102 lines
6.9 KiB
Text
102 lines
6.9 KiB
Text
psat(273.16) = 611.655
|
|
Comparisons to NIST: (see http://webbook.nist.gov):
|
|
|
|
H0(298.15) = -2.41826e+08 J/kmol
|
|
S0(298.15) = 188835 J/kmolK
|
|
|
|
Ideal Gas Standard State:
|
|
T Cp0 S0 -(G0-H298)/T H0-H298
|
|
(K) (J/molK) (J/molK) (J/molK) (kJ/mol)
|
|
298.15 33.5873 188.8350 188.8350 0.0000
|
|
500 35.2263 206.5346 192.6857 6.9245
|
|
600 36.3249 213.0529 195.5507 10.5013
|
|
1000 41.2673 232.7386 206.7385 26.0001
|
|
|
|
|
|
H_liq(298.15, onebar) = -2.85838e+08 J/kmol
|
|
S_liq(298.15, onebar) = 69922.3 J/kmolK
|
|
|
|
Liquid 1bar or psat Standard State
|
|
T press psat Cp0 S0 -(G0-H298)/T H0-H298
|
|
(K) (bar) (bar) (J/molK) (J/molK) (J/molK) (kJ/mol)
|
|
273.19 1 0.00612989 76.0121 63.3155 70.2193 -1.8860
|
|
298.15 1 0.0316993 75.3276 69.9223 69.9223 0.0000
|
|
300 1 0.0353681 75.3153 70.3882 69.9237 0.1393
|
|
373.15 1.01621 1.01418 75.9465 86.8568 71.6853 5.6613
|
|
400 2.46261 2.45769 76.6642 92.1543 72.8764 7.7112
|
|
500 26.4447 26.392 84.0126 109.8051 78.4401 15.6825
|
|
|
|
Liquid Densities:
|
|
T press psat Density molarVol
|
|
(K) (bar) (bar) (kg/m3) (m3/kmol)
|
|
273.19 1 0.00612989 999.8451 0.0180
|
|
298.15 1 0.0316993 997.0470 0.0181
|
|
300 1 0.0353681 996.5563 0.0181
|
|
373.15 1.01621 1.01418 958.3491 0.0188
|
|
400 2.46261 2.45769 937.4863 0.0192
|
|
500 26.4447 26.392 831.3184 0.0217
|
|
|
|
Liquid 1bar or psat State: Partial Molar Quantities
|
|
T press psat Cpbar Sbar -(G0-H298)/T H0-H298 Volume
|
|
(K) (bar) (bar) (J/molK) (J/molK) (J/molK) (kJ/mol) m3/kmol
|
|
273.19 1 0.00612989 76.0121 63.3155 70.2193 -1.8860 0.0180
|
|
298.15 1 0.0316993 75.3276 69.9223 69.9223 0.0000 0.0181
|
|
300 1 0.0353681 75.3153 70.3882 69.9237 0.1393 0.0181
|
|
373.15 1.01621 1.01418 75.9465 86.8568 71.6853 5.6613 0.0188
|
|
400 2.46261 2.45769 76.6642 92.1543 72.8764 7.7112 0.0192
|
|
500 26.4447 26.392 84.0126 109.8051 78.4401 15.6825 0.0217
|
|
|
|
Liquid 1bar or psat State: Standard State Quantities
|
|
T press psat Cpbar Sbar -(G0-H298)/T H0-H298 Volume
|
|
(K) (bar) (bar) (J/molK) (J/molK) (J/molK) (kJ/mol) m3/kmol
|
|
273.19 1 0.00612989 76.0121 63.3155 70.2193 -1.8860 0.0180
|
|
298.15 1 0.0316993 75.3276 69.9223 69.9223 0.0000 0.0181
|
|
300 1 0.0353681 75.3153 70.3882 69.9237 0.1393 0.0181
|
|
373.15 1.01621 1.01418 75.9465 86.8568 71.6853 5.6613 0.0188
|
|
400 2.46261 2.45769 76.6642 92.1543 72.8764 7.7112 0.0192
