A> 9.000000E+10</A>
<b>-0.59999999999999998</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H2:1 H:2</reactants>
<products>H2:2</products>
</reaction>
<!-- reaction 0041 -->
<reaction id="0041" reversible="yes">
<equation>2 H + H2O [=] H2 + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 6.000000E+13</A>
<b>-1.25</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:2 H2O:1</reactants>
<products>H2:1 H2O:1</products>
</reaction>
<!-- reaction 0042 -->
<reaction id="0042" reversible="yes">
<equation>2 H + CO2 [=] H2 + CO2</equation>
<rateCoeff>
<Arrhenius>
<A> 5.500000E+14</A>
<b>-2</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:2 CO2:1</reactants>
<products>H2:1 CO2:1</products>
</reaction>
<!-- reaction 0043 -->
<reaction id="0043" reversible="yes" type="threeBody">
<equation>H + OH + M [=] H2O + M</equation>
<rateCoeff>
<Arrhenius>
<A> 2.200000E+16</A>
<b>-2</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.38 C2H6:3 CH4:2 H2:0.73 H2O:3.65 </efficiencies>
</rateCoeff>
<reactants>H:1 OH:1</reactants>
<products>H2O:1</products>
</reaction>
<!-- reaction 0044 -->
<reaction id="0044" reversible="yes">
<equation>H + HO2 [=] O + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 3.970000E+09</A>
<b>0</b>
<E units="cal/mol">671.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 HO2:1</reactants>
<products>H2O:1 O:1</products>
</reaction>
<!-- reaction 0045 -->
<reaction id="0045" reversible="yes">
<equation>H + HO2 [=] O2 + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 4.480000E+10</A>
<b>0</b>
<E units="cal/mol">1068.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 HO2:1</reactants>
<products>H2:1 O2:1</products>
</reaction>
<!-- reaction 0046 -->
<reaction id="0046" reversible="yes">
<equation>H + HO2 [=] 2 OH</equation>
<rateCoeff>
<Arrhenius>
<A> 8.400000E+10</A>
<b>0</b>
<E units="cal/mol">635.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 HO2:1</reactants>
<products>OH:2</products>
</reaction>
<!-- reaction 0047 -->
<reaction id="0047" reversible="yes">
<equation>H + H2O2 [=] HO2 + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.210000E+04</A>
<b>2</b>
<E units="cal/mol">5200.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 H2O2:1</reactants>
<products>H2:1 HO2:1</products>
</reaction>
<!-- reaction 0048 -->
<reaction id="0048" reversible="yes">
<equation>H + H2O2 [=] OH + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+10</A>
<b>0</b>
<E units="cal/mol">3600.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 H2O2:1</reactants>
<products>H2O:1 OH:1</products>
</reaction>
<!-- reaction 0049 -->
<reaction id="0049" reversible="yes">
<equation>H + CH [=] C + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.650000E+11</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 CH:1</reactants>
<products>H2:1 C:1</products>
</reaction>
<!-- reaction 0050 -->
<reaction id="0050" reversible="yes" type="falloff">
<equation>H + CH2 (+ M) [=] CH3 (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 6.000000E+11</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 1.040000E+20</A>
<b>-2.7599999999999998</b>
<E units="cal/mol">1600.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.562 91 5836 8552 </falloff>
</rateCoeff>
<reactants>H:1 CH2:1</reactants>
<products>CH3:1</products>
</reaction>
<!-- reaction 0051 -->
<reaction id="0051" reversible="yes">
<equation>H + CH2(S) [=] CH + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 3.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 CH2(S):1</reactants>
<products>H2:1 CH:1</products>
</reaction>
<!-- reaction 0052 -->
<reaction id="0052" reversible="yes" type="falloff">
<equation>H + CH3 (+ M) [=] CH4 (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 1.390000E+13</A>
<b>-0.53400000000000003</b>
<E units="cal/mol">536.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 2.620000E+27</A>
<b>-4.7599999999999998</b>
<E units="cal/mol">2440.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:3 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.783 74 2941 6964 </falloff>
</rateCoeff>
<reactants>H:1 CH3:1</reactants>
<products>CH4:1</products>
</reaction>
<!-- reaction 0053 -->
<reaction id="0053" reversible="yes">
<equation>H + CH4 [=] CH3 + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 6.600000E+05</A>
<b>1.6200000000000001</b>
<E units="cal/mol">10840.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 CH4:1</reactants>
<products>H2:1 CH3:1</products>
</reaction>
<!-- reaction 0054 -->
<reaction id="0054" reversible="yes" type="falloff">
<equation>H + HCO (+ M) [=] CH2O (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 1.090000E+09</A>
<b>0.47999999999999998</b>
<E units="cal/mol">-260.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 2.470000E+18</A>
<b>-2.5699999999999998</b>
<E units="cal/mol">425.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.7824 271 2755 6570 </falloff>
</rateCoeff>
<reactants>H:1 HCO:1</reactants>
<products>CH2O:1</products>
</reaction>
<!-- reaction 0055 -->
<reaction id="0055" reversible="yes">
<equation>H + HCO [=] H2 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 7.340000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 HCO:1</reactants>
<products>H2:1 CO:1</products>
</reaction>
<!-- reaction 0056 -->
<reaction id="0056" reversible="yes" type="falloff">
<equation>H + CH2O (+ M) [=] CH2OH (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 5.400000E+08</A>
<b>0.45400000000000001</b>
<E units="cal/mol">3600.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 1.270000E+26</A>
<b>-4.8200000000000003</b>
<E units="cal/mol">6530.000000</E>
</Arrhenius>
<efficiencies default="1.0"> C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.7187 103 1291 4160 </falloff>
</rateCoeff>
<reactants>CH2O:1 H:1</reactants>
<products>CH2OH:1</products>
</reaction>
<!-- reaction 0057 -->
<reaction id="0057" reversible="yes" type="falloff">
<equation>H + CH2O (+ M) [=] CH3O (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 5.400000E+08</A>
<b>0.45400000000000001</b>
<E units="cal/mol">2600.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 2.200000E+24</A>
<b>-4.7999999999999998</b>
<E units="cal/mol">5560.000000</E>
</Arrhenius>
<efficiencies default="1.0"> C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.758 94 1555 4200 </falloff>
</rateCoeff>
<reactants>CH2O:1 H:1</reactants>
<products>CH3O:1</products>
</reaction>
<!-- reaction 0058 -->
<reaction id="0058" reversible="yes">
<equation>H + CH2O [=] HCO + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 5.740000E+04</A>
<b>1.8999999999999999</b>
<E units="cal/mol">2742.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2O:1 H:1</reactants>
<products>H2:1 HCO:1</products>
</reaction>
<!-- reaction 0059 -->
<reaction id="0059" reversible="yes" type="falloff">
<equation>H + CH2OH (+ M) [=] CH3OH (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 1.055000E+09</A>
<b>0.5</b>
<E units="cal/mol">86.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 4.360000E+25</A>
<b>-4.6500000000000004</b>
<E units="cal/mol">5080.000000</E>
</Arrhenius>
<efficiencies default="1.0"> C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.6 100 90000 10000 </falloff>
</rateCoeff>
<reactants>H:1 CH2OH:1</reactants>
<products>CH3OH:1</products>
</reaction>
<!-- reaction 0060 -->
<reaction id="0060" reversible="yes">
<equation>H + CH2OH [=] H2 + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 CH2OH:1</reactants>
<products>H2:1 CH2O:1</products>
</reaction>
<!-- reaction 0061 -->
<reaction id="0061" reversible="yes">
<equation>H + CH2OH [=] OH + CH3</equation>
<rateCoeff>
<Arrhenius>
<A> 1.650000E+08</A>
<b>0.65000000000000002</b>
<E units="cal/mol">-284.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 CH2OH:1</reactants>
<products>CH3:1 OH:1</products>
</reaction>
<!-- reaction 0062 -->
<reaction id="0062" reversible="yes">
<equation>H + CH2OH [=] CH2(S) + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 3.280000E+10</A>
<b>-0.089999999999999997</b>
<E units="cal/mol">610.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 CH2OH:1</reactants>
<products>CH2(S):1 H2O:1</products>
</reaction>
<!-- reaction 0063 -->
<reaction id="0063" reversible="yes" type="falloff">
<equation>H + CH3O (+ M) [=] CH3OH (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 2.430000E+09</A>
<b>0.51500000000000001</b>
<E units="cal/mol">50.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 4.660000E+35</A>
<b>-7.4400000000000004</b>
<E units="cal/mol">14080.000000</E>
</Arrhenius>
<efficiencies default="1.0"> C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.7 100 90000 10000 </falloff>
</rateCoeff>
<reactants>H:1 CH3O:1</reactants>
<products>CH3OH:1</products>
</reaction>
<!-- reaction 0064 -->
<reaction id="0064" reversible="yes">
<equation>H + CH3O [=] H + CH2OH</equation>
<rateCoeff>
<Arrhenius>
<A> 4.150000E+04</A>
<b>1.6299999999999999</b>
<E units="cal/mol">1924.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 CH3O:1</reactants>
<products>H:1 CH2OH:1</products>
</reaction>
<!-- reaction 0065 -->
<reaction id="0065" reversible="yes">
<equation>H + CH3O [=] H2 + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 CH3O:1</reactants>
<products>H2:1 CH2O:1</products>
</reaction>
<!-- reaction 0066 -->
<reaction id="0066" reversible="yes">
<equation>H + CH3O [=] OH + CH3</equation>
<rateCoeff>
<Arrhenius>
<A> 1.500000E+09</A>
<b>0.5</b>
<E units="cal/mol">-110.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 CH3O:1</reactants>
<products>CH3:1 OH:1</products>
</reaction>
<!-- reaction 0067 -->
<reaction id="0067" reversible="yes">
<equation>H + CH3O [=] CH2(S) + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 2.620000E+11</A>
<b>-0.23000000000000001</b>
<E units="cal/mol">1070.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 CH3O:1</reactants>
<products>CH2(S):1 H2O:1</products>
</reaction>
<!-- reaction 0068 -->
<reaction id="0068" reversible="yes">
<equation>H + CH3OH [=] CH2OH + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.700000E+04</A>
<b>2.1000000000000001</b>
<E units="cal/mol">4870.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3OH:1 H:1</reactants>
<products>H2:1 CH2OH:1</products>
</reaction>
<!-- reaction 0069 -->
<reaction id="0069" reversible="yes">
<equation>H + CH3OH [=] CH3O + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 4.200000E+03</A>
<b>2.1000000000000001</b>
<E units="cal/mol">4870.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3OH:1 H:1</reactants>
<products>H2:1 CH3O:1</products>
</reaction>
<!-- reaction 0070 -->
<reaction id="0070" reversible="yes" type="falloff">
<equation>H + C2H (+ M) [=] C2H2 (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+14</A>
<b>-1</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 3.750000E+27</A>
<b>-4.7999999999999998</b>
<E units="cal/mol">1900.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.6464 132 1315 5566 </falloff>
</rateCoeff>
<reactants>H:1 C2H:1</reactants>
<products>C2H2:1</products>
</reaction>
<!-- reaction 0071 -->
<reaction id="0071" reversible="yes" type="falloff">
<equation>H + C2H2 (+ M) [=] C2H3 (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 5.600000E+09</A>
<b>0</b>
<E units="cal/mol">2400.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 3.800000E+34</A>
<b>-7.2699999999999996</b>
