cantera/interfaces/cython/cantera/test/test_reactor.py

1359 lines
45 KiB
Python

import math
import re
import numpy as np
from .utilities import unittest
import cantera as ct
from . import utilities
class TestReactor(utilities.CanteraTest):
reactorClass = ct.Reactor
def make_reactors(self, independent=True, n_reactors=2,
T1=300, P1=101325, X1='O2:1.0',
T2=300, P2=101325, X2='O2:1.0'):
self.net = ct.ReactorNet()
self.gas1 = ct.Solution('h2o2.xml')
self.gas1.TPX = T1, P1, X1
self.r1 = self.reactorClass(self.gas1)
self.net.add_reactor(self.r1)
if independent:
self.gas2 = ct.Solution('h2o2.xml')
else:
self.gas2 = self.gas1
if n_reactors >= 2:
self.gas2.TPX = T2, P2, X2
self.r2 = self.reactorClass(self.gas2)
self.net.add_reactor(self.r2)
def add_wall(self, **kwargs):
self.w = ct.Wall(self.r1, self.r2, **kwargs)
return self.w
def test_verbose(self):
self.make_reactors(independent=False, n_reactors=1)
self.assertFalse(self.net.verbose)
self.net.verbose = True
self.assertTrue(self.net.verbose)
def test_insert(self):
R = self.reactorClass()
with self.assertRaises(Exception):
R.T
with self.assertRaises(Exception):
R.kinetics.net_production_rates
g = ct.Solution('h2o2.xml')
g.TP = 300, 101325
R.insert(g)
self.assertNear(R.T, 300)
self.assertEqual(len(R.kinetics.net_production_rates), g.n_species)
def test_volume(self):
R = self.reactorClass(volume=11)
self.assertEqual(R.volume, 11)
R.volume = 9
self.assertEqual(R.volume, 9)
def test_names(self):
self.make_reactors()
pattern = re.compile(r'(\d+)')
digits1 = pattern.search(self.r1.name).group(0)
digits2 = pattern.search(self.r2.name).group(0)
self.assertEqual(int(digits2), int(digits1) + 1)
self.r1.name = 'hello'
self.assertEqual(self.r1.name, 'hello')
def test_component_index(self):
self.make_reactors(n_reactors=1)
self.net.step()
N0 = self.net.n_vars - self.gas1.n_species
for i, name in enumerate(self.gas1.species_names):
self.assertEqual(i + N0, self.r1.component_index(name))
def test_disjoint(self):
T1, P1 = 300, 101325
T2, P2 = 500, 300000
self.make_reactors(T1=T1, T2=T2, P1=P1, P2=P2)
self.net.advance(1.0)
# Nothing should change from the initial condition
self.assertNear(T1, self.gas1.T)
self.assertNear(T2, self.gas2.T)
self.assertNear(P1, self.gas1.P)
self.assertNear(P2, self.gas2.P)
def test_disjoint2(self):
T1, P1 = 300, 101325
T2, P2 = 500, 300000
self.make_reactors(T1=T1, T2=T2, P1=P1, P2=P2, independent=False)
self.net.advance(1.0)
# Nothing should change from the initial condition
self.assertNear(T1, self.r1.T)
self.assertNear(T2, self.r2.T)
self.assertNear(P1, self.r1.thermo.P)
self.assertNear(P2, self.r2.thermo.P)
def test_timestepping(self):
self.make_reactors()
tStart = 0.3
tEnd = 10.0
dt_max = 0.07
t = tStart
self.net.set_max_time_step(dt_max)
self.net.set_initial_time(tStart)
self.assertNear(self.net.time, tStart)
while t < tEnd:
tPrev = t
t = self.net.step()
self.assertTrue(t - tPrev <= 1.0001 * dt_max)
self.assertNear(t, self.net.time)
#self.assertNear(self.net.time, tEnd)
def test_equalize_pressure(self):
self.make_reactors(P1=101325, P2=300000)
self.add_wall(K=0.1, A=1.0)
self.assertEqual(len(self.r1.walls), 1)
self.assertEqual(len(self.r2.walls), 1)
self.assertEqual(self.r1.walls[0], self.w)
self.assertEqual(self.r2.walls[0], self.w)
self.net.advance(1.0)
self.assertNear(self.net.time, 1.0)
self.assertNear(self.gas1.P, self.gas2.P)
self.assertNotAlmostEqual(self.r1.T, self.r2.T)
def test_tolerances(self):
def integrate(atol, rtol):
P0 = 10 * ct.one_atm
T0 = 1100
X0 = 'H2:1.0, O2:0.5, AR:8.0'
self.make_reactors(n_reactors=1, T1=T0, P1=P0, X1=X0)
self.net.rtol = rtol
self.net.atol = atol
self.assertEqual(self.net.rtol, rtol)
self.assertEqual(self.net.atol, atol)
tEnd = 1.0
nSteps = 0
t = 0
while t < tEnd:
t = self.net.step()
nSteps += 1
return nSteps
n_baseline = integrate(1e-10, 1e-20)
n_rtol = integrate(5e-7, 1e-20)
n_atol = integrate(1e-10, 1e-6)
self.assertTrue(n_baseline > n_rtol)
self.assertTrue(n_baseline > n_atol)
def test_heat_transfer1(self):
# Connected reactors reach thermal equilibrium after some time
self.make_reactors(T1=300, T2=1000)
self.add_wall(U=500, A=1.0)
self.net.advance(10.0)
self.assertNear(self.net.time, 10.0)
self.assertNear(self.r1.T, self.r2.T, 5e-7)
self.assertNotAlmostEqual(self.r1.thermo.P, self.r2.thermo.P)
def test_heat_transfer2(self):
# Result should be the same if (m * cp) / (U * A) is held constant
self.make_reactors(T1=300, T2=1000)
self.add_wall(U=200, A=1.0)
self.net.advance(1.0)
T1a = self.r1.T
T2a = self.r2.T
self.make_reactors(T1=300, T2=1000)
self.r1.volume = 0.25
self.r2.volume = 0.25
w = self.add_wall(U=100, A=0.5)
self.assertNear(w.heat_transfer_coeff * w.area * (self.r1.T - self.r2.T),
w.qdot(0))
self.net.advance(1.0)
self.assertNear(w.heat_transfer_coeff * w.area * (self.r1.T - self.r2.T),
w.qdot(1.0))
T1b = self.r1.T
T2b = self.r2.T
self.assertNear(T1a, T1b)
self.assertNear(T2a, T2b)
def test_equilibrium_UV(self):
