diff --git a/doc/sphinx/reactors.rst b/doc/sphinx/reactors.rst index efe8ba2d2..9b6b41208 100644 --- a/doc/sphinx/reactors.rst +++ b/doc/sphinx/reactors.rst @@ -241,10 +241,11 @@ time-dependent heat flux (W/m^2). This definition is such that positive `q_0(t)` implies heat transfer from the "left" reactor to the "right" reactor. Each of the user-specified terms defaults to 0. -In case of surface reactions, there is a net generation (or -destruction) of homogeneous phase species at the wall. The molar rate of -production for each species `k` on wall `w` is `\dot{s}_{k,w}` (in kmol/s/m\ -:sup:`2`). The total (mass) production rate for species `k` on all walls is: +In case of surface reactions, there can be a net generation (or destruction) of +homogeneous (gas) phase species at the wall. The molar rate of production for +each homogeneous phase species `k` on wall `w` is `\dot{s}_{k,w}` (in +kmol/s/m^2). The total (mass) production rate for homogeneous phase species `k` +on all walls is: .. math:: @@ -258,6 +259,17 @@ each wall. The net mass flux from all walls is then: \dot{m}_{wall} = \sum_k \dot{m}_{k,wall} +For each surface species `i`, the rate of change of the site fraction +`\theta_{i,w}` on each wall `w` is integrated with time: + +.. math:: + + \frac{d\theta_{i,w}}{dt} = \frac{\dot{s}_{i,w} n_i}{\Gamma_w} + +where `\Gamma_w` is the total surface site density on wall `w` and `n_i` is the +number of surface sites occupied by a molecule of species `i` (sometimes +referred to within Cantera as the molecule's "size"). + Reactor Networks and Devices ============================