<?xml version="1.0"?>
<ctml>
  <validate reactions="yes" species="yes"/>

  <!-- phase air     -->
  <phase dim="3" id="air">
    <elementArray datasrc="elements.xml">O  H N  Ar </elementArray>
    <speciesArray datasrc="#species_data">O  O2  N  NO  NO2  N2O  N2  NH  H H2O NH2 AR </speciesArray>
    <reactionArray datasrc="#reaction_data"/>
    <state>
      <temperature units="K">900.0</temperature>
      <pressure units="Pa">101325.0</pressure>
      <moleFractions>O2:0.21, N2:0.78, AR:0.01</moleFractions>
    </state>
    <thermo model="IdealGas"/>
    <kinetics model="GasKinetics"/>
    <transport model="Mix"/>
  </phase>

  <!-- species definitions     -->
  <speciesData id="species_data">

    <!-- species O    -->
    <species name="O">
      <atomArray>O:1 </atomArray>
      <note>L 1/90</note>
      <thermo>
        <NASA Tmax="1000.0" Tmin="200.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             3.168267100E+00,  -3.279318840E-03,   6.643063960E-06,  -6.128066240E-09, 
             2.112659710E-12,   2.912225920E+04,   2.051933460E+00</floatArray>
        </NASA>
        <NASA Tmax="3500.0" Tmin="1000.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             2.569420780E+00,  -8.597411370E-05,   4.194845890E-08,  -1.001777990E-11, 
             1.228336910E-15,   2.921757910E+04,   4.784338640E+00</floatArray>
        </NASA>
      </thermo>
      <transport model="gas_transport">
        <string title="geometry">atom</string>
        <LJ_welldepth units="K">80.000</LJ_welldepth>
        <LJ_diameter units="A">2.750</LJ_diameter>
        <dipoleMoment units="Debye">0.000</dipoleMoment>
        <polarizability units="A3">0.000</polarizability>
        <rotRelax>0.000</rotRelax>
      </transport>
    </species>

    <!-- species O2    -->
    <species name="O2">
      <atomArray>O:2 </atomArray>
      <note>TPIS89</note>
      <thermo>
        <NASA Tmax="1000.0" Tmin="200.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             3.782456360E+00,  -2.996734160E-03,   9.847302010E-06,  -9.681295090E-09, 
             3.243728370E-12,  -1.063943560E+03,   3.657675730E+00</floatArray>
        </NASA>
        <NASA Tmax="3500.0" Tmin="1000.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             3.282537840E+00,   1.483087540E-03,  -7.579666690E-07,   2.094705550E-10, 
             -2.167177940E-14,  -1.088457720E+03,   5.453231290E+00</floatArray>
        </NASA>
      </thermo>
      <transport model="gas_transport">
        <string title="geometry">linear</string>
        <LJ_welldepth units="K">107.400</LJ_welldepth>
        <LJ_diameter units="A">3.460</LJ_diameter>
        <dipoleMoment units="Debye">0.000</dipoleMoment>
        <polarizability units="A3">1.600</polarizability>
        <rotRelax>3.800</rotRelax>
      </transport>
    </species>

    <!-- species N    -->
    <species name="N">
      <atomArray>N:1 </atomArray>
      <note>L 6/88</note>
      <thermo>
        <NASA Tmax="1000.0" Tmin="200.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             2.500000000E+00,   0.000000000E+00,   0.000000000E+00,   0.000000000E+00, 
             0.000000000E+00,   5.610463700E+04,   4.193908700E+00</floatArray>
        </NASA>
        <NASA Tmax="6000.0" Tmin="1000.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             2.415942900E+00,   1.748906500E-04,  -1.190236900E-07,   3.022624500E-11, 
             -2.036098200E-15,   5.613377300E+04,   4.649609600E+00</floatArray>
        </NASA>
      </thermo>
      <transport model="gas_transport">
        <string title="geometry">atom</string>
        <LJ_welldepth units="K">71.400</LJ_welldepth>
        <LJ_diameter units="A">3.300</LJ_diameter>
        <dipoleMoment units="Debye">0.000</dipoleMoment>
        <polarizability units="A3">0.000</polarizability>
        <rotRelax>0.000</rotRelax>
      </transport>
    </species>

    <!-- species NO    -->
    <species name="NO">
      <atomArray>O:1 N:1 </atomArray>
      <note>RUS 78</note>
      <thermo>
        <NASA Tmax="1000.0" Tmin="200.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             4.218476300E+00,  -4.638976000E-03,   1.104102200E-05,  -9.336135400E-09, 
             2.803577000E-12,   9.844623000E+03,   2.280846400E+00</floatArray>
        </NASA>
        <NASA Tmax="6000.0" Tmin="1000.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             3.260605600E+00,   1.191104300E-03,  -4.291704800E-07,   6.945766900E-11, 
             -4.033609900E-15,   9.920974600E+03,   6.369302700E+00</floatArray>
        </NASA>
      </thermo>
      <transport model="gas_transport">
        <string title="geometry">linear</string>
        <LJ_welldepth units="K">97.530</LJ_welldepth>
        <LJ_diameter units="A">3.620</LJ_diameter>
        <dipoleMoment units="Debye">0.000</dipoleMoment>
        <polarizability units="A3">1.760</polarizability>
        <rotRelax>4.000</rotRelax>
      </transport>
    </species>