<E units="cal/mol">7220.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.7507 98.5 1302 4167 </falloff>
</rateCoeff>
<reactants>H:1 C2H2:1</reactants>
<products>C2H3:1</products>
</reaction>
<!-- reaction 0072 -->
<reaction id="0072" reversible="yes" type="falloff">
<equation>H + C2H3 (+ M) [=] C2H4 (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 6.080000E+09</A>
<b>0.27000000000000002</b>
<E units="cal/mol">280.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 1.400000E+24</A>
<b>-3.8599999999999999</b>
<E units="cal/mol">3320.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.782 207.5 2663 6095 </falloff>
</rateCoeff>
<reactants>H:1 C2H3:1</reactants>
<products>C2H4:1</products>
</reaction>
<!-- reaction 0073 -->
<reaction id="0073" reversible="yes">
<equation>H + C2H3 [=] H2 + C2H2</equation>
<rateCoeff>
<Arrhenius>
<A> 3.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 C2H3:1</reactants>
<products>H2:1 C2H2:1</products>
</reaction>
<!-- reaction 0074 -->
<reaction id="0074" reversible="yes" type="falloff">
<equation>H + C2H4 (+ M) [=] C2H5 (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 5.400000E+08</A>
<b>0.45400000000000001</b>
<E units="cal/mol">1820.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 6.000000E+35</A>
<b>-7.6200000000000001</b>
<E units="cal/mol">6970.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.9753 210 984 4374 </falloff>
</rateCoeff>
<reactants>H:1 C2H4:1</reactants>
<products>C2H5:1</products>
</reaction>
<!-- reaction 0075 -->
<reaction id="0075" reversible="yes">
<equation>H + C2H4 [=] C2H3 + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.325000E+03</A>
<b>2.5299999999999998</b>
<E units="cal/mol">12240.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 C2H4:1</reactants>
<products>H2:1 C2H3:1</products>
</reaction>
<!-- reaction 0076 -->
<reaction id="0076" reversible="yes" type="falloff">
<equation>H + C2H5 (+ M) [=] C2H6 (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 5.210000E+14</A>
<b>-0.98999999999999999</b>
<E units="cal/mol">1580.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 1.990000E+35</A>
<b>-7.0800000000000001</b>
<E units="cal/mol">6685.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.8422 125 2219 6882 </falloff>
</rateCoeff>
<reactants>H:1 C2H5:1</reactants>
<products>C2H6:1</products>
</reaction>
<!-- reaction 0077 -->
<reaction id="0077" reversible="yes">
<equation>H + C2H5 [=] H2 + C2H4</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+09</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 C2H5:1</reactants>
<products>H2:1 C2H4:1</products>
</reaction>
<!-- reaction 0078 -->
<reaction id="0078" reversible="yes">
<equation>H + C2H6 [=] C2H5 + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.150000E+05</A>
<b>1.8999999999999999</b>
<E units="cal/mol">7530.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 C2H6:1</reactants>
<products>H2:1 C2H5:1</products>
</reaction>
<!-- reaction 0079 -->
<reaction id="0079" reversible="yes">
<equation>H + HCCO [=] CH2(S) + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+11</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 HCCO:1</reactants>
<products>CH2(S):1 CO:1</products>
</reaction>
<!-- reaction 0080 -->
<reaction id="0080" reversible="yes">
<equation>H + CH2CO [=] HCCO + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+10</A>
<b>0</b>
<E units="cal/mol">8000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 CH2CO:1</reactants>
<products>H2:1 HCCO:1</products>
</reaction>
<!-- reaction 0081 -->
<reaction id="0081" reversible="yes">
<equation>H + CH2CO [=] CH3 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.130000E+10</A>
<b>0</b>
<E units="cal/mol">3428.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 CH2CO:1</reactants>
<products>CH3:1 CO:1</products>
</reaction>
<!-- reaction 0082 -->
<reaction id="0082" reversible="yes">
<equation>H + HCCOH [=] H + CH2CO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 HCCOH:1</reactants>
<products>H:1 CH2CO:1</products>
</reaction>
<!-- reaction 0083 -->
<reaction id="0083" reversible="yes" type="falloff">
<equation>H2 + CO (+ M) [=] CH2O (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 4.300000E+04</A>
<b>1.5</b>
<E units="cal/mol">79600.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 5.070000E+21</A>
<b>-3.4199999999999999</b>
<E units="cal/mol">84350.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.932 197 1540 10300 </falloff>
</rateCoeff>
<reactants>H2:1 CO:1</reactants>
<products>CH2O:1</products>
</reaction>
<!-- reaction 0084 -->
<reaction id="0084" reversible="yes">
<equation>OH + H2 [=] H + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 2.160000E+05</A>
<b>1.51</b>
<E units="cal/mol">3430.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H2:1 OH:1</reactants>
<products>H:1 H2O:1</products>
</reaction>
<!-- reaction 0085 -->
<reaction id="0085" reversible="yes" type="falloff">
<equation>2 OH (+ M) [=] H2O2 (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 7.400000E+10</A>
<b>-0.37</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 2.300000E+12</A>
<b>-0.90000000000000002</b>
<E units="cal/mol">-1700.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.7346 94 1756 5182 </falloff>
</rateCoeff>
<reactants>OH:2</reactants>
<products>H2O2:1</products>
</reaction>
<!-- reaction 0086 -->
<reaction id="0086" reversible="yes">
<equation>2 OH [=] O + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 3.570000E+01</A>
<b>2.3999999999999999</b>
<E units="cal/mol">-2110.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>OH:2</reactants>
<products>H2O:1 O:1</products>
</reaction>
<!-- reaction 0087 -->
<reaction duplicate="yes" id="0087" reversible="yes">
<equation>OH + HO2 [=] O2 + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.450000E+10</A>
<b>0</b>
<E units="cal/mol">-500.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HO2:1 OH:1</reactants>
<products>H2O:1 O2:1</products>
</reaction>
<!-- reaction 0088 -->
<reaction duplicate="yes" id="0088" reversible="yes">
<equation>OH + H2O2 [=] HO2 + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+09</A>
<b>0</b>
<E units="cal/mol">427.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H2O2:1 OH:1</reactants>
<products>H2O:1 HO2:1</products>
</reaction>
<!-- reaction 0089 -->
<reaction duplicate="yes" id="0089" reversible="yes">
<equation>OH + H2O2 [=] HO2 + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.700000E+15</A>
<b>0</b>
<E units="cal/mol">29410.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H2O2:1 OH:1</reactants>
<products>H2O:1 HO2:1</products>
</reaction>
<!-- reaction 0090 -->
<reaction id="0090" reversible="yes">
<equation>OH + C [=] H + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C:1 OH:1</reactants>
<products>H:1 CO:1</products>
</reaction>
<!-- reaction 0091 -->
<reaction id="0091" reversible="yes">
<equation>OH + CH [=] H + HCO</equation>
<rateCoeff>
<Arrhenius>
<A> 3.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH:1 OH:1</reactants>
<products>H:1 HCO:1</products>
</reaction>
<!-- reaction 0092 -->
<reaction id="0092" reversible="yes">
<equation>OH + CH2 [=] H + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:1 OH:1</reactants>
<products>CH2O:1 H:1</products>
</reaction>
<!-- reaction 0093 -->
<reaction id="0093" reversible="yes">
<equation>OH + CH2 [=] CH + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.130000E+04</A>
<b>2</b>
<E units="cal/mol">3000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:1 OH:1</reactants>
<products>H2O:1 CH:1</products>
</reaction>
<!-- reaction 0094 -->
<reaction id="0094" reversible="yes">
<equation>OH + CH2(S) [=] H + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 3.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 OH:1</reactants>
<products>CH2O:1 H:1</products>
</reaction>
<!-- reaction 0095 -->
<reaction id="0095" reversible="yes" type="falloff">
<equation>OH + CH3 (+ M) [=] CH3OH (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 2.790000E+15</A>
<b>-1.4299999999999999</b>
<E units="cal/mol">1330.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 4.000000E+30</A>
<b>-5.9199999999999999</b>
<E units="cal/mol">3140.000000</E>
</Arrhenius>
<efficiencies default="1.0"> C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.412 195 5900 6394 </falloff>
</rateCoeff>
<reactants>CH3:1 OH:1</reactants>
<products>CH3OH:1</products>
</reaction>
<!-- reaction 0096 -->
<reaction id="0096" reversible="yes">
<equation>OH + CH3 [=] CH2 + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 5.600000E+04</A>
<b>1.6000000000000001</b>
<E units="cal/mol">5420.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 OH:1</reactants>
<products>CH2:1 H2O:1</products>
</reaction>
<!-- reaction 0097 -->
<reaction id="0097" reversible="yes">
<equation>OH + CH3 [=] CH2(S) + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 6.440000E+14</A>
<b>-1.3400000000000001</b>
<E units="cal/mol">1417.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 OH:1</reactants>
<products>CH2(S):1 H2O:1</products>
</reaction>
<!-- reaction 0098 -->
<reaction id="0098" reversible="yes">
<equation>OH + CH4 [=] CH3 + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+05</A>
<b>1.6000000000000001</b>
<E units="cal/mol">3120.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH4:1 OH:1</reactants>
<products>H2O:1 CH3:1</products>
</reaction>
<!-- reaction 0099 -->
<reaction id="0099" reversible="yes">
<equation>OH + CO [=] H + CO2</equation>
<rateCoeff>
<Arrhenius>
<A> 4.760000E+04</A>
<b>1.228</b>
<E units="cal/mol">70.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CO:1 OH:1</reactants>
<products>H:1 CO2:1</products>
</reaction>
<!-- reaction 0100 -->
<reaction id="0100" reversible="yes">
<equation>OH + HCO [=] H2O + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HCO:1 OH:1</reactants>
<products>H2O:1 CO:1</products>
</reaction>
<!-- reaction 0101 -->
<reaction id="0101" reversible="yes">
<equation>OH + CH2O [=] HCO + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 3.430000E+06</A>
<b>1.1799999999999999</b>
<E units="cal/mol">-447.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2O:1 OH:1</reactants>
<products>H2O:1 HCO:1</products>
</reaction>
<!-- reaction 0102 -->
<reaction id="0102" reversible="yes">
<equation>OH + CH2OH [=] H2O + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+09</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2OH:1 OH:1</reactants>
<products>CH2O:1 H2O:1</products>
</reaction>
<!-- reaction 0103 -->
<reaction id="0103" reversible="yes">
<equation>OH + CH3O [=] H2O + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+09</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3O:1 OH:1</reactants>
<products>CH2O:1 H2O:1</products>
</reaction>
<!-- reaction 0104 -->
<reaction id="0104" reversible="yes">
<equation>OH + CH3OH [=] CH2OH + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.440000E+03</A>
<b>2</b>
<E units="cal/mol">-840.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3OH:1 OH:1</reactants>
<products>CH2OH:1 H2O:1</products>
</reaction>
<!-- reaction 0105 -->
<reaction id="0105" reversible="yes">
<equation>OH + CH3OH [=] CH3O + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 6.300000E+03</A>
<b>2</b>
<E units="cal/mol">1500.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3OH:1 OH:1</reactants>
