ELEMENTS SI H HE END SPECIES H2 H HE SIH4 SI SIH SIH2 SIH3 H3SISIH SI2H6 H2SISIH2 SI3H8 SI2 SI3 END THERMO ALL 300.000 1000.000 5000.000 HE 120186HE 1 G 0300.00 5000.00 1000.00 1 0.02500000E+02 0.00000000E+00 0.00000000E+00 0.00000000E+00 0.00000000E+00 2 -0.07453750E+04 0.09153489E+01 0.02500000E+02 0.00000000E+00 0.00000000E+00 3 0.00000000E+00 0.00000000E+00-0.07453750E+04 0.09153488E+01 4 SIH 121986SI 1H 1 G 0300.00 2000.00 1000.00 1 0.03110430E+02 0.01094946E-01 0.02898629E-06-0.02745104E-08 0.07051799E-12 2 0.04516898E+06 0.04193487E+02 0.03836010E+02-0.02702657E-01 0.06849070E-04 3 -0.05424184E-07 0.01472131E-10 0.04507593E+06 0.09350778E+01 4 SIH2 42489SI 1H 2 G 0300.00 3000.00 1000.00 1 0.04142390E+02 0.02150191E-01-0.02190730E-05-0.02073725E-08 0.04741018E-12 2 0.03110484E+06 0.02930745E+01 0.03475092E+02 0.02139338E-01 0.07672306E-05 3 0.05217668E-08-0.09898824E-11 0.03147397E+06 0.04436585E+02 4 SIH3 42489SI 1H 3 G 0300.00 3000.00 1000.00 1 0.05015906E+02 0.03732750E-01-0.03609053E-05-0.03729193E-08 0.08468490E-12 2 0.02190233E+06-0.04291368E+02 0.02946733E+02 0.06466764E-01 0.05991653E-05 3 -0.02218413E-07 0.03052670E-11 0.02270173E+06 0.07347948E+02 4 H3SISIH 111191H 4SI 2 G 0300.00 4000.00 1500.00 1 0.01127202E+03 0.02538145E-01-0.02998472E-05-0.09465367E-09 0.01855053E-12 2 0.03297169E+06-0.03264598E+03 0.03698707E+02 0.01870180E+00-0.01430704E-03 3 0.06005836E-07-0.01116293E-10 0.03590825E+06 0.08825191E+02 4 H2SISIH2 42489SI 2H 4 G 0300.00 3000.00 1000.00 1 0.08986817E+02 0.05405047E-01-0.05214022E-05-0.05313742E-08 0.01188727E-11 2 0.02832748E+06-0.02004478E+03 0.05133186E+02 0.01252855E+00-0.04620421E-05 3 -0.06606075E-07 0.02864345E-10 0.02956915E+06 0.07605133E+01 4 SIH4 90784SI 1H 4 0 0G 300.000 2000.000 1 0.79359380E+00 0.17671899E-01-0.11398009E-04 0.35992604E-08-0.45241571E-12 2 0.31982127E+04 0.15242257E+02 0.14516404E+01 0.13987363E-01-0.42345639E-05 3 -0.23606142E-08 0.13712089E-11 0.31134105E+04 0.12321855E+02 4 SI2H6 90784SI 2H 6 0 0G 300.000 2000.000 1 0.34074936E+01 0.27206479E-01-0.17713204E-04 0.56391177E-08 -.71378682E-12 2 0.75321842E+04 0.61321754E+01 0.67347983E+00 0.40931531E-01 -.44841255E-04 3 0.29952232E-07-0.89010854E-11 0.79327875E+04 0.18627403E+02 4 SI2 90784SI 2 0 0 0G 300.000 2000.000 1 0.41446779E+01 0.65234677E-03-0.50108520E-06 0.18062843E-09 -.25161111E-13 2 0.69694707E+05 0.38627366E+01 0.29671976E+01 0.63119558E-02 -.10970790E-04 3 0.89278680E-08-0.27873689E-11 0.69870738E+05 0.92789503E+01 4 SI3H8 90784SI 3H 8 0 0G 300.000 2000.000 1 0.60933341E+01 0.36580112E-01-0.23892361E-04 