/** * @file PDSS_ConstVol.cpp * Implementation of a pressure dependent standard state * virtual function. */ /* * Copyright (2006) Sandia Corporation. Under the terms of * Contract DE-AC04-94AL85000 with Sandia Corporation, the * U.S. Government retains certain rights in this software. */ #include "cantera/base/ctml.h" #include "cantera/thermo/PDSS_ConstVol.h" #include "cantera/thermo/VPStandardStateTP.h" #include using namespace std; namespace Cantera { PDSS_ConstVol::PDSS_ConstVol(VPStandardStateTP* tp, size_t spindex) : PDSS(tp, spindex) { m_pdssType = cPDSS_CONSTVOL; } PDSS_ConstVol::PDSS_ConstVol(VPStandardStateTP* tp, size_t spindex, const std::string& inputFile, const std::string& id) : PDSS(tp, spindex) { m_pdssType = cPDSS_CONSTVOL; constructPDSSFile(tp, spindex, inputFile, id); } PDSS_ConstVol::PDSS_ConstVol(VPStandardStateTP* tp, size_t spindex, const XML_Node& speciesNode, const XML_Node& phaseRoot, bool spInstalled) : PDSS(tp, spindex) { m_pdssType = cPDSS_CONSTVOL; constructPDSSXML(tp, spindex, speciesNode, phaseRoot, spInstalled) ; } PDSS_ConstVol::PDSS_ConstVol(const PDSS_ConstVol& b) : PDSS(b) { /* * Use the assignment operator to do the brunt * of the work for the copy constructor. */ *this = b; } PDSS_ConstVol& PDSS_ConstVol::operator=(const PDSS_ConstVol& b) { if (&b == this) { return *this; } PDSS::operator=(b); m_constMolarVolume = b.m_constMolarVolume; return *this; } PDSS* PDSS_ConstVol::duplMyselfAsPDSS() const { return new PDSS_ConstVol(*this); } void PDSS_ConstVol::constructPDSSXML(VPStandardStateTP* tp, size_t spindex, const XML_Node& speciesNode, const XML_Node& phaseNode, bool spInstalled) { PDSS::initThermo(); SpeciesThermo& sp = m_tp->speciesThermo(); m_p0 = sp.refPressure(m_spindex); if (!spInstalled) { throw CanteraError("PDSS_ConstVol::constructPDSSXML", "spInstalled false not handled"); } const XML_Node* ss = speciesNode.findByName("standardState"); if (!ss) { throw CanteraError("PDSS_ConstVol::constructPDSSXML", "no standardState Node for species " + speciesNode.name()); } std::string model = (*ss)["model"]; if (model != "constant_incompressible") { throw CanteraError("PDSS_ConstVol::initThermoXML", "standardState model for species isn't constant_incompressible: " + speciesNode.name()); } m_constMolarVolume = ctml::getFloat(*ss, "molarVolume", "toSI"); std::string id = ""; } void PDSS_ConstVol::constructPDSSFile(VPStandardStateTP* tp, size_t spindex, const std::string& inputFile, const std::string& id) { if (inputFile.size() == 0) { throw CanteraError("PDSS_ConstVol::initThermo", "input file is null"); } std::string path = findInputFile(inputFile); ifstream fin(path.c_str()); if (!fin) { throw CanteraError("PDSS_ConstVol::initThermo","could not open " +path+" for reading."); } /* * The phase object automatically constructs an XML object. * Use this object to store information. */ XML_Node* fxml = new XML_Node(); fxml->build(fin); XML_Node* fxml_phase = findXMLPhase(fxml, id); if (!fxml_phase) { throw CanteraError("PDSS_ConstVol::initThermo", "ERROR: Can not find phase named " + id + " in file named " + inputFile); } XML_Node& speciesList = fxml_phase->child("speciesArray"); XML_Node* speciesDB = get_XML_NameID("speciesData", speciesList["datasrc"], &(fxml_phase->root())); const