# Adiabatic, constant volume combustion should proceed to equilibrum
# at constant internal energy and volume.
P0 = 10 * ct.one_atm
T0 = 1100
X0 = 'H2:1.0, O2:0.5, AR:8.0'
self.make_reactors(n_reactors=1, T1=T0, P1=P0, X1=X0)
self.net.advance(1.0)
gas = ct.Solution('h2o2.xml')
gas.TPX = T0, P0, X0
gas.equilibrate('UV')
self.assertNear(self.r1.T, gas.T)
self.assertNear(self.r1.thermo.density, gas.density)
self.assertNear(self.r1.thermo.P, gas.P)
self.assertArrayNear(self.r1.thermo.X, gas.X)
def test_equilibrium_HP(self):
# Adiabatic, constant pressure combustion should proceed to equilibrum
# at constant enthalpy and pressure.
P0 = 10 * ct.one_atm
T0 = 1100
X0 = 'H2:1.0, O2:0.5, AR:8.0'
gas1 = ct.Solution('h2o2.xml')
gas1.TPX = T0, P0, X0
r1 = ct.IdealGasConstPressureReactor(gas1)
net = ct.ReactorNet()
net.add_reactor(r1)
net.advance(1.0)
gas2 = ct.Solution('h2o2.xml')
gas2.TPX = T0, P0, X0
gas2.equilibrate('HP')
self.assertNear(r1.T, gas2.T)
self.assertNear(r1.thermo.P, P0)
self.assertNear(r1.thermo.density, gas2.density)
self.assertArrayNear(r1.thermo.X, gas2.X)
def test_wall_velocity(self):
self.make_reactors()
A = 0.2
V1 = 2.0
V2 = 5.0
self.r1.volume = V1
self.r2.volume = V2
self.add_wall(A=A)
def v(t):
if 0 < t <= 1:
return t
elif 1 <= t <= 2:
return 2 - t
else:
return 0.0
self.w.set_velocity(v)
self.net.advance(1.0)
self.assertNear(self.w.vdot(1.0), 1.0 * A, 1e-7)
self.net.advance(2.0)
self.assertNear(self.w.vdot(2.0), 0.0, 1e-7)
self.assertNear(self.r1.volume, V1 + 1.0 * A, 1e-7)
self.assertNear(self.r2.volume, V2 - 1.0 * A, 1e-7)
def test_disable_energy(self):
self.make_reactors(T1=500)
self.r1.energy_enabled = False
self.add_wall(A=1.0, U=2500)
self.net.advance(11.0)
self.assertNear(self.r1.T, 500)
self.assertNear(self.r2.T, 500)
def test_heat_flux_func(self):
self.make_reactors(T1=500, T2=300)
self.r1.volume = 0.5
U1a = self.r1.volume * self.r1.density * self.r1.thermo.u
U2a = self.r2.volume * self.r2.density * self.r2.thermo.u
V1a = self.r1.volume
V2a = self.r2.volume
self.add_wall(A=0.3)
self.w.set_heat_flux(lambda t: 90000 * (1 - t**2) if t <= 1.0 else 0.0)
Q = 0.3 * 60000
self.net.advance(1.1)
U1b = self.r1.volume * self.r1.density * self.r1.thermo.u
U2b = self.r2.volume * self.r2.density * self.r2.thermo.u
self.assertNear(V1a, self.r1.volume)
self.assertNear(V2a, self.r2.volume)
self.assertNear(U1a - Q, U1b, 1e-6)
self.assertNear(U2a + Q, U2b, 1e-6)
def test_mass_flow_controller(self):
self.make_reactors(n_reactors=1)
gas2 = ct.Solution('h2o2.xml')
gas2.TPX = 300, 10*101325, 'H2:1.0'
reservoir = ct.Reservoir(gas2)
mfc = ct.MassFlowController(reservoir, self.r1)
mfc.set_mass_flow_rate(lambda t: 0.1 if 0.2 <= t < 1.2 else 0.0)
self.assertEqual(len(reservoir.inlets), 0)
self.assertEqual(len(reservoir.outlets), 1)
self.assertEqual(reservoir.outlets[0], mfc)
self.assertEqual(len(self.r1.outlets), 0)
self.assertEqual(len(self.r1.inlets), 1)
self.assertEqual(self.r1.inlets[0], mfc)
ma = self.r1.volume * self.r1.density
Ya = self.r1.Y
self.net.rtol = 1e-11
self.net.set_max_time_step(0.05)
self.net.advance(2.5)
mb = self.r1.volume * self.r1.density
Yb = self.r1.Y
self.assertNear(ma + 0.1, mb)
self.assertArrayNear(ma * Ya + 0.1 * gas2.Y, mb * Yb)
def test_valve1(self):
self.make_reactors(P1=10*ct.one_atm, X1='AR:1.0', X2='O2:1.0')
self.net.rtol = 1e-12
valve = ct.Valve(self.r1, self.r2)
k = 2e-5
valve.set_valve_coeff(k)
self.assertEqual(self.r1.outlets, self.r2.inlets)
self.assertTrue(self.r1.energy_enabled)
self.assertTrue(self.r2.energy_enabled)
self.assertNear((self.r1.thermo.P - self.r2.thermo.P) * k,
valve.mdot(0))
m1a = self.r1.thermo.density * self.r1.volume
m2a = self.r2.thermo.density * self.r2.volume
Y1a = self.r1.thermo.Y
Y2a = self.r2.thermo.Y
self.net.advance(0.1)
m1b = self.r1.thermo.density * self.r1.volume
m2b = self.r2.thermo.density * self.r2.volume
self.assertNear((self.r1.thermo.P - self.r2.thermo.P) * k,
valve.mdot(0.1))
self.assertNear(m1a+m2a, m1b+m2b)
Y1b = self.r1.thermo.Y
Y2b = self.r2.thermo.Y
self.assertArrayNear(m1a*Y1a + m2a*Y2a, m1b*Y1b + m2b*Y2b, atol=1e-10)
self.assertArrayNear(Y1a, Y1b)