0.76271932E-08 -.96769384E-12 2 0.11297205E+05-0.27475654E+01 0.77196846E+00 0.63442740E-01 -.76726109E-04 3 0.54543715E-07-0.16611729E-10 0.12071263E+05 0.21532507E+02 4 SI J 3/67SI 1 0 0 0G 300.000 5000.000 1 0.26506014E+01-0.35763852E-03 0.29592293E-06-0.72804829E-10 0.57963329E-14 2 0.53437054E+05 0.52204057E+01 0.31793537E+01-0.27646992E-02 0.44784038E-05 3 -0.32833177E-08 0.91213631E-12 0.53339032E+05 0.27273204E+01 4 SI3 J 3/67SI 3 0 0 0G 300.000 5000.000 1 0.74213360E+01-0.11709948E-03 0.89820775E-07 0.71935964E-11-0.25670837E-14 2 0.74146699E+05-0.10365274E+02 0.45979129E+01 0.10715274E-01-0.16100422E-04 3 0.10969207E-07-0.27832875E-11 0.74766324E+05 0.34421671E+01 4 H L 7/88H 1 00 00 00G 200.000 3500.000 1000.000 1 2.50000001E+00-2.30842973E-11 1.61561948E-14-4.73515235E-18 4.98197357E-22 2 2.54736599E+04-4.46682914E-01 2.50000000E+00 7.05332819E-13-1.99591964E-15 3 2.30081632E-18-9.27732332E-22 2.54736599E+04-4.46682853E-01 4 H2 TPIS78H 2 00 00 00G 200.000 3500.000 1000.000 1 3.33727920E+00-4.94024731E-05 4.99456778E-07-1.79566394E-10 2.00255376E-14 2 -9.50158922E+02-3.20502331E+00 2.34433112E+00 7.98052075E-03-1.94781510E-05 3 2.01572094E-08-7.37611761E-12-9.17935173E+02 6.83010238E-01 4 END REACTIONS SIH4 + H = SIH3 + H2 7.8e14 0.0 2260. ! Roth SIH4 + M = SIH3 + H + M 3.91e15 0.0 89356. ! 94TAK/MOM tst calc SIH3 + H = SIH2 + H2 7.8e14 0.0 2260. ! assume same as SIH4 SI + SI + M = SI2 + M 2.47e16 0.0 1178.0 ! 90MAR/RAF SIH4 + SIH2 = H3SISIH + H2 1.3E13 0.0 0.0 ! R8 SIH + H2 = SIH2 + H 4.8E14 0.0 23.64 ! R11 SIH + SIH4 = H3SISIH + H 1.6E14 0.0 0.0 ! R12 SI + H2 = SIH + H 1.5E15 0.0 31.8 ! R13 ! SIH4(+M)=SIH2+H2(+M) 0.3119E+10 1.669 54710. ! R1 LOW / 0.5214E30 -3.545 57550./ TROE / -0.4984 888.3 209.4 2760./ SIH4/4./ SI2H6/4./ ! HF(SiH2)=64.3, anh_inc.16b, beta(Ar,300) = 0.25 fit from 300 to 1200K H3SISIH(+M)=H2SISIH2(+M) 0.254E+14 -0.2239 5381.000 ! A6 LOW / 0.1099E34 -5.765 9152. / TROE / -0.4202 214.5 103. 136.3 / SIH4/4./ SI2H6/4./ ! ! RRKM fits 3/18/93 by MEC SI3H8(+M)=SIH4+H3SISIH(+M) 3.73E+12 0.992 50850.000 LOW / 4.36E76 -17.26 59303. / TROE / 0.4157 365.3 3102. 9.724 / SIH4/4./ SI2H6/4./ SI3H8(+M)=SIH2+SI2H6(+M) 6.97E+12 0.9691 52677.000 LOW / 1.73E69 -15.07 60491. / TROE / -3.47E-5 442.0 2412. 128.3 / SIH4/4./ SI2H6/4./ SI2H6(+M)=H2+H3SISIH(+M) 9.086E+9 1.834 54197.000 LOW / 1.945E44 -7.772 59023. / TROE / -0.1224 793.3 2400. 11.39 / SIH4/4./ SI2H6/4./ SI2H6(+M)=SIH4+SIH2(+M) 1.81E+10 1.747 50203.000 ! A3 LOW / 5.09E53 -10.37 56034. / TROE / 4.375E-5 438.5 2726. 438.2 / SIH4/4./ SI2H6/4./ END