102 lines
6.9 KiB
Text
102 lines
6.9 KiB
Text
psat(273.16) = 611.655
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Comparisons to NIST: (see http://webbook.nist.gov):
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H0(298.15) = -2.41826e+08 J/kmol
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S0(298.15) = 188835 J/kmolK
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Ideal Gas Standard State:
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T Cp0 S0 -(G0-H298)/T H0-H298
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(K) (J/molK) (J/molK) (J/molK) (kJ/mol)
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298.15 33.5873 188.8350 188.8350 0.0000
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500 35.2263 206.5346 192.6857 6.9245
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600 36.3249 213.0529 195.5507 10.5013
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1000 41.2673 232.7386 206.7385 26.0001
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H_liq(298.15, onebar) = -2.85838e+08 J/kmol
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S_liq(298.15, onebar) = 69922.3 J/kmolK
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Liquid 1bar or psat Standard State
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T press psat Cp0 S0 -(G0-H298)/T H0-H298
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(K) (bar) (bar) (J/molK) (J/molK) (J/molK) (kJ/mol)
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273.19 1 0.00612989 76.0121 63.3155 70.2193 -1.8860
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298.15 1 0.0316993 75.3276 69.9223 69.9223 0.0000
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300 1 0.0353681 75.3153 70.3882 69.9237 0.1393
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373.15 1.01621 1.01418 75.9465 86.8568 71.6853 5.6613
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400 2.46261 2.45769 76.6642 92.1543 72.8764 7.7112
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500 26.4447 26.392 84.0126 109.8051 78.4401 15.6825
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Liquid Densities:
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T press psat Density molarVol
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(K) (bar) (bar) (kg/m3) (m3/kmol)
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273.19 1 0.00612989 999.8451 0.0180
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298.15 1 0.0316993 997.0470 0.0181
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300 1 0.0353681 996.5563 0.0181
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373.15 1.01621 1.01418 958.3491 0.0188
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400 2.46261 2.45769 937.4863 0.0192
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500 26.4447 26.392 831.3184 0.0217
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Liquid 1bar or psat State: Partial Molar Quantities
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T press psat Cpbar Sbar -(G0-H298)/T H0-H298 Volume
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(K) (bar) (bar) (J/molK) (J/molK) (J/molK) (kJ/mol) m3/kmol
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273.19 1 0.00612989 76.0121 63.3155 70.2193 -1.8860 0.0180
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298.15 1 0.0316993 75.3276 69.9223 69.9223 0.0000 0.0181
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300 1 0.0353681 75.3153 70.3882 69.9237 0.1393 0.0181
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373.15 1.01621 1.01418 75.9465 86.8568 71.6853 5.6613 0.0188
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400 2.46261 2.45769 76.6642 92.1543 72.8764 7.7112 0.0192
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500 26.4447 26.392 84.0126 109.8051 78.4401 15.6825 0.0217
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Liquid 1bar or psat State: Standard State Quantities
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T press psat Cpbar Sbar -(G0-H298)/T H0-H298 Volume
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(K) (bar) (bar) (J/molK) (J/molK) (J/molK) (kJ/mol) m3/kmol
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273.19 1 0.00612989 76.0121 63.3155 70.2193 -1.8860 0.0180
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298.15 1 0.0316993 75.3276 69.9223 69.9223 0.0000 0.0181
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300 1 0.0353681 75.3153 70.3882 69.9237 0.1393 0.0181
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373.15 1.01621 1.01418 75.9465 86.8568 71.6853 5.6613 0.0188
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400 2.46261 2.45769 76.6642 92.1543 72.8764 7.7112 0.0192
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500 26.4447 26.392 84.0126 109.8051 78.4401 15.6825 0.0217
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Liquid 1bar or psat State: Reference State Quantities (Always 1 atm no matter what system pressure is)
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T press psat Cpbar Sbar -(G0-H298)/T H0-H298 Volume
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(K) (bar) (bar) (J/molK) (J/molK) (J/molK) (kJ/mol) m3/kmol
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273.19 1 0.00612989 76.0119 63.3155 70.2192 -1.8860 0.0180
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298.15 1 0.0316993 75.3275 69.9223 69.9222 0.0000 0.0181
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300 1 0.0353681 75.3153 70.3882 69.9236 0.1394 0.0181
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373.15 1.01621 1.01418 75.9465 86.8568 71.6853 5.6612 0.0188
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400 2.46261 2.45769 76.6712 92.1568 72.8834 7.7094 0.0192
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500 26.4447 26.392 84.4316 109.8967 78.5504 15.6732 0.0217
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Liquid 1 atm: Standard State Quantities - Should agree with table above
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T press psat Cpbar Sbar -(G0-H298)/T H0-H298 Volume
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(K) (bar) (bar) (J/molK) (J/molK) (J/molK) (kJ/mol) m3/kmol
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273.19 1.01325 0.00612989 76.0119 63.3155 70.2192 -1.8860 0.0180
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298.15 1.01325 0.0316993 75.3275 69.9223 69.9222 0.0000 0.0181
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300 1.01325 0.0353681 75.3153 70.3882 69.9236 0.1394 0.0181
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373.15 1.01325 1.01418 75.9465 86.8568 71.6853 5.6612 0.0188
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400 1.01325 2.45769 76.6712 92.1568 72.8834 7.7094 0.0192
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500 1.01325 26.392 84.4316 109.8967 78.5504 15.6732 0.0217
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Table of increasing Enthalpy at 1 atm
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Enthalpy, Temperature, x_Vapor, Density, Entropy_mass, Gibbs_mass
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-1.58671e+07, 298, 0, 997.09, 3879.2, -1.7023e+07
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-1.58671e+07, 298, 0, 997.09, 3879.2, -1.7023e+07
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-1.57671e+07, 321.924, 0, 988.58, 4202, -1.712e+07
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-1.56671e+07, 345.815, 0, 976.22, 4501.6, -1.7224e+07
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-1.55671e+07, 369.62, 0, 960.86, 4781.2, -1.7334e+07
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-1.54671e+07, 393.28, 0, 942.95, 5043.5, -1.7451e+07
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-1.53671e+07, 416.718, 0, 922.76, 5290.4, -1.7572e+07
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-1.52671e+07, 439.848, 0, 900.41, 5524, -1.7697e+07
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-1.51671e+07, 462.563, 0, 875.92, 5745.6, -1.7825e+07
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-1.50671e+07, 484.741, 0, 849.2, 5956.8, -1.7955e+07
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-1.49671e+07, 506.233, 0, 820.07, 6158.6, -1.8085e+07
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-1.48671e+07, 526.848, 0, 788.18, 6352.2, -1.8214e+07
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-1.47671e+07, 546.325, 0, 752.98, 6538.5, -1.8339e+07
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-1.46671e+07, 564.272, 0, 713.51, 6718.6, -1.8458e+07
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-1.45671e+07, 580.026, 0, 667.86, 6893.3, -1.8565e+07
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-1.44671e+07, -> Failed to converge, beyond the spinodal probably
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Critical Temp = 647 K
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Critical Pressure = 218 atm
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Critical Dens = 322 kg/m3
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