<products>H2O:1 CH3O:1</products>
</reaction>
<!-- reaction 0106 -->
<reaction id="0106" reversible="yes">
<equation>OH + C2H [=] H + HCCO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H:1 OH:1</reactants>
<products>H:1 HCCO:1</products>
</reaction>
<!-- reaction 0107 -->
<reaction id="0107" reversible="yes">
<equation>OH + C2H2 [=] H + CH2CO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.180000E-07</A>
<b>4.5</b>
<E units="cal/mol">-1000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H2:1 OH:1</reactants>
<products>H:1 CH2CO:1</products>
</reaction>
<!-- reaction 0108 -->
<reaction id="0108" reversible="yes">
<equation>OH + C2H2 [=] H + HCCOH</equation>
<rateCoeff>
<Arrhenius>
<A> 5.040000E+02</A>
<b>2.2999999999999998</b>
<E units="cal/mol">13500.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H2:1 OH:1</reactants>
<products>H:1 HCCOH:1</products>
</reaction>
<!-- reaction 0109 -->
<reaction id="0109" reversible="yes">
<equation>OH + C2H2 [=] C2H + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 3.370000E+04</A>
<b>2</b>
<E units="cal/mol">14000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H2:1 OH:1</reactants>
<products>C2H:1 H2O:1</products>
</reaction>
<!-- reaction 0110 -->
<reaction id="0110" reversible="yes">
<equation>OH + C2H2 [=] CH3 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 4.830000E-07</A>
<b>4</b>
<E units="cal/mol">-2000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H2:1 OH:1</reactants>
<products>CH3:1 CO:1</products>
</reaction>
<!-- reaction 0111 -->
<reaction id="0111" reversible="yes">
<equation>OH + C2H3 [=] H2O + C2H2</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+09</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H3:1 OH:1</reactants>
<products>H2O:1 C2H2:1</products>
</reaction>
<!-- reaction 0112 -->
<reaction id="0112" reversible="yes">
<equation>OH + C2H4 [=] C2H3 + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 3.600000E+03</A>
<b>2</b>
<E units="cal/mol">2500.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H4:1 OH:1</reactants>
<products>H2O:1 C2H3:1</products>
</reaction>
<!-- reaction 0113 -->
<reaction id="0113" reversible="yes">
<equation>OH + C2H6 [=] C2H5 + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 3.540000E+03</A>
<b>2.1200000000000001</b>
<E units="cal/mol">870.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H6:1 OH:1</reactants>
<products>C2H5:1 H2O:1</products>
</reaction>
<!-- reaction 0114 -->
<reaction id="0114" reversible="yes">
<equation>OH + CH2CO [=] HCCO + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 7.500000E+09</A>
<b>0</b>
<E units="cal/mol">2000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2CO:1 OH:1</reactants>
<products>H2O:1 HCCO:1</products>
</reaction>
<!-- reaction 0115 -->
<reaction duplicate="yes" id="0115" reversible="yes">
<equation>2 HO2 [=] O2 + H2O2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.300000E+08</A>
<b>0</b>
<E units="cal/mol">-1630.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HO2:2</reactants>
<products>O2:1 H2O2:1</products>
</reaction>
<!-- reaction 0116 -->
<reaction duplicate="yes" id="0116" reversible="yes">
<equation>2 HO2 [=] O2 + H2O2</equation>
<rateCoeff>
<Arrhenius>
<A> 4.200000E+11</A>
<b>0</b>
<E units="cal/mol">12000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HO2:2</reactants>
<products>O2:1 H2O2:1</products>
</reaction>
<!-- reaction 0117 -->
<reaction id="0117" reversible="yes">
<equation>HO2 + CH2 [=] OH + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:1 HO2:1</reactants>
<products>CH2O:1 OH:1</products>
</reaction>
<!-- reaction 0118 -->
<reaction id="0118" reversible="yes">
<equation>HO2 + CH3 [=] O2 + CH4</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+09</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 HO2:1</reactants>
<products>CH4:1 O2:1</products>
</reaction>
<!-- reaction 0119 -->
<reaction id="0119" reversible="yes">
<equation>HO2 + CH3 [=] OH + CH3O</equation>
<rateCoeff>
<Arrhenius>
<A> 3.780000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 HO2:1</reactants>
<products>CH3O:1 OH:1</products>
</reaction>
<!-- reaction 0120 -->
<reaction id="0120" reversible="yes">
<equation>HO2 + CO [=] OH + CO2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.500000E+11</A>
<b>0</b>
<E units="cal/mol">23600.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CO:1 HO2:1</reactants>
<products>CO2:1 OH:1</products>
</reaction>
<!-- reaction 0121 -->
<reaction id="0121" reversible="yes">
<equation>HO2 + CH2O [=] HCO + H2O2</equation>
<rateCoeff>
<Arrhenius>
<A> 5.600000E+03</A>
<b>2</b>
<E units="cal/mol">12000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2O:1 HO2:1</reactants>
<products>HCO:1 H2O2:1</products>
</reaction>
<!-- reaction 0122 -->
<reaction id="0122" reversible="yes">
<equation>C + O2 [=] O + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 5.800000E+10</A>
<b>0</b>
<E units="cal/mol">576.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C:1 O2:1</reactants>
<products>CO:1 O:1</products>
</reaction>
<!-- reaction 0123 -->
<reaction id="0123" reversible="yes">
<equation>C + CH2 [=] H + C2H</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C:1 CH2:1</reactants>
<products>H:1 C2H:1</products>
</reaction>
<!-- reaction 0124 -->
<reaction id="0124" reversible="yes">
<equation>C + CH3 [=] H + C2H2</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C:1 CH3:1</reactants>
<products>H:1 C2H2:1</products>
</reaction>
<!-- reaction 0125 -->
<reaction id="0125" reversible="yes">
<equation>CH + O2 [=] O + HCO</equation>
<rateCoeff>
<Arrhenius>
<A> 6.710000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH:1 O2:1</reactants>
<products>HCO:1 O:1</products>
</reaction>
<!-- reaction 0126 -->
<reaction id="0126" reversible="yes">
<equation>CH + H2 [=] H + CH2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.080000E+11</A>
<b>0</b>
<E units="cal/mol">3110.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H2:1 CH:1</reactants>
<products>H:1 CH2:1</products>
</reaction>
<!-- reaction 0127 -->
<reaction id="0127" reversible="yes">
<equation>CH + H2O [=] H + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 5.710000E+09</A>
<b>0</b>
<E units="cal/mol">-755.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H2O:1 CH:1</reactants>
<products>CH2O:1 H:1</products>
</reaction>
<!-- reaction 0128 -->
<reaction id="0128" reversible="yes">
<equation>CH + CH2 [=] H + C2H2</equation>
<rateCoeff>
<Arrhenius>
<A> 4.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:1 CH:1</reactants>
<products>H:1 C2H2:1</products>
</reaction>
<!-- reaction 0129 -->
<reaction id="0129" reversible="yes">
<equation>CH + CH3 [=] H + C2H3</equation>
<rateCoeff>
<Arrhenius>
<A> 3.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 CH:1</reactants>
<products>H:1 C2H3:1</products>
</reaction>
<!-- reaction 0130 -->
<reaction id="0130" reversible="yes">
<equation>CH + CH4 [=] H + C2H4</equation>
<rateCoeff>
<Arrhenius>
<A> 6.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH:1 CH4:1</reactants>
<products>H:1 C2H4:1</products>
</reaction>
<!-- reaction 0131 -->
<reaction id="0131" reversible="yes" type="falloff">
<equation>CH + CO (+ M) [=] HCCO (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 2.690000E+22</A>
<b>-3.7400000000000002</b>
<E units="cal/mol">1936.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.5757 237 1652 5069 </falloff>
</rateCoeff>
<reactants>CH:1 CO:1</reactants>
<products>HCCO:1</products>
</reaction>
<!-- reaction 0132 -->
<reaction id="0132" reversible="yes">
<equation>CH + CO2 [=] HCO + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.900000E+11</A>
<b>0</b>
<E units="cal/mol">15792.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH:1 CO2:1</reactants>
<products>CO:1 HCO:1</products>
</reaction>
<!-- reaction 0133 -->
<reaction id="0133" reversible="yes">
<equation>CH + CH2O [=] H + CH2CO</equation>
<rateCoeff>
<Arrhenius>
<A> 9.460000E+10</A>
<b>0</b>
<E units="cal/mol">-515.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2O:1 CH:1</reactants>
<products>H:1 CH2CO:1</products>
</reaction>
<!-- reaction 0134 -->
<reaction id="0134" reversible="yes">
<equation>CH + HCCO [=] CO + C2H2</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH:1 HCCO:1</reactants>
<products>CO:1 C2H2:1</products>
</reaction>
<!-- reaction 0135 -->
<reaction id="0135" reversible="no">
<equation>CH2 + O2 =] OH + H + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+09</A>
<b>0</b>
<E units="cal/mol">1500.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:1 O2:1</reactants>
<products>H:1 CO:1 OH:1</products>
</reaction>
<!-- reaction 0136 -->
<reaction id="0136" reversible="yes">
<equation>CH2 + H2 [=] H + CH3</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+02</A>
<b>2</b>
<E units="cal/mol">7230.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H2:1 CH2:1</reactants>
<products>H:1 CH3:1</products>
</reaction>
<!-- reaction 0137 -->
<reaction id="0137" reversible="yes">
<equation>2 CH2 [=] H2 + C2H2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.600000E+12</A>
<b>0</b>
<E units="cal/mol">11944.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:2</reactants>
<products>H2:1 C2H2:1</products>
</reaction>
<!-- reaction 0138 -->
<reaction id="0138" reversible="yes">
<equation>CH2 + CH3 [=] H + C2H4</equation>
<rateCoeff>
<Arrhenius>
<A> 4.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:1 CH3:1</reactants>
<products>H:1 C2H4:1</products>
</reaction>
<!-- reaction 0139 -->
<reaction id="0139" reversible="yes">
<equation>CH2 + CH4 [=] 2 CH3</equation>
<rateCoeff>
<Arrhenius>
<A> 2.460000E+03</A>
<b>2</b>
<E units="cal/mol">8270.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:1 CH4:1</reactants>
<products>CH3:2</products>
</reaction>
<!-- reaction 0140 -->
<reaction id="0140" reversible="yes" type="falloff">
<equation>CH2 + CO (+ M) [=] CH2CO (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 8.100000E+08</A>
<b>0.5</b>
<E units="cal/mol">4510.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 2.690000E+27</A>
<b>-5.1100000000000003</b>
<E units="cal/mol">7095.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.5907 275 1226 5185 </falloff>
</rateCoeff>
<reactants>CH2:1 CO:1</reactants>
<products>CH2CO:1</products>
</reaction>
<!-- reaction 0141 -->
<reaction id="0141" reversible="yes">
<equation>CH2 + HCCO [=] C2H3 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 3.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:1 HCCO:1</reactants>
<products>CO:1 C2H3:1</products>
</reaction>
<!-- reaction 0142 -->
<reaction id="0142" reversible="yes">
<equation>CH2(S) + N2 [=] CH2 + N2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.500000E+10</A>
<b>0</b>
<E units="cal/mol">600.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 N2:1</reactants>
<products>CH2:1 N2:1</products>
</reaction>
<!-- reaction 0143 -->
<reaction id="0143" reversible="yes">
<equation>CH2(S) + AR [=] CH2 + AR</equation>
<rateCoeff>
<Arrhenius>
<A> 9.000000E+09</A>
<b>0</b>
<E units="cal/mol">600.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 AR:1</reactants>
<products>CH2:1 AR:1</products>
</reaction>
<!-- reaction 0144 -->
<reaction id="0144" reversible="yes">
