39 lines
3.7 KiB
Text
39 lines
3.7 KiB
Text
A_V : Comparison to Pitzer's book, p. 99, can be made.
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Agreement to 3 sig digits
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Delta_V0: Heat Capacity of Solution per mole of salt (standard states)
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rxn for the ss heat of soln: NaCl(s) -> Na+(aq) + Cl-(aq)
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Delta_Vs: Delta volume of Solution per mole of salt
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rxn for heat of soln: n1 H2O(l,pure) + n2 NaCl(s) -> n2 MX(aq) + n1 H2O(l)
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Delta_Hs = (n1 h_H2O_bar + n2 h_MX_bar - n1 h_H2O_0 - n2 h_MX_0)/n2
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phiV: phiV, calculated from the program, is checked
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against analytical formula in V_standalone program.
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(comparison against Pitzer book, p. 97, eqn. 96)
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T, Pres, Aphi, A_V, Delta_V0, Delta_Vs, Vex, phiV, MolarV, MolarV0
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Kelvin, bar, sqrt(kg/gmol),sqrt(kg/gmol)cm3/gmol,cm**3/gmolSalt,cm**3/gmolSalt,cm**3/gmolSoln,cm**3/gmolSalt,cm**3/gmol, cm**3/gmol
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273.1, 1.013, 0.3767, 1.506, -10.31, -8.581, 0.15701, 1.732, 16.42, 16.26
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298.1, 1.013, 0.3914, 1.874, -10.31, -8.157, 0.19539, 2.155, 16.5, 16.3
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323.1, 1.013, 0.4103, 2.373, -10.31, -7.583, 0.24742, 2.729, 16.69, 16.44
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348.1, 1.013, 0.4333, 3.07, -10.31, -6.783, 0.32001, 3.53, 16.96, 16.64
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373.1, 1.014, 0.4606, 4.052, -10.31, -5.654, 0.42236, 4.659, 17.32, 16.9
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398.1, 2.322, 0.4925, 5.451, -10.31, -4.044, 0.56826, 6.269, 17.79, 17.22
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423.1, 4.762, 0.5295, 7.481, -10.31, -1.71, 0.77984, 8.603, 18.38, 17.6
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448.1, 8.926, 0.5726, 10.49, -10.31, 1.749, 1.0934, 12.06, 19.14, 18.04
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473.1, 15.55, 0.6228, 15.08, -10.31, 7.025, 1.5716, 17.34, 20.14, 18.57
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498.1, 25.5, 0.682, 22.34, -10.31, 15.38, 2.3287, 25.69, 21.53, 19.2
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523.1, 39.76, 0.7534, 34.43, -10.31, 29.28, 3.5893, 39.6, 23.56, 19.97
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548.1, 59.46, 0.8422, 56.03, -10.31, 54.13, 5.8411, 64.44, 26.79, 20.94
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573.1, 85.88, 0.9593, 98.81, -10.31, 103.3, 10.301, 113.6, 32.52, 22.22
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598.1, 120.5, 1.13, 198.5, -10.31, 217.9, 20.689, 228.2, 44.74, 24.05
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623.1, 165.3, 1.439, 494.9, -10.31, 558.8, 51.593, 569.2, 78.77, 27.18
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323.1, 1.013, 0.4103, 2.373, -10.31, -7.583, 0.24742, 2.729, 16.69, 16.44
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Breakdown of Volume Calculation at 323.15 K, 1atm:
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Species MoleFrac Molal V0 partV (partV - V0)
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H2O(L) 0.8187 0 18.23 18.15 -0.08195
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Na+ 0.09065 6.146 8.34 10.07 1.735
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Cl- 0.09065 6.146 8.34 10.07 1.735
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NaCl(s) 1 26.99 26.99 0
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