def test_valve2(self):
# Similar to test_valve1, but by disabling the energy equation
# (constant T) we can compare with an analytical solution for
# the mass of each reactor as a function of time
self.make_reactors(P1=10*ct.one_atm)
self.net.rtol = 1e-11
self.r1.energy_enabled = False
self.r2.energy_enabled = False
valve = ct.Valve(self.r1, self.r2)
k = 2e-5
valve.set_valve_coeff(k)
self.assertFalse(self.r1.energy_enabled)
self.assertFalse(self.r2.energy_enabled)
m1a = self.r1.thermo.density * self.r1.volume
m2a = self.r2.thermo.density * self.r2.volume
P1a = self.r1.thermo.P
P2a = self.r2.thermo.P
Y1 = self.r1.Y
A = k * P1a * (1 + m2a/m1a)
B = k * (P1a/m1a + P2a/m2a)
for t in np.linspace(1e-5, 0.5):
self.net.advance(t)
m1 = self.r1.thermo.density * self.r1.volume
m2 = self.r2.thermo.density * self.r2.volume
self.assertNear(m2, (m2a - A/B) * np.exp(-B * t) + A/B)
self.assertNear(m1a+m2a, m1+m2)
self.assertArrayNear(self.r1.Y, Y1)
def test_valve3(self):
# This case specifies a non-linear relationship between pressure drop
# and flow rate.
self.make_reactors(P1=10*ct.one_atm, X1='AR:0.5, O2:0.5',
X2='O2:1.0')
self.net.rtol = 1e-12
self.net.atol = 1e-20
valve = ct.Valve(self.r1, self.r2)
mdot = lambda dP: 5e-3 * np.sqrt(dP) if dP > 0 else 0.0
valve.set_valve_coeff(mdot)
Y1 = self.r1.Y
kO2 = self.gas1.species_index('O2')
kAr = self.gas1.species_index('AR')
def speciesMass(k):
return self.r1.Y[k] * self.r1.mass + self.r2.Y[k] * self.r2.mass
mO2 = speciesMass(kO2)
mAr = speciesMass(kAr)
t = 0
while t < 1.0:
t = self.net.step()
p1 = self.r1.thermo.P
p2 = self.r2.thermo.P
self.assertNear(mdot(p1-p2), valve.mdot(t))
self.assertArrayNear(Y1, self.r1.Y)
self.assertNear(speciesMass(kAr), mAr)
self.assertNear(speciesMass(kO2), mO2)
def test_valve_errors(self):
self.make_reactors()
res = ct.Reservoir()
with self.assertRaises(RuntimeError):
# Must assign contents of both reactors before creating Valve
v = ct.Valve(self.r1, res)
v = ct.Valve(self.r1, self.r2)
with self.assertRaises(RuntimeError):
# inlet and outlet cannot be reassigned
v._install(self.r2, self.r1)
def test_pressure_controller(self):
self.make_reactors(n_reactors=1)
g = ct.Solution('h2o2.xml')
g.TPX = 500, 2*101325, 'H2:1.0'
inlet_reservoir = ct.Reservoir(g)
g.TP = 300, 101325
outlet_reservoir = ct.Reservoir(g)
mfc = ct.MassFlowController(inlet_reservoir, self.r1)
mdot = lambda t: np.exp(-100*(t-0.5)**2)
mfc.set_mass_flow_rate(mdot)
pc = ct.PressureController(self.r1, outlet_reservoir)
pc.set_master(mfc)
pc.set_pressure_coeff(1e-5)
t = 0
while t < 1.0:
t = self.net.step()
self.assertNear(mdot(t), mfc.mdot(t))
dP = self.r1.thermo.P - outlet_reservoir.thermo.P
self.assertNear(mdot(t) + 1e-5 * dP, pc.mdot(t))
def test_pressure_controller_errors(self):
self.make_reactors()
res = ct.Reservoir(self.gas1)
mfc = ct.MassFlowController(res, self.r1, mdot=0.6)
p = ct.PressureController(self.r1, self.r2, master=mfc, K=0.5)
with self.assertRaises(RuntimeError):
p = ct.PressureController(self.r1, self.r2, K=0.5)
p.mdot(0.0)
with self.assertRaises(RuntimeError):
p = ct.PressureController(self.r1, self.r2, master=mfc)
p.mdot(0.0)
with self.assertRaises(RuntimeError):
p = ct.PressureController(self.r1, self.r2)
p.mdot(0.0)
def test_set_initial_time(self):
self.make_reactors(P1=10*ct.one_atm, X1='AR:1.0', X2='O2:1.0')
self.net.rtol = 1e-12
valve = ct.Valve(self.r1, self.r2)
mdot = lambda dP: 5e-3 * np.sqrt(dP) if dP > 0 else 0.0
valve.set_valve_coeff(mdot)
t0 = 0.0
tf = t0 + 0.5
self.net.advance(tf)
self.assertNear(self.net.time, tf)
p1a = self.r1.thermo.P
p2a = self.r2.thermo.P
self.make_reactors(P1=10*ct.one_atm, X1='AR:1.0', X2='O2:1.0')
self.net.rtol = 1e-12
valve = ct.Valve(self.r1, self.r2)
mdot = lambda dP: 5e-3 * np.sqrt(dP) if dP > 0 else 0.0
valve.set_valve_coeff(mdot)
t0 = 0.2
self.net.set_initial_time(t0)
tf = t0 + 0.5
self.net.advance(tf)
self.assertNear(self.net.time, tf)
p1b = self.r1.thermo.P
p2b = self.r2.thermo.P
self.assertNear(p1a, p1b)
self.assertNear(p2a, p2b)
def test_reinitialize(self):
self.make_reactors(T1=300, T2=1000, independent=False)