<equation>CH2(S) + O2 [=] H + OH + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.800000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 O2:1</reactants>
<products>H:1 CO:1 OH:1</products>
</reaction>
<!-- reaction 0145 -->
<reaction id="0145" reversible="yes">
<equation>CH2(S) + O2 [=] CO + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.200000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 O2:1</reactants>
<products>H2O:1 CO:1</products>
</reaction>
<!-- reaction 0146 -->
<reaction id="0146" reversible="yes">
<equation>CH2(S) + H2 [=] CH3 + H</equation>
<rateCoeff>
<Arrhenius>
<A> 7.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H2:1 CH2(S):1</reactants>
<products>H:1 CH3:1</products>
</reaction>
<!-- reaction 0147 -->
<reaction id="0147" reversible="yes" type="falloff">
<equation>CH2(S) + H2O (+ M) [=] CH3OH (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 4.820000E+14</A>
<b>-1.1599999999999999</b>
<E units="cal/mol">1145.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 1.880000E+32</A>
<b>-6.3600000000000003</b>
<E units="cal/mol">5040.000000</E>
</Arrhenius>
<efficiencies default="1.0"> C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.6027 208 3922 10180 </falloff>
</rateCoeff>
<reactants>CH2(S):1 H2O:1</reactants>
<products>CH3OH:1</products>
</reaction>
<!-- reaction 0148 -->
<reaction id="0148" reversible="yes">
<equation>CH2(S) + H2O [=] CH2 + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 3.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 H2O:1</reactants>
<products>CH2:1 H2O:1</products>
</reaction>
<!-- reaction 0149 -->
<reaction id="0149" reversible="yes">
<equation>CH2(S) + CH3 [=] H + C2H4</equation>
<rateCoeff>
<Arrhenius>
<A> 1.200000E+10</A>
<b>0</b>
<E units="cal/mol">-570.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 CH3:1</reactants>
<products>H:1 C2H4:1</products>
</reaction>
<!-- reaction 0150 -->
<reaction id="0150" reversible="yes">
<equation>CH2(S) + CH4 [=] 2 CH3</equation>
<rateCoeff>
<Arrhenius>
<A> 1.600000E+10</A>
<b>0</b>
<E units="cal/mol">-570.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 CH4:1</reactants>
<products>CH3:2</products>
</reaction>
<!-- reaction 0151 -->
<reaction id="0151" reversible="yes">
<equation>CH2(S) + CO [=] CH2 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 9.000000E+09</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 CO:1</reactants>
<products>CH2:1 CO:1</products>
</reaction>
<!-- reaction 0152 -->
<reaction id="0152" reversible="yes">
<equation>CH2(S) + CO2 [=] CH2 + CO2</equation>
<rateCoeff>
<Arrhenius>
<A> 7.000000E+09</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 CO2:1</reactants>
<products>CH2:1 CO2:1</products>
</reaction>
<!-- reaction 0153 -->
<reaction id="0153" reversible="yes">
<equation>CH2(S) + CO2 [=] CO + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.400000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 CO2:1</reactants>
<products>CH2O:1 CO:1</products>
</reaction>
<!-- reaction 0154 -->
<reaction id="0154" reversible="yes">
<equation>CH2(S) + C2H6 [=] CH3 + C2H5</equation>
<rateCoeff>
<Arrhenius>
<A> 4.000000E+10</A>
<b>0</b>
<E units="cal/mol">-550.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 C2H6:1</reactants>
<products>C2H5:1 CH3:1</products>
</reaction>
<!-- reaction 0155 -->
<reaction id="0155" reversible="yes">
<equation>CH3 + O2 [=] O + CH3O</equation>
<rateCoeff>
<Arrhenius>
<A> 3.560000E+10</A>
<b>0</b>
<E units="cal/mol">30480.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 O2:1</reactants>
<products>CH3O:1 O:1</products>
</reaction>
<!-- reaction 0156 -->
<reaction id="0156" reversible="yes">
<equation>CH3 + O2 [=] OH + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 2.310000E+09</A>
<b>0</b>
<E units="cal/mol">20315.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 O2:1</reactants>
<products>CH2O:1 OH:1</products>
</reaction>
<!-- reaction 0157 -->
<reaction id="0157" reversible="yes">
<equation>CH3 + H2O2 [=] HO2 + CH4</equation>
<rateCoeff>
<Arrhenius>
<A> 2.450000E+01</A>
<b>2.4700000000000002</b>
<E units="cal/mol">5180.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 H2O2:1</reactants>
<products>CH4:1 HO2:1</products>
</reaction>
<!-- reaction 0158 -->
<reaction id="0158" reversible="yes" type="falloff">
<equation>2 CH3 (+ M) [=] C2H6 (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 6.770000E+13</A>
<b>-1.1799999999999999</b>
<E units="cal/mol">654.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 3.400000E+35</A>
<b>-7.0300000000000002</b>
<E units="cal/mol">2762.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.619 73.2 1180 9999 </falloff>
</rateCoeff>
<reactants>CH3:2</reactants>
<products>C2H6:1</products>
</reaction>
<!-- reaction 0159 -->
<reaction id="0159" reversible="yes">
<equation>2 CH3 [=] H + C2H5</equation>
<rateCoeff>
<Arrhenius>
<A> 6.840000E+09</A>
<b>0.10000000000000001</b>
<E units="cal/mol">10600.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:2</reactants>
<products>H:1 C2H5:1</products>
</reaction>
<!-- reaction 0160 -->
<reaction id="0160" reversible="yes">
<equation>CH3 + HCO [=] CH4 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.648000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 HCO:1</reactants>
<products>CO:1 CH4:1</products>
</reaction>
<!-- reaction 0161 -->
<reaction id="0161" reversible="yes">
<equation>CH3 + CH2O [=] HCO + CH4</equation>
<rateCoeff>
<Arrhenius>
<A> 3.320000E+00</A>
<b>2.8100000000000001</b>
<E units="cal/mol">5860.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2O:1 CH3:1</reactants>
<products>CH4:1 HCO:1</products>
</reaction>
<!-- reaction 0162 -->
<reaction id="0162" reversible="yes">
<equation>CH3 + CH3OH [=] CH2OH + CH4</equation>
<rateCoeff>
<Arrhenius>
<A> 3.000000E+04</A>
<b>1.5</b>
<E units="cal/mol">9940.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3OH:1 CH3:1</reactants>
<products>CH2OH:1 CH4:1</products>
</reaction>
<!-- reaction 0163 -->
<reaction id="0163" reversible="yes">
<equation>CH3 + CH3OH [=] CH3O + CH4</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+04</A>
<b>1.5</b>
<E units="cal/mol">9940.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3OH:1 CH3:1</reactants>
<products>CH3O:1 CH4:1</products>
</reaction>
<!-- reaction 0164 -->
<reaction id="0164" reversible="yes">
<equation>CH3 + C2H4 [=] C2H3 + CH4</equation>
<rateCoeff>
<Arrhenius>
<A> 2.270000E+02</A>
<b>2</b>
<E units="cal/mol">9200.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 C2H4:1</reactants>
<products>CH4:1 C2H3:1</products>
</reaction>
<!-- reaction 0165 -->
<reaction id="0165" reversible="yes">
<equation>CH3 + C2H6 [=] C2H5 + CH4</equation>
<rateCoeff>
<Arrhenius>
<A> 6.140000E+03</A>
<b>1.74</b>
<E units="cal/mol">10450.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H6:1 CH3:1</reactants>
<products>C2H5:1 CH4:1</products>
</reaction>
<!-- reaction 0166 -->
<reaction id="0166" reversible="yes">
<equation>HCO + H2O [=] H + CO + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.500000E+15</A>
<b>-1</b>
<E units="cal/mol">17000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H2O:1 HCO:1</reactants>
<products>H:1 H2O:1 CO:1</products>
</reaction>
<!-- reaction 0167 -->
<reaction id="0167" reversible="yes" type="threeBody">
<equation>HCO + M [=] H + CO + M</equation>
<rateCoeff>
<Arrhenius>
<A> 1.870000E+14</A>
<b>-1</b>
<E units="cal/mol">17000.000000</E>
</Arrhenius>
<efficiencies default="1.0"> C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:0 </efficiencies>
</rateCoeff>
<reactants>HCO:1</reactants>
<products>H:1 CO:1</products>
</reaction>
<!-- reaction 0168 -->
<reaction id="0168" reversible="yes">
<equation>HCO + O2 [=] HO2 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.345000E+10</A>
<b>0</b>
<E units="cal/mol">400.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HCO:1 O2:1</reactants>
<products>CO:1 HO2:1</products>
</reaction>
<!-- reaction 0169 -->
<reaction id="0169" reversible="yes">
<equation>CH2OH + O2 [=] HO2 + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.800000E+10</A>
<b>0</b>
<E units="cal/mol">900.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2OH:1 O2:1</reactants>
<products>CH2O:1 HO2:1</products>
</reaction>
<!-- reaction 0170 -->
<reaction id="0170" reversible="yes">
<equation>CH3O + O2 [=] HO2 + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 4.280000E-16</A>
<b>7.5999999999999996</b>
<E units="cal/mol">-3530.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3O:1 O2:1</reactants>
<products>CH2O:1 HO2:1</products>
</reaction>
<!-- reaction 0171 -->
<reaction id="0171" reversible="yes">
<equation>C2H + O2 [=] HCO + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+10</A>
<b>0</b>
<E units="cal/mol">-755.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H:1 O2:1</reactants>
<products>CO:1 HCO:1</products>
</reaction>
<!-- reaction 0172 -->
<reaction id="0172" reversible="yes">
<equation>C2H + H2 [=] H + C2H2</equation>
<rateCoeff>
<Arrhenius>
<A> 5.680000E+07</A>
<b>0.90000000000000002</b>
<E units="cal/mol">1993.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H2:1 C2H:1</reactants>
<products>H:1 C2H2:1</products>
</reaction>
<!-- reaction 0173 -->
<reaction id="0173" reversible="yes">
<equation>C2H3 + O2 [=] HCO + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 4.580000E+13</A>
<b>-1.3899999999999999</b>
<E units="cal/mol">1015.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H3:1 O2:1</reactants>
<products>CH2O:1 HCO:1</products>
</reaction>
<!-- reaction 0174 -->
<reaction id="0174" reversible="yes" type="falloff">
<equation>C2H4 (+ M) [=] H2 + C2H2 (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 8.000000E+12</A>
<b>0.44</b>
<E units="cal/mol">86770.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 1.580000E+48</A>
<b>-9.3000000000000007</b>
<E units="cal/mol">97800.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.7345 180 1035 5417 </falloff>
</rateCoeff>
<reactants>C2H4:1</reactants>
<products>H2:1 C2H2:1</products>
</reaction>
<!-- reaction 0175 -->
<reaction id="0175" reversible="yes">
<equation>C2H5 + O2 [=] HO2 + C2H4</equation>
<rateCoeff>
<Arrhenius>
<A> 8.400000E+08</A>
<b>0</b>
<E units="cal/mol">3875.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H5:1 O2:1</reactants>
<products>C2H4:1 HO2:1</products>
</reaction>
<!-- reaction 0176 -->
<reaction id="0176" reversible="yes">
<equation>HCCO + O2 [=] OH + 2 CO</equation>
<rateCoeff>
<Arrhenius>
<A> 3.200000E+09</A>
<b>0</b>
<E units="cal/mol">854.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HCCO:1 O2:1</reactants>
<products>CO:2 OH:1</products>
</reaction>
<!-- reaction 0177 -->
<reaction id="0177" reversible="yes">
<equation>2 HCCO [=] 2 CO + C2H2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HCCO:2</reactants>
<products>CO:2 C2H2:1</products>
</reaction>
<!-- reaction 0178 -->
<reaction id="0178" reversible="yes">
<equation>N + NO [=] N2 + O</equation>
<rateCoeff>
<Arrhenius>
<A> 2.700000E+10</A>
<b>0</b>
<E units="cal/mol">355.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NO:1 N:1</reactants>
<products>N2:1 O:1</products>
</reaction>
<!-- reaction 0179 -->
<reaction id="0179" reversible="yes">
<equation>N + O2 [=] NO + O</equation>
<rateCoeff>
<Arrhenius>
<A> 9.000000E+06</A>
<b>1</b>
<E units="cal/mol">6500.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>O2:1 N:1</reactants>