|
|
500 26.4447 26.392 84.0126 109.8051 78.4401 15.6825 0.0217
|
|
|
|
Liquid 1bar or psat State: Reference State Quantities (Always 1 atm no matter what system pressure is)
|
|
T press psat Cpbar Sbar -(G0-H298)/T H0-H298 Volume
|
|
(K) (bar) (bar) (J/molK) (J/molK) (J/molK) (kJ/mol) m3/kmol
|
|
273.19 1 0.00612989 76.0119 63.3155 70.2192 -1.8860 0.0180
|
|
298.15 1 0.0316993 75.3275 69.9223 69.9222 0.0000 0.0181
|
|
300 1 0.0353681 75.3153 70.3882 69.9236 0.1394 0.0181
|
|
373.15 1.01621 1.01418 75.9465 86.8568 71.6853 5.6612 0.0188
|
|
400 2.46261 2.45769 76.6712 92.1568 72.8834 7.7094 0.0192
|
|
500 26.4447 26.392 84.4316 109.8968 78.5504 15.6732 0.0217
|
|
|
|
Liquid 1 atm: Standard State Quantities - Should agree with table above
|
|
T press psat Cpbar Sbar -(G0-H298)/T H0-H298 Volume
|
|
(K) (bar) (bar) (J/molK) (J/molK) (J/molK) (kJ/mol) m3/kmol
|
|
273.19 1.01325 0.00612989 76.0119 63.3155 70.2192 -1.8860 0.0180
|
|
298.15 1.01325 0.0316993 75.3275 69.9223 69.9222 0.0000 0.0181
|
|
300 1.01325 0.0353681 75.3153 70.3882 69.9236 0.1394 0.0181
|
|
373.15 1.01325 1.01418 75.9465 86.8568 71.6853 5.6612 0.0188
|
|
400 1.01325 2.45769 76.6712 92.1568 72.8834 7.7094 0.0192
|
|
500 1.01325 26.392 84.4316 109.8968 78.5504 15.6732 0.0217
|
|
|
|
|
|
Table of increasing Enthalpy at 1 atm
|
|
|
|
Enthalpy, Temperature, x_Vapor, Density, Entropy_mass, Gibbs_mass
|
|
-1.58673e+07, 298, 0, 997.09, 3879.2, -1.7023e+07
|
|
-1.58673e+07, 298, 0, 997.09, 3879.2, -1.7023e+07
|
|
-1.57673e+07, 321.924, 0, 988.58, 4202, -1.712e+07
|
|
-1.56673e+07, 345.815, 0, 976.22, 4501.7, -1.7224e+07
|
|
-1.55673e+07, 369.619, 0, 960.86, 4781.3, -1.7335e+07
|
|
-1.54673e+07, 393.278, 0, 942.95, 5043.5, -1.7451e+07
|
|
-1.53673e+07, 416.717, 0, 922.76, 5290.5, -1.7572e+07
|
|
-1.52673e+07, 439.845, 0, 900.41, 5524, -1.7697e+07
|
|
-1.51673e+07, 462.56, 0, 875.92, 5745.7, -1.7825e+07
|
|
-1.50673e+07, 484.738, 0, 849.21, 5956.8, -1.7955e+07
|
|
-1.49673e+07, 506.23, 0, 820.08, 6158.7, -1.8085e+07
|
|
-1.48673e+07, 526.845, 0, 788.19, 6352.3, -1.8214e+07
|
|
-1.47673e+07, 546.321, 0, 752.99, 6538.6, -1.8339e+07
|
|
-1.46673e+07, 564.269, 0, 713.51, 6718.7, -1.8458e+07
|
|
-1.45673e+07, 580.023, 0, 667.87, 6893.4, -1.8566e+07
|
|
-1.44673e+07, -> Failed to converge, beyond the spinodal probably
|
|
|
|
Critical Temp = 647 K
|
|
Critical Pressure = 218 atm
|
|
Critical Dens = 322 kg/m3
|