self.add_wall(U=200, A=1.0)
self.net.advance(1.0)
T1a = self.r1.T
T2a = self.r2.T
self.r1.thermo.TD = 300, None
self.r1.syncState()
self.r2.thermo.TD = 1000, None
self.r2.syncState()
self.assertNear(self.r1.T, 300)
self.assertNear(self.r2.T, 1000)
self.net.advance(2.0)
T1b = self.r1.T
T2b = self.r2.T
self.assertNear(T1a, T1b)
self.assertNear(T2a, T2b)
def test_unpicklable(self):
self.make_reactors()
import pickle
with self.assertRaises(NotImplementedError):
pickle.dumps(self.r1)
with self.assertRaises(NotImplementedError):
pickle.dumps(self.net)
def test_uncopyable(self):
self.make_reactors()
import copy
with self.assertRaises(NotImplementedError):
copy.copy(self.r1)
with self.assertRaises(NotImplementedError):
copy.copy(self.net)
def test_invalid_property(self):
self.make_reactors()
for x in (self.r1, self.net):
with self.assertRaises(AttributeError):
x.foobar = 300
with self.assertRaises(AttributeError):
x.foobar
def test_bad_kwarg(self):
self.reactorClass(name='ok')
with self.assertRaises(TypeError):
r1 = self.reactorClass(foobar=3.14)
class TestIdealGasReactor(TestReactor):
reactorClass = ct.IdealGasReactor
class TestWellStirredReactorIgnition(utilities.CanteraTest):
""" Ignition (or not) of a well-stirred reactor """
def setup(self, T0, P0, mdot_fuel, mdot_ox):
self.gas = ct.Solution('gri30.xml')
# fuel inlet
self.gas.TPX = T0, P0, "CH4:1.0"
self.fuel_in = ct.Reservoir(self.gas)
# oxidizer inlet
self.gas.TPX = T0, P0, "N2:3.76, O2:1.0"
self.oxidizer_in = ct.Reservoir(self.gas)
# reactor, initially filled with N2
self.gas.TPX = T0, P0, "N2:1.0"
self.combustor = ct.IdealGasReactor(self.gas)
self.combustor.volume = 1.0
# outlet
self.exhaust = ct.Reservoir(self.gas)
# connect the reactor to the reservoirs
self.fuel_mfc = ct.MassFlowController(self.fuel_in, self.combustor)
self.fuel_mfc.set_mass_flow_rate(mdot_fuel)
self.oxidizer_mfc = ct.MassFlowController(self.oxidizer_in, self.combustor)
self.oxidizer_mfc.set_mass_flow_rate(mdot_ox)
self.valve = ct.Valve(self.combustor, self.exhaust)
self.valve.set_valve_coeff(1.0)
self.net = ct.ReactorNet()
self.net.add_reactor(self.combustor)
self.net.max_err_test_fails = 10
def integrate(self, tf):
t = 0.0
times = []
T = []
i = 0
while t < tf:
i += 1
t = self.net.step()
times.append(t)
T.append(self.combustor.T)
return times, T
def test_nonreacting(self):
mdot_f = 1.0
mdot_o = 5.0
T0 = 900.0
self.setup(T0, 10*ct.one_atm, mdot_f, mdot_o)
self.gas.set_multiplier(0.0)
t,T = self.integrate(100.0)
for i in range(len(t)):
self.assertNear(T[i], T0, rtol=1e-5)
self.assertNear(self.combustor.thermo['CH4'].Y,
mdot_f / (mdot_o + mdot_f))
def test_ignition1(self):
self.setup(900.0, 10*ct.one_atm, 1.0, 5.0)
t,T = self.integrate(10.0)
self.assertTrue(T[-1] > 1200) # mixture ignited
for i in range(len(t)):
if T[i] > 0.5 * (T[0] + T[-1]):
tIg = t[i]
break
# regression test; no external basis for this result
self.assertNear(tIg, 2.2249, 1e-3)
def test_ignition2(self):
self.setup(900.0, 10*ct.one_atm, 1.0, 20.0)
t,T = self.integrate(10.0)
self.assertTrue(T[-1] > 1200) # mixture ignited
for i in range(len(t)):
if T[i] > 0.5 * (T[0] + T[-1]):
tIg = t[i]
break
# regression test; no external basis for this result
self.assertNear(tIg, 1.4856, 1e-3)
def test_ignition3(self):
self.setup(900.0, 10*ct.one_atm, 1.0, 80.0)
self.net.set_max_time_step(0.5)
t,T = self.integrate(100.0)
self.assertTrue(T[-1] < 910) # mixture did not ignite
def test_steady_state(self):
self.setup(900.0, 10*ct.one_atm, 1.0, 20.0)
residuals = self.net.advance_to_steady_state(return_residuals=True)
# test if steady state is reached
self.assertTrue(residuals[-1] < 10. * self.net.rtol)
# regression test; no external basis for these results
self.assertNear(self.combustor.T, 2486.14, 1e-5)
self.assertNear(self.combustor.thermo['H2O'].Y[0], 0.103804, 1e-5)
self.assertNear(self.combustor.thermo['HO2'].Y[0], 7.71296e-06, 1e-5)
class TestConstPressureReactor(utilities.CanteraTest):
"""
The constant pressure reactor should give essentially the same results as
as a regular "Reactor" with a wall with a very high expansion rate
coefficient.