<products>O:1 NO:1</products>
</reaction>
<!-- reaction 0180 -->
<reaction id="0180" reversible="yes">
<equation>N + OH [=] NO + H</equation>
<rateCoeff>
<Arrhenius>
<A> 3.360000E+10</A>
<b>0</b>
<E units="cal/mol">385.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>OH:1 N:1</reactants>
<products>H:1 NO:1</products>
</reaction>
<!-- reaction 0181 -->
<reaction id="0181" reversible="yes">
<equation>N2O + O [=] N2 + O2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.400000E+09</A>
<b>0</b>
<E units="cal/mol">10810.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>N2O:1 O:1</reactants>
<products>N2:1 O2:1</products>
</reaction>
<!-- reaction 0182 -->
<reaction id="0182" reversible="yes">
<equation>N2O + O [=] 2 NO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.900000E+10</A>
<b>0</b>
<E units="cal/mol">23150.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>N2O:1 O:1</reactants>
<products>NO:2</products>
</reaction>
<!-- reaction 0183 -->
<reaction id="0183" reversible="yes">
<equation>N2O + H [=] N2 + OH</equation>
<rateCoeff>
<Arrhenius>
<A> 3.870000E+11</A>
<b>0</b>
<E units="cal/mol">18880.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 N2O:1</reactants>
<products>N2:1 OH:1</products>
</reaction>
<!-- reaction 0184 -->
<reaction id="0184" reversible="yes">
<equation>N2O + OH [=] N2 + HO2</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+09</A>
<b>0</b>
<E units="cal/mol">21060.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>N2O:1 OH:1</reactants>
<products>N2:1 HO2:1</products>
</reaction>
<!-- reaction 0185 -->
<reaction id="0185" reversible="yes" type="falloff">
<equation>N2O (+ M) [=] N2 + O (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 7.910000E+10</A>
<b>0</b>
<E units="cal/mol">56020.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 6.370000E+11</A>
<b>0</b>
<E units="cal/mol">56640.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.625 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Lindemann"/>
</rateCoeff>
<reactants>N2O:1</reactants>
<products>N2:1 O:1</products>
</reaction>
<!-- reaction 0186 -->
<reaction id="0186" reversible="yes">
<equation>HO2 + NO [=] NO2 + OH</equation>
<rateCoeff>
<Arrhenius>
<A> 2.110000E+09</A>
<b>0</b>
<E units="cal/mol">-480.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HO2:1 NO:1</reactants>
<products>NO2:1 OH:1</products>
</reaction>
<!-- reaction 0187 -->
<reaction id="0187" reversible="yes" type="threeBody">
<equation>NO + O + M [=] NO2 + M</equation>
<rateCoeff>
<Arrhenius>
<A> 1.060000E+14</A>
<b>-1.4099999999999999</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
</rateCoeff>
<reactants>O:1 NO:1</reactants>
<products>NO2:1</products>
</reaction>
<!-- reaction 0188 -->
<reaction id="0188" reversible="yes">
<equation>NO2 + O [=] NO + O2</equation>
<rateCoeff>
<Arrhenius>
<A> 3.900000E+09</A>
<b>0</b>
<E units="cal/mol">-240.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>O:1 NO2:1</reactants>
<products>O2:1 NO:1</products>
</reaction>
<!-- reaction 0189 -->
<reaction id="0189" reversible="yes">
<equation>NO2 + H [=] NO + OH</equation>
<rateCoeff>
<Arrhenius>
<A> 1.320000E+11</A>
<b>0</b>
<E units="cal/mol">360.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 NO2:1</reactants>
<products>OH:1 NO:1</products>
</reaction>
<!-- reaction 0190 -->
<reaction id="0190" reversible="yes">
<equation>NH + O [=] NO + H</equation>
<rateCoeff>
<Arrhenius>
<A> 4.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NH:1 O:1</reactants>
<products>H:1 NO:1</products>
</reaction>
<!-- reaction 0191 -->
<reaction id="0191" reversible="yes">
<equation>NH + H [=] N + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 3.200000E+10</A>
<b>0</b>
<E units="cal/mol">330.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NH:1 H:1</reactants>
<products>H2:1 N:1</products>
</reaction>
<!-- reaction 0192 -->
<reaction id="0192" reversible="yes">
<equation>NH + OH [=] HNO + H</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NH:1 OH:1</reactants>
<products>H:1 HNO:1</products>
</reaction>
<!-- reaction 0193 -->
<reaction id="0193" reversible="yes">
<equation>NH + OH [=] N + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+06</A>
<b>1.2</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NH:1 OH:1</reactants>
<products>H2O:1 N:1</products>
</reaction>
<!-- reaction 0194 -->
<reaction id="0194" reversible="yes">
<equation>NH + O2 [=] HNO + O</equation>
<rateCoeff>
<Arrhenius>
<A> 4.610000E+02</A>
<b>2</b>
<E units="cal/mol">6500.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NH:1 O2:1</reactants>
<products>O:1 HNO:1</products>
</reaction>
<!-- reaction 0195 -->
<reaction id="0195" reversible="yes">
<equation>NH + O2 [=] NO + OH</equation>
<rateCoeff>
<Arrhenius>
<A> 1.280000E+03</A>
<b>1.5</b>
<E units="cal/mol">100.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NH:1 O2:1</reactants>
<products>OH:1 NO:1</products>
</reaction>
<!-- reaction 0196 -->
<reaction id="0196" reversible="yes">
<equation>NH + N [=] N2 + H</equation>
<rateCoeff>
<Arrhenius>
<A> 1.500000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NH:1 N:1</reactants>
<products>H:1 N2:1</products>
</reaction>
<!-- reaction 0197 -->
<reaction id="0197" reversible="yes">
<equation>NH + H2O [=] HNO + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+10</A>
<b>0</b>
<E units="cal/mol">13850.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NH:1 H2O:1</reactants>
<products>H2:1 HNO:1</products>
</reaction>
<!-- reaction 0198 -->
<reaction id="0198" reversible="yes">
<equation>NH + NO [=] N2 + OH</equation>
<rateCoeff>
<Arrhenius>
<A> 2.160000E+10</A>
<b>-0.23000000000000001</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NH:1 NO:1</reactants>
<products>N2:1 OH:1</products>
</reaction>
<!-- reaction 0199 -->
<reaction id="0199" reversible="yes">
<equation>NH + NO [=] N2O + H</equation>
<rateCoeff>
<Arrhenius>
<A> 3.650000E+11</A>
<b>-0.45000000000000001</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NH:1 NO:1</reactants>
<products>H:1 N2O:1</products>
</reaction>
<!-- reaction 0200 -->
<reaction id="0200" reversible="yes">
<equation>NH2 + O [=] OH + NH</equation>
<rateCoeff>
<Arrhenius>
<A> 3.000000E+09</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>O:1 NH2:1</reactants>
<products>NH:1 OH:1</products>
</reaction>
<!-- reaction 0201 -->
<reaction id="0201" reversible="yes">
<equation>NH2 + O [=] H + HNO</equation>
<rateCoeff>
<Arrhenius>
<A> 3.900000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>O:1 NH2:1</reactants>
<products>H:1 HNO:1</products>
</reaction>
<!-- reaction 0202 -->
<reaction id="0202" reversible="yes">
<equation>NH2 + H [=] NH + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 4.000000E+10</A>
<b>0</b>
<E units="cal/mol">3650.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 NH2:1</reactants>
<products>NH:1 H2:1</products>
</reaction>
<!-- reaction 0203 -->
<reaction id="0203" reversible="yes">
<equation>NH2 + OH [=] NH + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 9.000000E+04</A>
<b>1.5</b>
<E units="cal/mol">-460.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>OH:1 NH2:1</reactants>
<products>NH:1 H2O:1</products>
</reaction>
<!-- reaction 0204 -->
<reaction id="0204" reversible="yes">
<equation>NNH [=] N2 + H</equation>
<rateCoeff>
<Arrhenius>
<A> 3.300000E+08</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NNH:1</reactants>
<products>H:1 N2:1</products>
</reaction>
<!-- reaction 0205 -->
<reaction id="0205" reversible="yes" type="threeBody">
<equation>NNH + M [=] N2 + H + M</equation>
<rateCoeff>
<Arrhenius>
<A> 1.300000E+11</A>
<b>-0.11</b>
<E units="cal/mol">4980.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
</rateCoeff>
<reactants>NNH:1</reactants>
<products>H:1 N2:1</products>
</reaction>
<!-- reaction 0206 -->
<reaction id="0206" reversible="yes">
<equation>NNH + O2 [=] HO2 + N2</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+09</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>O2:1 NNH:1</reactants>
<products>N2:1 HO2:1</products>
</reaction>
<!-- reaction 0207 -->
<reaction id="0207" reversible="yes">
<equation>NNH + O [=] OH + N2</equation>
<rateCoeff>
<Arrhenius>
<A> 2.500000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>O:1 NNH:1</reactants>
<products>N2:1 OH:1</products>
</reaction>
<!-- reaction 0208 -->
<reaction id="0208" reversible="yes">
<equation>NNH + O [=] NH + NO</equation>
<rateCoeff>
<Arrhenius>
<A> 7.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>O:1 NNH:1</reactants>
<products>NH:1 NO:1</products>
</reaction>
<!-- reaction 0209 -->
<reaction id="0209" reversible="yes">
<equation>NNH + H [=] H2 + N2</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 NNH:1</reactants>
<products>H2:1 N2:1</products>
</reaction>
<!-- reaction 0210 -->
<reaction id="0210" reversible="yes">
<equation>NNH + OH [=] H2O + N2</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>OH:1 NNH:1</reactants>
<products>H2O:1 N2:1</products>
</reaction>
<!-- reaction 0211 -->
<reaction id="0211" reversible="yes">
<equation>NNH + CH3 [=] CH4 + N2</equation>
<rateCoeff>
<Arrhenius>
<A> 2.500000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 NNH:1</reactants>
<products>N2:1 CH4:1</products>
</reaction>
<!-- reaction 0212 -->
<reaction id="0212" reversible="yes" type="threeBody">
<equation>H + NO + M [=] HNO + M</equation>
<rateCoeff>
<Arrhenius>
<A> 4.480000E+13</A>
<b>-1.3200000000000001</b>
<E units="cal/mol">740.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
</rateCoeff>
<reactants>H:1 NO:1</reactants>
<products>HNO:1</products>
</reaction>
<!-- reaction 0213 -->
<reaction id="0213" reversible="yes">
<equation>HNO + O [=] NO + OH</equation>
<rateCoeff>
<Arrhenius>
<A> 2.500000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>O:1 HNO:1</reactants>
<products>OH:1 NO:1</products>
</reaction>
<!-- reaction 0214 -->
<reaction id="0214" reversible="yes">
<equation>HNO + H [=] H2 + NO</equation>
<rateCoeff>
<Arrhenius>
<A> 9.000000E+08</A>
<b>0.71999999999999997</b>
<E units="cal/mol">660.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 HNO:1</reactants>
<products>H2:1 NO:1</products>
</reaction>
<!-- reaction 0215 -->
<reaction id="0215" reversible="yes">
<equation>HNO + OH [=] NO + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.300000E+04</A>
<b>1.8999999999999999</b>
<E units="cal/mol">-950.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HNO:1 OH:1</reactants>
<products>H2O:1 NO:1</products>
</reaction>
<!-- reaction 0216 -->
<reaction id="0216" reversible="yes">
<equation>HNO + O2 [=] HO2 + NO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+10</A>
<b>0</b>
<E units="cal/mol">13000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>O2:1 HNO:1</reactants>
<products>HO2:1 NO:1</products>
</reaction>
<!-- reaction 0217 -->
<reaction id="0217" reversible="yes">
<equation>CN + O [=] CO + N</equation>
<rateCoeff>
<Arrhenius>
<A> 7.700000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CN:1 O:1</reactants>
<products>CO:1 N:1</products>
</reaction>
<!-- reaction 0218 -->
<reaction id="0218" reversible="yes">
<equation>CN + OH [=] NCO + H</equation>
<rateCoeff>
<Arrhenius>
<A> 4.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CN:1 OH:1</reactants>
<products>H:1 NCO:1</products>
</reaction>
<!-- reaction 0219 -->
