39 lines
3.7 KiB
Text
39 lines
3.7 KiB
Text
A_V : Comparison to Pitzer's book, p. 99, can be made.
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Agreement to 3 sig digits
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Delta_V0: Heat Capacity of Solution per mole of salt (standard states)
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rxn for the ss heat of soln: NaCl(s) -> Na+(aq) + Cl-(aq)
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Delta_Vs: Delta volume of Solution per mole of salt
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rxn for heat of soln: n1 H2O(l,pure) + n2 NaCl(s) -> n2 MX(aq) + n1 H2O(l)
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Delta_Hs = (n1 h_H2O_bar + n2 h_MX_bar - n1 h_H2O_0 - n2 h_MX_0)/n2
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phiV: phiV, calculated from the program, is checked
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against analytical formula in V_standalone program.
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(comparison against Pitzer book, p. 97, eqn. 96)
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T, Pres, Aphi, A_V, Delta_V0, Delta_Vs, Vex, phiV, MolarV, MolarV0
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Kelvin, bar, sqrt(kg/gmol),sqrt(kg/gmol)cm3/gmol,cm**3/gmolSalt,cm**3/gmolSalt,cm**3/gmolSoln,cm**3/gmolSalt,cm**3/gmol, cm**3/gmol
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273.15, 1.01325, 0.376717, 1.50615, -10.3142, -8.58213, 0.15701, 1.73208, 16.4205, 16.2635
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298.15, 1.01325, 0.391447, 1.87431, -10.3142, -8.15874, 0.19539, 2.15547, 16.5002, 16.3049
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323.15, 1.01325, 0.410293, 2.37345, -10.3142, -7.58473, 0.24742, 2.72949, 16.6872, 16.4398
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348.15, 1.01325, 0.433273, 3.06975, -10.3142, -6.78398, 0.32001, 3.53023, 16.9618, 16.6418
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373.15, 1.01418, 0.460559, 4.05157, -10.3142, -5.65488, 0.42236, 4.65934, 17.3246, 16.9022
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398.15, 2.32238, 0.492454, 5.45118, -10.3142, -4.04532, 0.56826, 6.26889, 17.7872, 17.2189
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423.15, 4.76165, 0.529514, 7.4808, -10.3142, -1.71124, 0.77985, 8.60297, 18.3759, 17.596
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448.15, 8.92602, 0.572549, 10.4889, -10.3142, 1.74814, 1.0934, 12.0624, 19.1352, 18.0417
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473.15, 15.5493, 0.622769, 15.0761, -10.3142, 7.02345, 1.5716, 17.3377, 20.1414, 18.5698
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498.15, 25.4972, 0.682036, 22.3385, -10.3142, 15.3752, 2.3287, 25.6894, 21.5309, 19.2022
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523.15, 39.7617, 0.753389, 34.431, -10.3142, 29.2817, 3.5893, 39.5959, 23.5633, 19.974
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548.15, 59.4639, 0.842213, 56.0329, -10.3142, 54.124, 5.8412, 64.4382, 26.7855, 20.9443
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573.15, 85.879, 0.959258, 98.8122, -10.3142, 103.321, 10.301, 113.635, 32.524, 22.2232
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598.15, 120.51, 1.13023, 198.465, -10.3142, 217.922, 20.689, 228.237, 44.7422, 24.053
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623.15, 165.294, 1.43872, 494.917, -10.3142, 558.844, 51.593, 569.158, 78.7691, 27.1758
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323.15, 1.01325, 0.410293, 2.37345, -10.3142, -7.58473, 0.24742, 2.72949, 16.6872, 16.4398
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Breakdown of Volume Calculation at 323.15 K, 1atm:
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Species MoleFrac Molal V0 partV (partV - V0)
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H2O(L) 0.818703 0 18.2334 18.1515 -0.0819503
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Na+ 0.0906484 6.146 8.34 10.0748 1.73482
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Cl- 0.0906484 6.146 8.34 10.0748 1.73482
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NaCl(s) 1 26.9942 26.9942 0
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