"""
reactorClass = ct.ConstPressureReactor
def create_reactors(self, add_Q=False, add_mdot=False, add_surf=False):
self.gas = ct.Solution('gri30.xml')
self.gas.TPX = 900, 25*ct.one_atm, 'CO:0.5, H2O:0.2'
self.gas1 = ct.Solution('gri30.xml')
self.gas1.ID = 'gas'
self.gas2 = ct.Solution('gri30.xml')
self.gas2.ID = 'gas'
resGas = ct.Solution('gri30.xml')
solid = ct.Solution('diamond.xml', 'diamond')
T0 = 1200
P0 = 25*ct.one_atm
X0 = 'CH4:0.5, H2O:0.2, CO:0.3'
self.gas1.TPX = T0, P0, X0
self.gas2.TPX = T0, P0, X0
self.r1 = ct.IdealGasReactor(self.gas1)
self.r2 = self.reactorClass(self.gas2)
self.r1.volume = 0.2
self.r2.volume = 0.2
resGas.TP = T0 - 300, P0
env = ct.Reservoir(resGas)
U = 300 if add_Q else 0
self.w1 = ct.Wall(self.r1, env, K=1e3, A=0.1, U=U)
self.w2 = ct.Wall(self.r2, env, A=0.1, U=U)
if add_mdot:
mfc1 = ct.MassFlowController(env, self.r1, mdot=0.05)
mfc2 = ct.MassFlowController(env, self.r2, mdot=0.05)
if add_surf:
self.interface1 = ct.Interface('diamond.xml', 'diamond_100',
(self.gas1, solid))
self.interface2 = ct.Interface('diamond.xml', 'diamond_100',
(self.gas2, solid))
C = np.zeros(self.interface1.n_species)
C[0] = 0.3
C[4] = 0.7
self.w1.left.kinetics = self.interface1
self.w2.left.kinetics = self.interface2
self.w1.left.coverages = C
self.w2.left.coverages = C
self.net1 = ct.ReactorNet([self.r1])
self.net2 = ct.ReactorNet([self.r2])
self.net1.set_max_time_step(0.05)
self.net2.set_max_time_step(0.05)
self.net2.max_err_test_fails = 10
def test_component_index(self):
self.create_reactors(add_surf=True)
for (gas,net,iface,r) in ((self.gas1, self.net1, self.interface1, self.r1),
(self.gas2, self.net2, self.interface2, self.r2)):
net.step()
N0 = net.n_vars - gas.n_species - iface.n_species
N1 = net.n_vars - iface.n_species
for i, name in enumerate(gas.species_names):
self.assertEqual(i + N0, r.component_index(name))
for i, name in enumerate(iface.species_names):
self.assertEqual(i + N1, r.component_index(name))
def integrate(self, surf=False):
for t in np.arange(0.5, 50, 1.0):
self.net1.advance(t)
self.net2.advance(t)
self.assertArrayNear(self.r1.thermo.Y, self.r2.thermo.Y,
rtol=5e-4, atol=1e-6)
self.assertNear(self.r1.T, self.r2.T, rtol=1e-5)
self.assertNear(self.r1.thermo.P, self.r2.thermo.P, rtol=1e-6)
if surf:
self.assertArrayNear(self.w1.left.coverages,
self.w2.left.coverages,
rtol=1e-4, atol=1e-8)
def test_closed(self):
self.create_reactors()
self.integrate()
def test_with_heat_transfer(self):
self.create_reactors(add_Q=True)
self.integrate()
def test_with_mdot(self):
self.create_reactors(add_mdot=True)
self.integrate()
def test_with_surface_reactions(self):
self.create_reactors(add_surf=True)
self.net1.atol = self.net2.atol = 1e-18
self.net1.rtol = self.net2.rtol = 1e-9
self.integrate(surf=True)
class TestIdealGasConstPressureReactor(TestConstPressureReactor):
reactorClass = ct.IdealGasConstPressureReactor
class TestFlowReactor(utilities.CanteraTest):
def test_nonreacting(self):
g = ct.Solution('h2o2.xml')
g.TPX = 300, 101325, 'O2:1.0'
r = ct.FlowReactor(g)
r.mass_flow_rate = 10
net = ct.ReactorNet()
net.add_reactor(r)
t = 0
v0 = r.speed
self.assertNear(v0, 10 / r.density)
while t < 10.0:
t = net.step()
self.assertNear(v0, r.speed)
self.assertNear(r.distance, v0 * t)
def test_reacting(self):
g = ct.Solution('gri30.xml')
g.TPX = 1400, 20*101325, 'CO:1.0, H2O:1.0'
r = ct.FlowReactor(g)
r.mass_flow_rate = 10
net = ct.ReactorNet()
net.add_reactor(r)
net.atol = 1e-18
net.rtol = 1e-9
net.max_err_test_fails = 10
t = 0
self.assertNear(r.speed, 10 / r.density)
while t < 1.0:
t1 = net.time
x1 = r.distance
t = net.step()
v = (r.distance - x1) / (net.time - t1)
self.assertNear(r.speed, v, 1e-3)
class TestWallKinetics(utilities.CanteraTest):
def make_reactors(self):
self.net = ct.ReactorNet()
self.gas = ct.Solution('diamond.xml', 'gas')
self.solid = ct.Solution('diamond.xml', 'diamond')
self.interface = ct.Interface('diamond.xml', 'diamond_100',
(self.gas, self.solid))
self.r1 = ct.IdealGasReactor(self.gas)
self.r1.volume = 0.01
self.net.add_reactor(self.r1)
self.r2 = ct.IdealGasReactor(self.gas)
self.r2.volume = 0.01
self.net.add_reactor(self.r2)
self.w = ct.Wall(self.r1, self.r2)
self.w.area = 1.0
def test_coverages(self):
self.make_reactors()
self.w.left.kinetics = self.interface
self.w.left.coverages = {'c6HH':0.3, 'c6HM':0.7}
self.assertNear(self.w.left.coverages[0], 0.3)
self.assertNear(self.w.left.coverages[1], 0.0)
self.assertNear(self.w.left.coverages[4], 0.7)
self.net.advance(1e-5)