vector&sss = tp->speciesNames(); const XML_Node* s = speciesDB->findByAttr("name", sss[spindex]); constructPDSSXML(tp, spindex, *s, *fxml_phase, true); delete fxml; } void PDSS_ConstVol::initThermoXML(const XML_Node& phaseNode, const std::string& id) { PDSS::initThermoXML(phaseNode, id); m_minTemp = m_spthermo->minTemp(m_spindex); m_maxTemp = m_spthermo->maxTemp(m_spindex); m_p0 = m_spthermo->refPressure(m_spindex); m_mw = m_tp->molecularWeight(m_spindex); } void PDSS_ConstVol::initThermo() { PDSS::initThermo(); SpeciesThermo& sp = m_tp->speciesThermo(); m_p0 = sp.refPressure(m_spindex); m_V0_ptr[m_spindex] = m_constMolarVolume; m_Vss_ptr[m_spindex] = m_constMolarVolume; } doublereal PDSS_ConstVol::enthalpy_RT() const { return m_hss_RT_ptr[m_spindex]; } doublereal PDSS_ConstVol::intEnergy_mole() const { doublereal pVRT = (m_pres * m_Vss_ptr[m_spindex]) / (GasConstant * m_temp); doublereal val = m_h0_RT_ptr[m_spindex] - pVRT; doublereal RT = GasConstant * m_temp; return val * RT; } doublereal PDSS_ConstVol::entropy_R() const { return m_sss_R_ptr[m_spindex]; } doublereal PDSS_ConstVol::gibbs_RT() const { return m_gss_RT_ptr[m_spindex]; } doublereal PDSS_ConstVol::cp_R() const { return m_cpss_R_ptr[m_spindex]; } doublereal PDSS_ConstVol::cv_mole() const { return (cp_mole() - m_V0_ptr[m_spindex]); } doublereal PDSS_ConstVol::molarVolume() const { return m_Vss_ptr[m_spindex]; } doublereal PDSS_ConstVol::density() const { doublereal val = m_Vss_ptr[m_spindex]; return m_mw/val; } doublereal PDSS_ConstVol::gibbs_RT_ref() const { return m_g0_RT_ptr[m_spindex]; } doublereal PDSS_ConstVol::enthalpy_RT_ref() const { return m_h0_RT_ptr[m_spindex]; } doublereal PDSS_ConstVol::entropy_R_ref() const { return m_s0_R_ptr[m_spindex]; } doublereal PDSS_ConstVol::cp_R_ref() const { doublereal val = m_cp0_R_ptr[m_spindex]; return (val); } doublereal PDSS_ConstVol::molarVolume_ref() const { return m_V0_ptr[m_spindex]; } void PDSS_ConstVol::setPressure(doublereal p) { m_pres = p; doublereal del_pRT = (m_pres - m_p0) / (GasConstant * m_temp); m_hss_RT_ptr[m_spindex] = m_h0_RT_ptr[m_spindex] + del_pRT * m_Vss_ptr[m_spindex]; m_gss_RT_ptr[m_spindex] = m_hss_RT_ptr[m_spindex] - m_sss_R_ptr[m_spindex]; } void PDSS_ConstVol::setTemperature(doublereal temp) { m_temp = temp; m_spthermo->update_one(m_spindex, temp, m_cp0_R_ptr, m_h0_RT_ptr, m_s0_R_ptr); m_g0_RT_ptr[m_spindex] = m_h0_RT_ptr[m_spindex] - m_s0_R_ptr[m_spindex]; doublereal del_pRT = (m_pres - m_p0) / (GasConstant * m_temp); m_hss_RT_ptr[m_spindex] = m_h0_RT_ptr[m_spindex] + del_pRT * m_Vss_ptr[m_spindex]; m_cpss_R_ptr[m_spindex] = m_cp0_R_ptr[m_spindex]; m_sss_R_ptr[m_spindex] = m_s0_R_ptr[m_spindex]; m_gss_RT_ptr[m_spindex] = m_hss_RT_ptr[m_spindex] - m_sss_R_ptr[m_spindex]; } void PDSS_ConstVol::setState_TP(doublereal temp, doublereal pres) { setTemperature(temp); setPressure(pres); } void PDSS_ConstVol::setState_TR(doublereal temp, doublereal rho) { doublereal rhoStored = m_mw / m_constMolarVolume; if (fabs(rhoStored - rho) / (rhoStored + rho) > 1.0E-4) { throw CanteraError("PDSS_ConstVol::setState_TR", "Inconsistent supplied rho"); } setTemperature(temp); } doublereal PDSS_ConstVol::satPressure(doublereal t) { return 1.0E-200; } }