<reaction id="0219" reversible="yes">
<equation>CN + H2O [=] HCN + OH</equation>
<rateCoeff>
<Arrhenius>
<A> 8.000000E+09</A>
<b>0</b>
<E units="cal/mol">7460.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H2O:1 CN:1</reactants>
<products>HCN:1 OH:1</products>
</reaction>
<!-- reaction 0220 -->
<reaction id="0220" reversible="yes">
<equation>CN + O2 [=] NCO + O</equation>
<rateCoeff>
<Arrhenius>
<A> 6.140000E+09</A>
<b>0</b>
<E units="cal/mol">-440.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CN:1 O2:1</reactants>
<products>O:1 NCO:1</products>
</reaction>
<!-- reaction 0221 -->
<reaction id="0221" reversible="yes">
<equation>CN + H2 [=] HCN + H</equation>
<rateCoeff>
<Arrhenius>
<A> 2.950000E+02</A>
<b>2.4500000000000002</b>
<E units="cal/mol">2240.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H2:1 CN:1</reactants>
<products>H:1 HCN:1</products>
</reaction>
<!-- reaction 0222 -->
<reaction id="0222" reversible="yes">
<equation>NCO + O [=] NO + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.350000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>O:1 NCO:1</reactants>
<products>CO:1 NO:1</products>
</reaction>
<!-- reaction 0223 -->
<reaction id="0223" reversible="yes">
<equation>NCO + H [=] NH + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 5.400000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 NCO:1</reactants>
<products>NH:1 CO:1</products>
</reaction>
<!-- reaction 0224 -->
<reaction id="0224" reversible="yes">
<equation>NCO + OH [=] NO + H + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.500000E+09</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>OH:1 NCO:1</reactants>
<products>H:1 CO:1 NO:1</products>
</reaction>
<!-- reaction 0225 -->
<reaction id="0225" reversible="yes">
<equation>NCO + N [=] N2 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>N:1 NCO:1</reactants>
<products>N2:1 CO:1</products>
</reaction>
<!-- reaction 0226 -->
<reaction id="0226" reversible="yes">
<equation>NCO + O2 [=] NO + CO2</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+09</A>
<b>0</b>
<E units="cal/mol">20000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>O2:1 NCO:1</reactants>
<products>CO2:1 NO:1</products>
</reaction>
<!-- reaction 0227 -->
<reaction id="0227" reversible="yes" type="threeBody">
<equation>NCO + M [=] N + CO + M</equation>
<rateCoeff>
<Arrhenius>
<A> 3.100000E+11</A>
<b>0</b>
<E units="cal/mol">54050.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
</rateCoeff>
<reactants>NCO:1</reactants>
<products>CO:1 N:1</products>
</reaction>
<!-- reaction 0228 -->
<reaction id="0228" reversible="yes">
<equation>NCO + NO [=] N2O + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.900000E+14</A>
<b>-1.52</b>
<E units="cal/mol">740.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NO:1 NCO:1</reactants>
<products>CO:1 N2O:1</products>
</reaction>
<!-- reaction 0229 -->
<reaction id="0229" reversible="yes">
<equation>NCO + NO [=] N2 + CO2</equation>
<rateCoeff>
<Arrhenius>
<A> 3.800000E+15</A>
<b>-2</b>
<E units="cal/mol">800.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NO:1 NCO:1</reactants>
<products>N2:1 CO2:1</products>
</reaction>
<!-- reaction 0230 -->
<reaction id="0230" reversible="yes" type="threeBody">
<equation>HCN + M [=] H + CN + M</equation>
<rateCoeff>
<Arrhenius>
<A> 1.040000E+26</A>
<b>-3.2999999999999998</b>
<E units="cal/mol">126600.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
</rateCoeff>
<reactants>HCN:1</reactants>
<products>H:1 CN:1</products>
</reaction>
<!-- reaction 0231 -->
<reaction id="0231" reversible="yes">
<equation>HCN + O [=] NCO + H</equation>
<rateCoeff>
<Arrhenius>
<A> 2.030000E+01</A>
<b>2.6400000000000001</b>
<E units="cal/mol">4980.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HCN:1 O:1</reactants>
<products>H:1 NCO:1</products>
</reaction>
<!-- reaction 0232 -->
<reaction id="0232" reversible="yes">
<equation>HCN + O [=] NH + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 5.070000E+00</A>
<b>2.6400000000000001</b>
<E units="cal/mol">4980.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HCN:1 O:1</reactants>
<products>NH:1 CO:1</products>
</reaction>
<!-- reaction 0233 -->
<reaction id="0233" reversible="yes">
<equation>HCN + O [=] CN + OH</equation>
<rateCoeff>
<Arrhenius>
<A> 3.910000E+06</A>
<b>1.5800000000000001</b>
<E units="cal/mol">26600.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HCN:1 O:1</reactants>
<products>CN:1 OH:1</products>
</reaction>
<!-- reaction 0234 -->
<reaction id="0234" reversible="yes">
<equation>HCN + OH [=] HOCN + H</equation>
<rateCoeff>
<Arrhenius>
<A> 1.100000E+03</A>
<b>2.0299999999999998</b>
<E units="cal/mol">13370.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HCN:1 OH:1</reactants>
<products>HOCN:1 H:1</products>
</reaction>
<!-- reaction 0235 -->
<reaction id="0235" reversible="yes">
<equation>HCN + OH [=] HNCO + H</equation>
<rateCoeff>
<Arrhenius>
<A> 4.400000E+00</A>
<b>2.2599999999999998</b>
<E units="cal/mol">6400.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HCN:1 OH:1</reactants>
<products>HNCO:1 H:1</products>
</reaction>
<!-- reaction 0236 -->
<reaction id="0236" reversible="yes">
<equation>HCN + OH [=] NH2 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.600000E-01</A>
<b>2.5600000000000001</b>
<E units="cal/mol">9000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HCN:1 OH:1</reactants>
<products>CO:1 NH2:1</products>
</reaction>
<!-- reaction 0237 -->
<reaction id="0237" reversible="yes" type="falloff">
<equation>H + HCN (+ M) [=] H2CN (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 3.300000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 1.400000E+20</A>
<b>-3.3999999999999999</b>
<E units="cal/mol">1900.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Lindemann"/>
</rateCoeff>
<reactants>H:1 HCN:1</reactants>
<products>H2CN:1</products>
</reaction>
<!-- reaction 0238 -->
<reaction id="0238" reversible="yes">
<equation>H2CN + N [=] N2 + CH2</equation>
<rateCoeff>
<Arrhenius>
<A> 6.000000E+10</A>
<b>0</b>
<E units="cal/mol">400.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H2CN:1 N:1</reactants>
<products>N2:1 CH2:1</products>
</reaction>
<!-- reaction 0239 -->
<reaction id="0239" reversible="yes">
<equation>C + N2 [=] CN + N</equation>
<rateCoeff>
<Arrhenius>
<A> 6.300000E+10</A>
<b>0</b>
<E units="cal/mol">46020.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C:1 N2:1</reactants>
<products>CN:1 N:1</products>
</reaction>
<!-- reaction 0240 -->
<reaction id="0240" reversible="yes">
<equation>CH + N2 [=] HCN + N</equation>
<rateCoeff>
<Arrhenius>
<A> 3.120000E+06</A>
<b>0.88</b>
<E units="cal/mol">20130.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>N2:1 CH:1</reactants>
<products>HCN:1 N:1</products>
</reaction>
<!-- reaction 0241 -->
<reaction id="0241" reversible="yes" type="falloff">
<equation>CH + N2 (+ M) [=] HCNN (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 3.100000E+09</A>
<b>0.14999999999999999</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 1.300000E+19</A>
<b>-3.1600000000000001</b>
<E units="cal/mol">740.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:1 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.667 235 2117 4536 </falloff>
</rateCoeff>
<reactants>N2:1 CH:1</reactants>
<products>HCNN:1</products>
</reaction>
<!-- reaction 0242 -->
<reaction id="0242" reversible="yes">
<equation>CH2 + N2 [=] HCN + NH</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+10</A>
<b>0</b>
<E units="cal/mol">74000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:1 N2:1</reactants>
<products>NH:1 HCN:1</products>
</reaction>
<!-- reaction 0243 -->
<reaction id="0243" reversible="yes">
<equation>CH2(S) + N2 [=] NH + HCN</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+08</A>
<b>0</b>
<E units="cal/mol">65000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 N2:1</reactants>
<products>NH:1 HCN:1</products>
</reaction>
<!-- reaction 0244 -->
<reaction id="0244" reversible="yes">
<equation>C + NO [=] CN + O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.900000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C:1 NO:1</reactants>
<products>CN:1 O:1</products>
</reaction>
<!-- reaction 0245 -->
<reaction id="0245" reversible="yes">
<equation>C + NO [=] CO + N</equation>
<rateCoeff>
<Arrhenius>
<A> 2.900000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C:1 NO:1</reactants>
<products>CO:1 N:1</products>
</reaction>
<!-- reaction 0246 -->
<reaction id="0246" reversible="yes">
<equation>CH + NO [=] HCN + O</equation>
<rateCoeff>
<Arrhenius>
<A> 4.100000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH:1 NO:1</reactants>
<products>HCN:1 O:1</products>
</reaction>
<!-- reaction 0247 -->
<reaction id="0247" reversible="yes">
<equation>CH + NO [=] H + NCO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.620000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH:1 NO:1</reactants>
<products>H:1 NCO:1</products>
</reaction>
<!-- reaction 0248 -->
<reaction id="0248" reversible="yes">
<equation>CH + NO [=] N + HCO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.460000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH:1 NO:1</reactants>
<products>HCO:1 N:1</products>
</reaction>
<!-- reaction 0249 -->
<reaction id="0249" reversible="yes">
<equation>CH2 + NO [=] H + HNCO</equation>
<rateCoeff>
<Arrhenius>
<A> 3.100000E+14</A>
<b>-1.3799999999999999</b>
<E units="cal/mol">1270.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:1 NO:1</reactants>
<products>HNCO:1 H:1</products>
</reaction>
<!-- reaction 0250 -->
<reaction id="0250" reversible="yes">
<equation>CH2 + NO [=] OH + HCN</equation>
<rateCoeff>
<Arrhenius>
<A> 2.900000E+11</A>
<b>-0.68999999999999995</b>
<E units="cal/mol">760.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:1 NO:1</reactants>
<products>HCN:1 OH:1</products>
</reaction>
<!-- reaction 0251 -->
<reaction id="0251" reversible="yes">
<equation>CH2 + NO [=] H + HCNO</equation>
<rateCoeff>
<Arrhenius>
<A> 3.800000E+10</A>
<b>-0.35999999999999999</b>
<E units="cal/mol">580.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:1 NO:1</reactants>
<products>H:1 HCNO:1</products>
</reaction>
<!-- reaction 0252 -->
<reaction id="0252" reversible="yes">
<equation>CH2(S) + NO [=] H + HNCO</equation>
<rateCoeff>
<Arrhenius>
<A> 3.100000E+14</A>
<b>-1.3799999999999999</b>
<E units="cal/mol">1270.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 NO:1</reactants>
<products>HNCO:1 H:1</products>
</reaction>
<!-- reaction 0253 -->
<reaction id="0253" reversible="yes">
<equation>CH2(S) + NO [=] OH + HCN</equation>
<rateCoeff>
<Arrhenius>
<A> 2.900000E+11</A>
<b>-0.68999999999999995</b>
<E units="cal/mol">760.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 NO:1</reactants>
<products>HCN:1 OH:1</products>
</reaction>
<!-- reaction 0254 -->
<reaction id="0254" reversible="yes">
<equation>CH2(S) + NO [=] H + HCNO</equation>
<rateCoeff>
<Arrhenius>
<A> 3.800000E+10</A>
<b>-0.35999999999999999</b>
<E units="cal/mol">580.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 NO:1</reactants>
<products>H:1 HCNO:1</products>
</reaction>
<!-- reaction 0255 -->
<reaction id="0255" reversible="yes">
<equation>CH3 + NO [=] HCN + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 9.600000E+10</A>
<b>0</b>