C_left = self.w.left.coverages
self.assertEqual(self.w.right.kinetics, None)
with self.assertRaises(Exception):
self.w.right.coverages
self.make_reactors()
self.w.right.kinetics = self.interface
self.w.right.coverages = 'c6HH:0.3, c6HM:0.7'
self.assertNear(self.w.right.coverages[0], 0.3)
self.assertNear(self.w.right.coverages[4], 0.7)
self.assertEqual(self.w.left.kinetics, None)
with self.assertRaises(Exception):
self.w.left.coverages
self.net.advance(1e-5)
C_right = self.w.right.coverages
self.assertNear(sum(C_left), 1.0)
self.assertArrayNear(C_left, C_right)
def test_coverages_regression1(self):
# Test with energy equation disabled
self.make_reactors()
self.r1.energy_enabled = False
self.r2.energy_enabled = False
self.w.left.kinetics = self.interface
C = np.zeros(self.interface.n_species)
C[0] = 0.3
C[4] = 0.7
self.w.left.coverages = C
self.assertArrayNear(self.w.left.coverages, C)
data = []
test_file = 'test_coverages_regression1.csv'
reference_file = '../data/WallKinetics-coverages-regression1.csv'
data = []
for t in np.linspace(1e-6, 1e-3):
self.net.advance(t)
data.append([t, self.r1.T, self.r1.thermo.P, self.r1.mass] +
list(self.r1.thermo.X) + list(self.w.left.coverages))
np.savetxt(test_file, data, delimiter=',')
bad = utilities.compareProfiles(reference_file, test_file,
rtol=1e-5, atol=1e-9, xtol=1e-12)
self.assertFalse(bool(bad), bad)
def test_coverages_regression2(self):
# Test with energy equation enabled
self.make_reactors()
self.w.left.kinetics = self.interface
C = np.zeros(self.interface.n_species)
C[0] = 0.3
C[4] = 0.7
self.w.left.coverages = C
self.assertArrayNear(self.w.left.coverages, C)
data = []
test_file = 'test_coverages_regression2.csv'
reference_file = '../data/WallKinetics-coverages-regression2.csv'
data = []
for t in np.linspace(1e-6, 1e-3):
self.net.advance(t)
data.append([t, self.r1.T, self.r1.thermo.P, self.r1.mass] +
list(self.r1.thermo.X) + list(self.w.left.coverages))
np.savetxt(test_file, data, delimiter=',')
bad = utilities.compareProfiles(reference_file, test_file,
rtol=1e-5, atol=1e-9, xtol=1e-12)
self.assertFalse(bool(bad), bad)
class TestReactorSensitivities(utilities.CanteraTest):
def test_sensitivities1(self):
net = ct.ReactorNet()
gas = ct.Solution('gri30.xml')
gas.TPX = 1300, 20*101325, 'CO:1.0, H2:0.1, CH4:0.1, H2O:0.5'
r1 = ct.IdealGasReactor(gas)
net.add_reactor(r1)
self.assertEqual(net.n_sensitivity_params, 0)
r1.add_sensitivity_reaction(40)
r1.add_sensitivity_reaction(41)
net.advance(0.1)
self.assertEqual(net.n_sensitivity_params, 2)
self.assertEqual(net.n_vars,
gas.n_species + r1.component_index(gas.species_name(0)))
S = net.sensitivities()
self.assertEqual(S.shape, (net.n_vars, net.n_sensitivity_params))
def test_sensitivities2(self):
net = ct.ReactorNet()
gas1 = ct.Solution('diamond.xml', 'gas')
solid = ct.Solution('diamond.xml', 'diamond')
interface = ct.Interface('diamond.xml', 'diamond_100',
(gas1, solid))
r1 = ct.IdealGasReactor(gas1)
net.add_reactor(r1)
net.atol_sensitivity = 1e-10
net.rtol_sensitivity = 1e-8
gas2 = ct.Solution('h2o2.xml')
gas2.TPX = 900, 101325, 'H2:0.1, OH:1e-7, O2:0.1, AR:1e-5'
r2 = ct.IdealGasReactor(gas2)
net.add_reactor(r2)
w = ct.Wall(r1, r2)
w.area = 1.5
w.left.kinetics = interface
C = np.zeros(interface.n_species)
C[0] = 0.3
C[4] = 0.7
w.left.coverages = C
w.left.add_sensitivity_reaction(2)
r2.add_sensitivity_reaction(18)
for T in (901, 905, 910, 950, 1500):
while r2.T < T:
net.step()
S = net.sensitivities()
# number of non-species variables in each reactor
Ns = r1.component_index(gas1.species_name(0))
# Index of first variable corresponding to r2
K2 = Ns + gas1.n_species + interface.n_species
# Constant volume should generate zero sensitivity coefficient
self.assertArrayNear(S[1,:], np.zeros(2))
self.assertArrayNear(S[K2+1,:], np.zeros(2))
# Sensitivity coefficients for the disjoint reactors should be zero
self.assertNear(np.linalg.norm(S[Ns:K2,1]), 0.0, atol=1e-5)
self.assertNear(np.linalg.norm(S[K2+Ns:,0]), 0.0, atol=1e-5)
def _test_parameter_order1(self, reactorClass):
# Single reactor, changing the order in which parameters are added
gas = ct.Solution('h2o2.xml')
def setup(params):
net = ct.ReactorNet()
gas.TPX = 900, 101325, 'H2:0.1, OH:1e-7, O2:0.1, AR:1e-5'
r = reactorClass(gas)
net.add_reactor(r)
for kind, p in params:
if kind == 'r':
r.add_sensitivity_reaction(p)
elif kind == 's':
r.add_sensitivity_species_enthalpy(p)
return r, net
def integrate(r, net):
while r.T < 910:
net.step()
