#include "Wall.h" #include "ReactorBase.h" #include "Func1.h" #include "../InterfaceKinetics.h" #include "../SurfPhase.h" namespace Cantera { Wall::Wall() : m_left(0), m_right(0), m_area(0.0), m_k(0.0), m_rrth(0.0), m_emiss(0.0), m_vf(0), m_qf(0) { for (int n = 0; n < 2; n++) { m_chem[n] = 0; m_surf[n] = 0; m_nsp[n] = 0; } } bool Wall::install(ReactorBase& rleft, ReactorBase& rright) { // check if wall is already installed if (m_left || m_right) return false; m_left = &rleft; m_right = &rright; m_left->addWall(*this, 0); m_right->addWall(*this, 1); return true; } /** Specify the kinetics managers for the surface mechanisms on * the left side and right side of the wall. Enter 0 if there is * no reaction mechanism. */ void Wall::setKinetics(Kinetics* left, Kinetics* right) { m_chem[0] = left; m_chem[1] = right; int ileft = 0, iright = 0; if (left) { ileft = left->surfacePhaseIndex(); if (ileft >= 0) { m_surf[0] = (SurfPhase*)&left->thermo(ileft); m_nsp[0] = m_surf[0]->nSpecies(); m_leftcov.resize(m_nsp[0]); m_surf[0]->getCoverages(m_leftcov.begin()); } } if (right) { iright = right->surfacePhaseIndex(); if (iright >= 0) { m_surf[1] = (SurfPhase*)&right->thermo(iright); m_nsp[1] = m_surf[1]->nSpecies(); m_rightcov.resize(m_nsp[1]); m_surf[1]->getCoverages(m_rightcov.begin()); } } if (ileft < 0 || iright < 0) { throw CanteraError("Wall::setKinetics", "specified surface kinetics manager does not " "represent a surface reaction mechanism."); } } /** * The volume rate of change is given by * \f[ \dot V = K A (P_{left} - P_{right}) + F(t) \f] * where \f$ F(t) \f$ is a specified function of time. * * This method is used by class Reactor to compute the * rate of volume change of the reactor. */ doublereal Wall::vdot(doublereal t) { double rate1 = m_k * m_area * (m_left->pressure() - m_right->pressure()); if (m_vf) rate1 += m_area * m_vf->eval(t); return rate1; } /** * The heat flux is given by * \f[ Q = h A (T_{left} - T_{right}) + A G(t) \f] * where h is the heat transfer coefficient, and * \f$ G(t) \f$ is a specified function of time. */ doublereal Wall::Q(doublereal t) { double q1 = (m_area * m_rrth) * (m_left->temperature() - m_right->temperature()); if (m_emiss > 0.0) { double tl = m_left->temperature(); double tr = m_right->temperature(); q1 += m_area * StefanBoltz * (tl*tl*tl*tl - tr*tr*tr*tr); } if (m_qf) q1 += m_area * m_qf->eval(t); return q1; } void Wall::setCoverages(int leftright, const doublereal* cov) { if (leftright == 0) copy(cov, cov + m_nsp[0], m_leftcov.begin()); else copy(cov, cov + m_nsp[1], m_rightcov.begin()); } void Wall::getCoverages(int leftright, doublereal* cov) { if (leftright == 0) copy(m_leftcov.begin(), m_leftcov.end(), cov); else copy(m_rightcov.begin(), m_rightcov.end(), cov); } void Wall::syncCoverages(int leftright) { if (leftright == 0) m_surf[0]->setCoverages(m_leftcov.begin()); else m_surf[1]->setCoverages(m_rightcov.begin()); } }