<E units="cal/mol">28800.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 NO:1</reactants>
<products>H2O:1 HCN:1</products>
</reaction>
<!-- reaction 0256 -->
<reaction id="0256" reversible="yes">
<equation>CH3 + NO [=] H2CN + OH</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+09</A>
<b>0</b>
<E units="cal/mol">21750.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 NO:1</reactants>
<products>H2CN:1 OH:1</products>
</reaction>
<!-- reaction 0257 -->
<reaction id="0257" reversible="yes">
<equation>HCNN + O [=] CO + H + N2</equation>
<rateCoeff>
<Arrhenius>
<A> 2.200000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>O:1 HCNN:1</reactants>
<products>H:1 N2:1 CO:1</products>
</reaction>
<!-- reaction 0258 -->
<reaction id="0258" reversible="yes">
<equation>HCNN + O [=] HCN + NO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+09</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>O:1 HCNN:1</reactants>
<products>HCN:1 NO:1</products>
</reaction>
<!-- reaction 0259 -->
<reaction id="0259" reversible="yes">
<equation>HCNN + O2 [=] O + HCO + N2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.200000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>O2:1 HCNN:1</reactants>
<products>N2:1 HCO:1 O:1</products>
</reaction>
<!-- reaction 0260 -->
<reaction id="0260" reversible="yes">
<equation>HCNN + OH [=] H + HCO + N2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.200000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>OH:1 HCNN:1</reactants>
<products>H:1 N2:1 HCO:1</products>
</reaction>
<!-- reaction 0261 -->
<reaction id="0261" reversible="yes">
<equation>HCNN + H [=] CH2 + N2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+11</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 HCNN:1</reactants>
<products>CH2:1 N2:1</products>
</reaction>
<!-- reaction 0262 -->
<reaction id="0262" reversible="yes">
<equation>HNCO + O [=] NH + CO2</equation>
<rateCoeff>
<Arrhenius>
<A> 9.800000E+04</A>
<b>1.4099999999999999</b>
<E units="cal/mol">8500.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HNCO:1 O:1</reactants>
<products>NH:1 CO2:1</products>
</reaction>
<!-- reaction 0263 -->
<reaction id="0263" reversible="yes">
<equation>HNCO + O [=] HNO + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.500000E+05</A>
<b>1.5700000000000001</b>
<E units="cal/mol">44000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HNCO:1 O:1</reactants>
<products>CO:1 HNO:1</products>
</reaction>
<!-- reaction 0264 -->
<reaction id="0264" reversible="yes">
<equation>HNCO + O [=] NCO + OH</equation>
<rateCoeff>
<Arrhenius>
<A> 2.200000E+03</A>
<b>2.1099999999999999</b>
<E units="cal/mol">11400.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HNCO:1 O:1</reactants>
<products>OH:1 NCO:1</products>
</reaction>
<!-- reaction 0265 -->
<reaction id="0265" reversible="yes">
<equation>HNCO + H [=] NH2 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.250000E+04</A>
<b>1.7</b>
<E units="cal/mol">3800.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HNCO:1 H:1</reactants>
<products>CO:1 NH2:1</products>
</reaction>
<!-- reaction 0266 -->
<reaction id="0266" reversible="yes">
<equation>HNCO + H [=] H2 + NCO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.050000E+02</A>
<b>2.5</b>
<E units="cal/mol">13300.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HNCO:1 H:1</reactants>
<products>H2:1 NCO:1</products>
</reaction>
<!-- reaction 0267 -->
<reaction id="0267" reversible="yes">
<equation>HNCO + OH [=] NCO + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 3.300000E+04</A>
<b>1.5</b>
<E units="cal/mol">3600.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HNCO:1 OH:1</reactants>
<products>H2O:1 NCO:1</products>
</reaction>
<!-- reaction 0268 -->
<reaction id="0268" reversible="yes">
<equation>HNCO + OH [=] NH2 + CO2</equation>
<rateCoeff>
<Arrhenius>
<A> 3.300000E+03</A>
<b>1.5</b>
<E units="cal/mol">3600.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HNCO:1 OH:1</reactants>
<products>CO2:1 NH2:1</products>
</reaction>
<!-- reaction 0269 -->
<reaction id="0269" reversible="yes" type="threeBody">
<equation>HNCO + M [=] NH + CO + M</equation>
<rateCoeff>
<Arrhenius>
<A> 1.180000E+13</A>
<b>0</b>
<E units="cal/mol">84720.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
</rateCoeff>
<reactants>HNCO:1</reactants>
<products>NH:1 CO:1</products>
</reaction>
<!-- reaction 0270 -->
<reaction id="0270" reversible="yes">
<equation>HCNO + H [=] H + HNCO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.100000E+12</A>
<b>-0.68999999999999995</b>
<E units="cal/mol">2850.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 HCNO:1</reactants>
<products>HNCO:1 H:1</products>
</reaction>
<!-- reaction 0271 -->
<reaction id="0271" reversible="yes">
<equation>HCNO + H [=] OH + HCN</equation>
<rateCoeff>
<Arrhenius>
<A> 2.700000E+08</A>
<b>0.17999999999999999</b>
<E units="cal/mol">2120.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 HCNO:1</reactants>
<products>HCN:1 OH:1</products>
</reaction>
<!-- reaction 0272 -->
<reaction id="0272" reversible="yes">
<equation>HCNO + H [=] NH2 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.700000E+11</A>
<b>-0.75</b>
<E units="cal/mol">2890.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 HCNO:1</reactants>
<products>CO:1 NH2:1</products>
</reaction>
<!-- reaction 0273 -->
<reaction id="0273" reversible="yes">
<equation>HOCN + H [=] H + HNCO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+04</A>
<b>2</b>
<E units="cal/mol">2000.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HOCN:1 H:1</reactants>
<products>HNCO:1 H:1</products>
</reaction>
<!-- reaction 0274 -->
<reaction id="0274" reversible="yes">
<equation>HCCO + NO [=] HCNO + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 9.000000E+09</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HCCO:1 NO:1</reactants>
<products>CO:1 HCNO:1</products>
</reaction>
<!-- reaction 0275 -->
<reaction id="0275" reversible="yes">
<equation>CH3 + N [=] H2CN + H</equation>
<rateCoeff>
<Arrhenius>
<A> 6.100000E+11</A>
<b>-0.31</b>
<E units="cal/mol">290.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 N:1</reactants>
<products>H:1 H2CN:1</products>
</reaction>
<!-- reaction 0276 -->
<reaction id="0276" reversible="yes">
<equation>CH3 + N [=] HCN + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 3.700000E+09</A>
<b>0.14999999999999999</b>
<E units="cal/mol">-90.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 N:1</reactants>
<products>H2:1 HCN:1</products>
</reaction>
<!-- reaction 0277 -->
<reaction id="0277" reversible="yes">
<equation>NH3 + H [=] NH2 + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 5.400000E+02</A>
<b>2.3999999999999999</b>
<E units="cal/mol">9915.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 NH3:1</reactants>
<products>H2:1 NH2:1</products>
</reaction>
<!-- reaction 0278 -->
<reaction id="0278" reversible="yes">
<equation>NH3 + OH [=] NH2 + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+04</A>
<b>1.6000000000000001</b>
<E units="cal/mol">955.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NH3:1 OH:1</reactants>
<products>H2O:1 NH2:1</products>
</reaction>
<!-- reaction 0279 -->
<reaction id="0279" reversible="yes">
<equation>NH3 + O [=] NH2 + OH</equation>
<rateCoeff>
<Arrhenius>
<A> 9.400000E+03</A>
<b>1.9399999999999999</b>
<E units="cal/mol">6460.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>O:1 NH3:1</reactants>
<products>OH:1 NH2:1</products>
</reaction>
<!-- reaction 0280 -->
<reaction id="0280" reversible="yes">
<equation>NH + CO2 [=] HNO + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.000000E+10</A>
<b>0</b>
<E units="cal/mol">14350.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NH:1 CO2:1</reactants>
<products>CO:1 HNO:1</products>
</reaction>
<!-- reaction 0281 -->
<reaction id="0281" reversible="yes">
<equation>CN + NO2 [=] NCO + NO</equation>
<rateCoeff>
<Arrhenius>
<A> 6.160000E+12</A>
<b>-0.752</b>
<E units="cal/mol">345.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CN:1 NO2:1</reactants>
<products>NO:1 NCO:1</products>
</reaction>
<!-- reaction 0282 -->
<reaction id="0282" reversible="yes">
<equation>NCO + NO2 [=] N2O + CO2</equation>
<rateCoeff>
<Arrhenius>
<A> 3.250000E+09</A>
<b>0</b>
<E units="cal/mol">-705.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>NO2:1 NCO:1</reactants>
<products>CO2:1 N2O:1</products>
</reaction>
<!-- reaction 0283 -->
<reaction id="0283" reversible="yes">
<equation>N + CO2 [=] NO + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 3.000000E+09</A>
<b>0</b>
<E units="cal/mol">11300.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CO2:1 N:1</reactants>
<products>CO:1 NO:1</products>
</reaction>
<!-- reaction 0284 -->
<reaction id="0284" reversible="no">
<equation>O + CH3 =] H + H2 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 3.370000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 O:1</reactants>
<products>H2:1 H:1 CO:1</products>
</reaction>
<!-- reaction 0285 -->
<reaction id="0285" reversible="yes">
<equation>O + C2H4 [=] H + CH2CHO</equation>
<rateCoeff>
<Arrhenius>
<A> 6.700000E+03</A>
<b>1.8300000000000001</b>
<E units="cal/mol">220.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H4:1 O:1</reactants>
<products>H:1 CH2CHO:1</products>
</reaction>
<!-- reaction 0286 -->
<reaction id="0286" reversible="yes">
<equation>O + C2H5 [=] H + CH3CHO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.096000E+11</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H5:1 O:1</reactants>
<products>H:1 CH3CHO:1</products>
</reaction>
<!-- reaction 0287 -->
<reaction duplicate="yes" id="0287" reversible="yes">
<equation>OH + HO2 [=] O2 + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 5.000000E+12</A>
<b>0</b>
<E units="cal/mol">17330.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>HO2:1 OH:1</reactants>
<products>H2O:1 O2:1</products>
</reaction>
<!-- reaction 0288 -->
<reaction id="0288" reversible="no">
<equation>OH + CH3 =] H2 + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 8.000000E+06</A>
<b>0.5</b>
<E units="cal/mol">-1755.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 OH:1</reactants>
<products>H2:1 CH2O:1</products>
</reaction>
<!-- reaction 0289 -->
<reaction id="0289" reversible="yes" type="falloff">
<equation>CH + H2 (+ M) [=] CH3 (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 1.970000E+09</A>
<b>0.42999999999999999</b>
<E units="cal/mol">-370.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 4.820000E+19</A>
<b>-2.7999999999999998</b>
<E units="cal/mol">590.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.578 122 2535 9365 </falloff>
</rateCoeff>
<reactants>H2:1 CH:1</reactants>
<products>CH3:1</products>
</reaction>
<!-- reaction 0290 -->
<reaction id="0290" reversible="no">
<equation>CH2 + O2 =] 2 H + CO2</equation>
<rateCoeff>
<Arrhenius>
<A> 5.800000E+09</A>
<b>0</b>
<E units="cal/mol">1500.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:1 O2:1</reactants>
<products>H:2 CO2:1</products>
</reaction>
<!-- reaction 0291 -->
<reaction id="0291" reversible="yes">
<equation>CH2 + O2 [=] O + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 2.400000E+09</A>
<b>0</b>
<E units="cal/mol">1500.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:1 O2:1</reactants>
<products>CH2O:1 O:1</products>
</reaction>