return net.sensitivities()
def check_names(reactor, net, params):
for i,(kind,p) in enumerate(params):
rname, comp = net.sensitivity_parameter_name(i).split(': ')
self.assertEqual(reactor.name, rname)
if kind == 'r':
self.assertEqual(gas.reaction_equation(p), comp)
elif kind == 's':
self.assertEqual(p + ' enthalpy', comp)
params1 = [('r', 2), ('r', 10), ('r', 18), ('r', 19), ('s', 'O2'),
('s', 'OH'), ('s', 'H2O2')]
r1,net1 = setup(params1)
S1 = integrate(r1, net1)
check_names(r1, net1, params1)
params2 = [('r', 19), ('s', 'H2O2'), ('s', 'OH'), ('r', 10),
('s', 'O2'), ('r', 2), ('r', 18)]
r2,net2 = setup(params2)
S2 = integrate(r2, net2)
check_names(r2, net2, params2)
for i,j in enumerate((5,3,6,0,4,2,1)):
self.assertArrayNear(S1[:,i], S2[:,j])
def test_parameter_order1a(self):
self._test_parameter_order1(ct.IdealGasReactor)
def test_parameter_order1b(self):
self._test_parameter_order1(ct.IdealGasConstPressureReactor)
def test_parameter_order2(self):
# Multiple reactors, changing the order in which parameters are added
gas = ct.Solution('h2o2.xml')
def setup(reverse=False):
net = ct.ReactorNet()
gas1 = ct.Solution('h2o2.xml')
gas1.TPX = 900, 101325, 'H2:0.1, OH:1e-7, O2:0.1, AR:1e-5'
rA = ct.IdealGasReactor(gas1)
gas2 = ct.Solution('h2o2.xml')
gas2.TPX = 920, 101325, 'H2:0.1, OH:1e-7, O2:0.1, AR:0.5'
rB = ct.IdealGasReactor(gas2)
if reverse:
net.add_reactor(rB)
net.add_reactor(rA)
else:
net.add_reactor(rA)
net.add_reactor(rB)
return rA, rB, net
def integrate(r, net):
net.advance(1e-4)
return net.sensitivities()
S = []
for reverse in (True,False):
rA1,rB1,net1 = setup(reverse)
params1 = [(rA1,2),(rA1,19),(rB1,10),(rB1,18)]
for r,p in params1:
r.add_sensitivity_reaction(p)
S.append(integrate(rA1, net1))
pname = lambda r,i: '%s: %s' % (r.name, gas.reaction_equation(i))
for i,(r,p) in enumerate(params1):
self.assertEqual(pname(r,p), net1.sensitivity_parameter_name(i))
rA2,rB2,net2 = setup(reverse)
params2 = [(rB2,10),(rA2,19),(rB2,18),(rA2,2)]
for r,p in params2:
r.add_sensitivity_reaction(p)
S.append(integrate(rA2, net2))
for i,(r,p) in enumerate(params2):
self.assertEqual(pname(r,p), net2.sensitivity_parameter_name(i))
# Check that the results reflect the changed parameter ordering
for a,b in ((0,1), (2,3)):
for i,j in enumerate((3,1,0,2)):
self.assertArrayNear(S[a][:,i], S[b][:,j])
# Check that results are consistent after changing the order that
# reactors are added to the network
N = gas.n_species + r.component_index(gas.species_name(0))
self.assertArrayNear(S[0][:N], S[2][N:], 1e-5, 1e-5)
self.assertArrayNear(S[0][N:], S[2][:N], 1e-5, 1e-5)
self.assertArrayNear(S[1][:N], S[3][N:], 1e-5, 1e-5)
self.assertArrayNear(S[1][N:], S[3][:N], 1e-5, 1e-5)
def test_parameter_order3(self):
# Test including reacting surfaces
gas1 = ct.Solution('diamond.xml', 'gas')
solid = ct.Solution('diamond.xml', 'diamond')
interface = ct.Interface('diamond.xml', 'diamond_100',
(gas1, solid))
gas2 = ct.Solution('h2o2.xml')
def setup(order):
gas1.TPX = 1200, 1e3, 'H:0.002, H2:1, CH4:0.01, CH3:0.0002'
gas2.TPX = 900, 101325, 'H2:0.1, OH:1e-7, O2:0.1, AR:1e-5'
net = ct.ReactorNet()
rA = ct.IdealGasReactor(gas1)
rB = ct.IdealGasReactor(gas2)
if order % 2 == 0:
wA = ct.Wall(rA, rB)
wB = ct.Wall(rB, rA)
else:
wB = ct.Wall(rB, rA)
wA = ct.Wall(rA, rB)
wA.left.kinetics = interface
wB.right.kinetics = interface
wA.area = 0.1
wB.area = 10
C1 = np.zeros(interface.n_species)
C2 = np.zeros(interface.n_species)
C1[0] = 0.3
C1[4] = 0.7
C2[0] = 0.9
C2[4] = 0.1
wA.left.coverages = C1
wB.right.coverages = C2
if order // 2 == 0:
net.add_reactor(rA)
net.add_reactor(rB)
else:
net.add_reactor(rB)
net.add_reactor(rA)
return rA,rB,wA,wB,net
def integrate(r, net):
net.advance(1e-4)
return net.sensitivities()
S = []
for order in range(4):
rA,rB,wA,wB,net = setup(order)
for (obj,k) in [(rB,2), (rB,18), (wA.left,2),
(wA.left,0), (wB.right,2)]:
obj.add_sensitivity_reaction(k)
integrate(rB, net)
S.append(net.sensitivities())
rA,rB,wA,wB,net = setup(order)
for (obj,k) in [(wB.right,2), (wA.left,2), (rB,18),
(wA.left,0), (rB,2)]:
obj.add_sensitivity_reaction(k)
integrate(rB, net)
S.append(net.sensitivities())
for a,b in [(0,1),(2,3),(4,5),(6,7)]:
for i,j in enumerate((4,2,1,3,0)):
self.assertArrayNear(S[a][:,i], S[b][:,j], 1e-2, 1e-3)
class CombustorTestImplementation(object):
"""
These tests are based on the sample:
interfaces/cython/cantera/examples/reactors/combustor.py
with some simplifications so that they run faster and produce more
consistent output.