    <!-- species NO2    -->
    <species name="NO2">
      <atomArray>O:2 N:1 </atomArray>
      <note>L 7/88</note>
      <thermo>
        <NASA Tmax="1000.0" Tmin="200.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             3.944031200E+00,  -1.585429000E-03,   1.665781200E-05,  -2.047542600E-08, 
             7.835056400E-12,   2.896617900E+03,   6.311991700E+00</floatArray>
        </NASA>
        <NASA Tmax="6000.0" Tmin="1000.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             4.884754200E+00,   2.172395600E-03,  -8.280690600E-07,   1.574751000E-10, 
             -1.051089500E-14,   2.316498300E+03,  -1.174169500E-01</floatArray>
        </NASA>
      </thermo>
      <transport model="gas_transport">
        <string title="geometry">nonlinear</string>
        <LJ_welldepth units="K">200.000</LJ_welldepth>
        <LJ_diameter units="A">3.500</LJ_diameter>
        <dipoleMoment units="Debye">0.000</dipoleMoment>
        <polarizability units="A3">0.000</polarizability>
        <rotRelax>1.000</rotRelax>
      </transport>
    </species>

    <!-- species N2O    -->
    <species name="N2O">
      <atomArray>O:1 N:2 </atomArray>
      <note>L 7/88</note>
      <thermo>
        <NASA Tmax="1000.0" Tmin="200.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             2.257150200E+00,   1.130472800E-02,  -1.367131900E-05,   9.681980600E-09, 
             -2.930718200E-12,   8.741774400E+03,   1.075799200E+01</floatArray>
        </NASA>
        <NASA Tmax="6000.0" Tmin="1000.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             4.823072900E+00,   2.627025100E-03,  -9.585087400E-07,   1.600071200E-10, 
             -9.775230300E-15,   8.073404800E+03,  -2.201720700E+00</floatArray>
        </NASA>
      </thermo>
      <transport model="gas_transport">
        <string title="geometry">linear</string>
        <LJ_welldepth units="K">232.400</LJ_welldepth>
        <LJ_diameter units="A">3.830</LJ_diameter>
        <dipoleMoment units="Debye">0.000</dipoleMoment>
        <polarizability units="A3">0.000</polarizability>
        <rotRelax>1.000</rotRelax>
      </transport>
    </species>

    <!-- species N2    -->
    <species name="N2">
      <atomArray>N:2 </atomArray>
      <note>121286</note>
      <thermo>
        <NASA Tmax="1000.0" Tmin="300.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             3.298677000E+00,   1.408240400E-03,  -3.963222000E-06,   5.641515000E-09, 
             -2.444854000E-12,  -1.020899900E+03,   3.950372000E+00</floatArray>
        </NASA>
        <NASA Tmax="5000.0" Tmin="1000.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             2.926640000E+00,   1.487976800E-03,  -5.684760000E-07,   1.009703800E-10, 
             -6.753351000E-15,  -9.227977000E+02,   5.980528000E+00</floatArray>
        </NASA>
      </thermo>
      <transport model="gas_transport">
        <string title="geometry">linear</string>
        <LJ_welldepth units="K">97.530</LJ_welldepth>
        <LJ_diameter units="A">3.620</LJ_diameter>
        <dipoleMoment units="Debye">0.000</dipoleMoment>
        <polarizability units="A3">1.760</polarizability>
        <rotRelax>4.000</rotRelax>
      </transport>
    </species>

    <!-- species NH    -->
    <species name="NH">
      <atomArray>H:1 N:1 </atomArray>
      <note>And94: Obtained from grimech</note>
      <thermo>
        <NASA Tmax="1000.0" Tmin="200.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             3.492908500E+00,   3.117919800E-04,  -1.489048400E-06,   2.481644200E-09, 
             -1.035696700E-12,   4.188062900E+04,   1.848327800E+00</floatArray>
        </NASA>
        <NASA Tmax="6000.0" Tmin="1000.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             2.783692800E+00,   1.329843000E-03,  -4.247804700E-07,   7.834850100E-11, 
             -5.504447000E-15,   4.212084800E+04,   5.740779900E+00</floatArray>
        </NASA>
      </thermo>
      <transport model="gas_transport">
        <string title="geometry">linear</string>
        <LJ_welldepth units="K">80.000</LJ_welldepth>
        <LJ_diameter units="A">2.650</LJ_diameter>
        <dipoleMoment units="Debye">0.000</dipoleMoment>
        <polarizability units="A3">0.000</polarizability>
        <rotRelax>4.000</rotRelax>
      </transport>
    </species>