<!-- reaction 0292 -->
<reaction id="0292" reversible="no">
<equation>CH2 + CH2 =] 2 H + C2H2</equation>
<rateCoeff>
<Arrhenius>
<A> 2.000000E+11</A>
<b>0</b>
<E units="cal/mol">10989.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2:2</reactants>
<products>H:2 C2H2:1</products>
</reaction>
<!-- reaction 0293 -->
<reaction id="0293" reversible="no">
<equation>CH2(S) + H2O =] H2 + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 6.820000E+07</A>
<b>0.25</b>
<E units="cal/mol">-935.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2(S):1 H2O:1</reactants>
<products>H2:1 CH2O:1</products>
</reaction>
<!-- reaction 0294 -->
<reaction id="0294" reversible="yes">
<equation>C2H3 + O2 [=] O + CH2CHO</equation>
<rateCoeff>
<Arrhenius>
<A> 3.030000E+08</A>
<b>0.28999999999999998</b>
<E units="cal/mol">11.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H3:1 O2:1</reactants>
<products>CH2CHO:1 O:1</products>
</reaction>
<!-- reaction 0295 -->
<reaction id="0295" reversible="yes">
<equation>C2H3 + O2 [=] HO2 + C2H2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.337000E+03</A>
<b>1.6100000000000001</b>
<E units="cal/mol">-384.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C2H3:1 O2:1</reactants>
<products>HO2:1 C2H2:1</products>
</reaction>
<!-- reaction 0296 -->
<reaction id="0296" reversible="yes">
<equation>O + CH3CHO [=] OH + CH2CHO</equation>
<rateCoeff>
<Arrhenius>
<A> 5.840000E+09</A>
<b>0</b>
<E units="cal/mol">1808.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3CHO:1 O:1</reactants>
<products>CH2CHO:1 OH:1</products>
</reaction>
<!-- reaction 0297 -->
<reaction id="0297" reversible="no">
<equation>O + CH3CHO =] OH + CH3 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 5.840000E+09</A>
<b>0</b>
<E units="cal/mol">1808.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3CHO:1 O:1</reactants>
<products>CH3:1 CO:1 OH:1</products>
</reaction>
<!-- reaction 0298 -->
<reaction id="0298" reversible="no">
<equation>O2 + CH3CHO =] HO2 + CH3 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 3.010000E+10</A>
<b>0</b>
<E units="cal/mol">39150.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3CHO:1 O2:1</reactants>
<products>CO:1 CH3:1 HO2:1</products>
</reaction>
<!-- reaction 0299 -->
<reaction id="0299" reversible="yes">
<equation>H + CH3CHO [=] CH2CHO + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 2.050000E+06</A>
<b>1.1599999999999999</b>
<E units="cal/mol">2405.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 CH3CHO:1</reactants>
<products>H2:1 CH2CHO:1</products>
</reaction>
<!-- reaction 0300 -->
<reaction id="0300" reversible="no">
<equation>H + CH3CHO =] CH3 + H2 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.050000E+06</A>
<b>1.1599999999999999</b>
<E units="cal/mol">2405.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 CH3CHO:1</reactants>
<products>H2:1 CH3:1 CO:1</products>
</reaction>
<!-- reaction 0301 -->
<reaction id="0301" reversible="no">
<equation>OH + CH3CHO =] CH3 + H2O + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.343000E+07</A>
<b>0.72999999999999998</b>
<E units="cal/mol">-1113.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3CHO:1 OH:1</reactants>
<products>H2O:1 CH3:1 CO:1</products>
</reaction>
<!-- reaction 0302 -->
<reaction id="0302" reversible="no">
<equation>HO2 + CH3CHO =] CH3 + H2O2 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 3.010000E+09</A>
<b>0</b>
<E units="cal/mol">11923.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3CHO:1 HO2:1</reactants>
<products>CH3:1 CO:1 H2O2:1</products>
</reaction>
<!-- reaction 0303 -->
<reaction id="0303" reversible="no">
<equation>CH3 + CH3CHO =] CH3 + CH4 + CO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.720000E+03</A>
<b>1.77</b>
<E units="cal/mol">5920.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3CHO:1 CH3:1</reactants>
<products>CO:1 CH3:1 CH4:1</products>
</reaction>
<!-- reaction 0304 -->
<reaction id="0304" reversible="yes" type="falloff">
<equation>H + CH2CO (+ M) [=] CH2CHO (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 4.865000E+08</A>
<b>0.42199999999999999</b>
<E units="cal/mol">-1755.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 1.012000E+36</A>
<b>-7.6299999999999999</b>
<E units="cal/mol">3854.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.465 201 1773 5333 </falloff>
</rateCoeff>
<reactants>H:1 CH2CO:1</reactants>
<products>CH2CHO:1</products>
</reaction>
<!-- reaction 0305 -->
<reaction id="0305" reversible="no">
<equation>O + CH2CHO =] H + CH2 + CO2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.500000E+11</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2CHO:1 O:1</reactants>
<products>H:1 CH2:1 CO2:1</products>
</reaction>
<!-- reaction 0306 -->
<reaction id="0306" reversible="no">
<equation>O2 + CH2CHO =] OH + CO + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 1.810000E+07</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2CHO:1 O2:1</reactants>
<products>CH2O:1 CO:1 OH:1</products>
</reaction>
<!-- reaction 0307 -->
<reaction id="0307" reversible="no">
<equation>O2 + CH2CHO =] OH + 2 HCO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.350000E+07</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2CHO:1 O2:1</reactants>
<products>HCO:2 OH:1</products>
</reaction>
<!-- reaction 0308 -->
<reaction id="0308" reversible="yes">
<equation>H + CH2CHO [=] CH3 + HCO</equation>
<rateCoeff>
<Arrhenius>
<A> 2.200000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 CH2CHO:1</reactants>
<products>CH3:1 HCO:1</products>
</reaction>
<!-- reaction 0309 -->
<reaction id="0309" reversible="yes">
<equation>H + CH2CHO [=] CH2CO + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.100000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 CH2CHO:1</reactants>
<products>H2:1 CH2CO:1</products>
</reaction>
<!-- reaction 0310 -->
<reaction id="0310" reversible="yes">
<equation>OH + CH2CHO [=] H2O + CH2CO</equation>
<rateCoeff>
<Arrhenius>
<A> 1.200000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2CHO:1 OH:1</reactants>
<products>H2O:1 CH2CO:1</products>
</reaction>
<!-- reaction 0311 -->
<reaction id="0311" reversible="yes">
<equation>OH + CH2CHO [=] HCO + CH2OH</equation>
<rateCoeff>
<Arrhenius>
<A> 3.010000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH2CHO:1 OH:1</reactants>
<products>CH2OH:1 HCO:1</products>
</reaction>
<!-- reaction 0312 -->
<reaction id="0312" reversible="yes" type="falloff">
<equation>CH3 + C2H5 (+ M) [=] C3H8 (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 9.430000E+09</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 2.710000E+68</A>
<b>-16.82</b>
<E units="cal/mol">13065.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.1527 291 2742 7748 </falloff>
</rateCoeff>
<reactants>C2H5:1 CH3:1</reactants>
<products>C3H8:1</products>
</reaction>
<!-- reaction 0313 -->
<reaction id="0313" reversible="yes">
<equation>O + C3H8 [=] OH + C3H7</equation>
<rateCoeff>
<Arrhenius>
<A> 1.930000E+02</A>
<b>2.6800000000000002</b>
<E units="cal/mol">3716.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C3H8:1 O:1</reactants>
<products>C3H7:1 OH:1</products>
</reaction>
<!-- reaction 0314 -->
<reaction id="0314" reversible="yes">
<equation>H + C3H8 [=] C3H7 + H2</equation>
<rateCoeff>
<Arrhenius>
<A> 1.320000E+03</A>
<b>2.54</b>
<E units="cal/mol">6756.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 C3H8:1</reactants>
<products>H2:1 C3H7:1</products>
</reaction>
<!-- reaction 0315 -->
<reaction id="0315" reversible="yes">
<equation>OH + C3H8 [=] C3H7 + H2O</equation>
<rateCoeff>
<Arrhenius>
<A> 3.160000E+04</A>
<b>1.8</b>
<E units="cal/mol">934.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C3H8:1 OH:1</reactants>
<products>C3H7:1 H2O:1</products>
</reaction>
<!-- reaction 0316 -->
<reaction id="0316" reversible="yes">
<equation>C3H7 + H2O2 [=] HO2 + C3H8</equation>
<rateCoeff>
<Arrhenius>
<A> 3.780000E-01</A>
<b>2.7200000000000002</b>
<E units="cal/mol">1500.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C3H7:1 H2O2:1</reactants>
<products>HO2:1 C3H8:1</products>
</reaction>
<!-- reaction 0317 -->
<reaction id="0317" reversible="yes">
<equation>CH3 + C3H8 [=] C3H7 + CH4</equation>
<rateCoeff>
<Arrhenius>
<A> 9.030000E-04</A>
<b>3.6499999999999999</b>
<E units="cal/mol">7154.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>CH3:1 C3H8:1</reactants>
<products>C3H7:1 CH4:1</products>
</reaction>
<!-- reaction 0318 -->
<reaction id="0318" reversible="yes" type="falloff">
<equation>CH3 + C2H4 (+ M) [=] C3H7 (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 2.550000E+03</A>
<b>1.6000000000000001</b>
<E units="cal/mol">5700.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 3.000000E+57</A>
<b>-14.6</b>
<E units="cal/mol">18170.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.1894 277 8748 7891 </falloff>
</rateCoeff>
<reactants>CH3:1 C2H4:1</reactants>
<products>C3H7:1</products>
</reaction>
<!-- reaction 0319 -->
<reaction id="0319" reversible="yes">
<equation>O + C3H7 [=] C2H5 + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 9.640000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C3H7:1 O:1</reactants>
<products>CH2O:1 C2H5:1</products>
</reaction>
<!-- reaction 0320 -->
<reaction id="0320" reversible="yes" type="falloff">
<equation>H + C3H7 (+ M) [=] C3H8 (+ M)</equation>
<rateCoeff>
<Arrhenius>
<A> 3.613000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
<Arrhenius name="k0">
<A> 4.420000E+55</A>
<b>-13.545</b>
<E units="cal/mol">11357.000000</E>
</Arrhenius>
<efficiencies default="1.0"> AR:0.7 C2H6:3 CH4:2 CO:1.5 CO2:2 H2:2 H2O:6 </efficiencies>
<falloff type="Troe">0.315 369 3285 6667 </falloff>
</rateCoeff>
<reactants>H:1 C3H7:1</reactants>
<products>C3H8:1</products>
</reaction>
<!-- reaction 0321 -->
<reaction id="0321" reversible="yes">
<equation>H + C3H7 [=] CH3 + C2H5</equation>
<rateCoeff>
<Arrhenius>
<A> 4.060000E+03</A>
<b>2.1899999999999999</b>
<E units="cal/mol">890.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>H:1 C3H7:1</reactants>
<products>C2H5:1 CH3:1</products>
</reaction>
<!-- reaction 0322 -->
<reaction id="0322" reversible="yes">
<equation>OH + C3H7 [=] C2H5 + CH2OH</equation>
<rateCoeff>
<Arrhenius>
<A> 2.410000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C3H7:1 OH:1</reactants>
<products>CH2OH:1 C2H5:1</products>
</reaction>
<!-- reaction 0323 -->
<reaction id="0323" reversible="yes">
<equation>HO2 + C3H7 [=] O2 + C3H8</equation>
<rateCoeff>
<Arrhenius>
<A> 2.550000E+07</A>
<b>0.255</b>
<E units="cal/mol">-943.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C3H7:1 HO2:1</reactants>
<products>O2:1 C3H8:1</products>
</reaction>
<!-- reaction 0324 -->
<reaction id="0324" reversible="no">
<equation>HO2 + C3H7 =] OH + C2H5 + CH2O</equation>
<rateCoeff>
<Arrhenius>
<A> 2.410000E+10</A>
<b>0</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C3H7:1 HO2:1</reactants>
<products>CH2O:1 C2H5:1 OH:1</products>
</reaction>
<!-- reaction 0325 -->
<reaction id="0325" reversible="yes">
<equation>CH3 + C3H7 [=] 2 C2H5</equation>
<rateCoeff>
<Arrhenius>
<A> 1.927000E+10</A>
<b>-0.32000000000000001</b>
<E units="cal/mol">0.000000</E>
</Arrhenius>
</rateCoeff>
<reactants>C3H7:1 CH3:1</reactants>
<products>C2H5:2</products>
</reaction>
</reactionData>
</ctml>
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