"""
referenceFile = '../data/CombustorTest-integrateWithAdvance.csv'
def setUp(self):
self.gas = ct.Solution('h2o2.xml')
# create a reservoir for the fuel inlet, and set to pure methane.
self.gas.TPX = 300.0, ct.one_atm, 'H2:1.0'
fuel_in = ct.Reservoir(self.gas)
fuel_mw = self.gas.mean_molecular_weight
# Oxidizer inlet
self.gas.TPX = 300.0, ct.one_atm, 'O2:1.0, AR:3.0'
oxidizer_in = ct.Reservoir(self.gas)
oxidizer_mw = self.gas.mean_molecular_weight
# to ignite the fuel/air mixture, we'll introduce a pulse of radicals.
# The steady-state behavior is independent of how we do this, so we'll
# just use a stream of pure atomic hydrogen.
self.gas.TPX = 300.0, ct.one_atm, 'H:1.0'
self.igniter = ct.Reservoir(self.gas)
# create the combustor, and fill it in initially with a diluent
self.gas.TPX = 300.0, ct.one_atm, 'AR:1.0'
self.combustor = ct.IdealGasReactor(self.gas)
# create a reservoir for the exhaust
self.exhaust = ct.Reservoir(self.gas)
# compute fuel and air mass flow rates
factor = 0.1
oxidizer_mdot = 4 * factor*oxidizer_mw
fuel_mdot = factor*fuel_mw
# The igniter will use a time-dependent igniter mass flow rate.
def igniter_mdot(t, t0=0.1, fwhm=0.05, amplitude=0.1):
return amplitude * math.exp(-(t-t0)**2 * 4 * math.log(2) / fwhm**2)
# create and install the mass flow controllers. Controllers
# m1 and m2 provide constant mass flow rates, and m3 provides
# a short Gaussian pulse only to ignite the mixture
m1 = ct.MassFlowController(fuel_in, self.combustor, mdot=fuel_mdot)
m2 = ct.MassFlowController(oxidizer_in, self.combustor, mdot=oxidizer_mdot)
m3 = ct.MassFlowController(self.igniter, self.combustor, mdot=igniter_mdot)
# put a valve on the exhaust line to regulate the pressure
self.v = ct.Valve(self.combustor, self.exhaust, K=1.0)
# the simulation only contains one reactor
self.sim = ct.ReactorNet([self.combustor])
def test_integrateWithStep(self):
tnow = 0.0
tfinal = 0.25
self.data = []
while tnow < tfinal:
tnow = self.sim.step()
self.data.append([tnow, self.combustor.T] +
list(self.combustor.thermo.X))
self.assertTrue(tnow >= tfinal)
bad = utilities.compareProfiles(self.referenceFile, self.data,
rtol=1e-3, atol=1e-9)
self.assertFalse(bad, bad)
def test_integrateWithAdvance(self, saveReference=False):
self.data = []
for t in np.linspace(0, 0.25, 101)[1:]:
self.sim.advance(t)
self.data.append([t, self.combustor.T] +
list(self.combustor.thermo.X))
if saveReference:
np.savetxt(self.referenceFile, np.array(self.data), '%11.6e', ', ')
else:
bad = utilities.compareProfiles(self.referenceFile, self.data,
rtol=1e-6, atol=1e-12)
self.assertFalse(bad, bad)
class WallTestImplementation(object):
"""
These tests are based on the sample:
interfaces/cython/cantera/examples/reactors/reactor2.py
with some simplifications so that they run faster and produce more
consistent output.
"""
referenceFile = '../data/WallTest-integrateWithAdvance.csv'
def setUp(self):
# reservoir to represent the environment
self.gas0 = ct.Solution('air.xml')
self.gas0.TP = 300, ct.one_atm
self.env = ct.Reservoir(self.gas0)
# reactor to represent the side filled with Argon
self.gas1 = ct.Solution('air.xml')
self.gas1.TPX = 1000.0, 30*ct.one_atm, 'AR:1.0'
self.r1 = ct.Reactor(self.gas1)
# reactor to represent the combustible mixture
self.gas2 = ct.Solution('h2o2.xml')
self.gas2.TPX = 500.0, 1.5*ct.one_atm, 'H2:0.5, O2:1.0, AR:10.0'
self.r2 = ct.Reactor(self.gas2)
# Wall between the two reactors
self.w1 = ct.Wall(self.r2, self.r1, A=1.0, K=2e-4, U=400.0)
# Wall to represent heat loss to the environment
self.w2 = ct.Wall(self.r2, self.env, A=1.0, U=2000.0)
# Create the reactor network
self.sim = ct.ReactorNet([self.r1, self.r2])
def test_integrateWithStep(self):
tnow = 0.0
tfinal = 0.01
self.data = []
while tnow < tfinal:
tnow = self.sim.step()
self.data.append([tnow,
self.r1.T, self.r2.T,
self.r1.thermo.P, self.r2.thermo.P,
self.r1.volume, self.r2.volume])
self.assertTrue(tnow >= tfinal)
bad = utilities.compareProfiles(self.referenceFile, self.data,
rtol=1e-3, atol=1e-8)
self.assertFalse(bad, bad)
def test_integrateWithAdvance(self, saveReference=False):
self.data = []
for t in np.linspace(0, 0.01, 200)[1:]:
self.sim.advance(t)
self.data.append([t,
self.r1.T, self.r2.T,
self.r1.thermo.P, self.r2.thermo.P,
self.r1.volume, self.r2.volume])
if saveReference:
np.savetxt(self.referenceFile, np.array(self.data), '%11.6e', ', ')
else:
bad = utilities.compareProfiles(self.referenceFile, self.data,
rtol=2e-5, atol=1e-9)
self.assertFalse(bad, bad)
# Keep the implementations separate from the unittest-derived class
# so that they can be run independently to generate the reference data files.
class CombustorTest(CombustorTestImplementation, unittest.TestCase): pass
class WallTest(WallTestImplementation, unittest.TestCase): pass