    <!-- species H    -->
    <species name="H">
      <atomArray>H:1 </atomArray>
      <note>L 7/88</note>
      <thermo>
        <NASA Tmax="1000.0" Tmin="200.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             2.500000000E+00,   7.053328190E-13,  -1.995919640E-15,   2.300816320E-18, 
             -9.277323320E-22,   2.547365990E+04,  -4.466828530E-01</floatArray>
        </NASA>
        <NASA Tmax="3500.0" Tmin="1000.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             2.500000010E+00,  -2.308429730E-11,   1.615619480E-14,  -4.735152350E-18, 
             4.981973570E-22,   2.547365990E+04,  -4.466829140E-01</floatArray>
        </NASA>
      </thermo>
      <transport model="gas_transport">
        <string title="geometry">atom</string>
        <LJ_welldepth units="K">145.000</LJ_welldepth>
        <LJ_diameter units="A">2.050</LJ_diameter>
        <dipoleMoment units="Debye">0.000</dipoleMoment>
        <polarizability units="A3">0.000</polarizability>
        <rotRelax>0.000</rotRelax>
      </transport>
    </species>

    <!-- species H2O    -->
    <species name="H2O">
      <atomArray>H:2 O:1 </atomArray>
      <note>L 8/89</note>
      <thermo>
        <NASA Tmax="1000.0" Tmin="200.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             4.198640560E+00,  -2.036434100E-03,   6.520402110E-06,  -5.487970620E-09, 
             1.771978170E-12,  -3.029372670E+04,  -8.490322080E-01</floatArray>
        </NASA>
        <NASA Tmax="3500.0" Tmin="1000.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             3.033992490E+00,   2.176918040E-03,  -1.640725180E-07,  -9.704198700E-11, 
             1.682009920E-14,  -3.000429710E+04,   4.966770100E+00</floatArray>
        </NASA>
      </thermo>
      <transport model="gas_transport">
        <string title="geometry">nonlinear</string>
        <LJ_welldepth units="K">572.400</LJ_welldepth>
        <LJ_diameter units="A">2.600</LJ_diameter>
        <dipoleMoment units="Debye">1.840</dipoleMoment>
        <polarizability units="A3">0.000</polarizability>
        <rotRelax>4.000</rotRelax>
      </transport>
    </species>

    <!-- species NH2    -->
    <species name="NH2">
      <atomArray>H:2 N:1 </atomArray>
      <note>And89</note>
      <thermo>
        <NASA Tmax="1000.0" Tmin="200.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             4.204002900E+00,  -2.106138500E-03,   7.106834800E-06,  -5.611519700E-09, 
             1.644071700E-12,   2.188591000E+04,  -1.418424800E-01</floatArray>
        </NASA>
        <NASA Tmax="6000.0" Tmin="1000.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             2.834742100E+00,   3.207308200E-03,  -9.339080400E-07,   1.370295300E-10, 
             -7.920614400E-15,   2.217195700E+04,   6.520416300E+00</floatArray>
        </NASA>
      </thermo>
      <transport model="gas_transport">
        <string title="geometry">nonlinear</string>
        <LJ_welldepth units="K">80.000</LJ_welldepth>
        <LJ_diameter units="A">2.650</LJ_diameter>
        <dipoleMoment units="Debye">0.000</dipoleMoment>
        <polarizability units="A3">2.260</polarizability>
        <rotRelax>4.000</rotRelax>
      </transport>
    </species>

    <!-- species AR    -->
    <species name="AR">
      <atomArray>Ar:1 </atomArray>
      <note>120186</note>
      <thermo>
        <NASA Tmax="1000.0" Tmin="300.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             2.500000000E+00,   0.000000000E+00,   0.000000000E+00,   0.000000000E+00, 
             0.000000000E+00,  -7.453750000E+02,   4.366000000E+00</floatArray>
        </NASA>
        <NASA Tmax="5000.0" Tmin="1000.0" P0="100000.0">
           <floatArray name="coeffs" size="7">
             2.500000000E+00,   0.000000000E+00,   0.000000000E+00,   0.000000000E+00, 
             0.000000000E+00,  -7.453750000E+02,   4.366000000E+00</floatArray>
        </NASA>
      </thermo>
      <transport model="gas_transport">
        <string title="geometry">atom</string>
        <LJ_welldepth units="K">136.500</LJ_welldepth>
        <LJ_diameter units="A">3.330</LJ_diameter>
        <dipoleMoment units="Debye">0.000</dipoleMoment>
        <polarizability units="A3">0.000</polarizability>
        <rotRelax>0.000</rotRelax>
      </transport>
    </species>
  </speciesData>
  <reactionData id="reaction_data">

    <!-- reaction 0001    -->
    <reaction duplicate="yes" reversible="yes" id="0001">
      <equation>NH + NO [=] N2O + H</equation>
      <rateCoeff>
        <Arrhenius>
           <A>2.940000E+11</A>
           <b>-0.40000000000000002</b>
           <E units="cal/mol">0.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>NH:1.0 NO:1</reactants>
      <products>H:1 N2O:1.0</products>
    </reaction>

    <!-- reaction 0002    -->
    <reaction duplicate="yes" reversible="yes" negative_A="yes" id="0002">
      <equation>NH + NO [=] N2O + H</equation>
      <rateCoeff>
        <Arrhenius>
           <A>-2.160000E+10</A>
           <b>-0.23000000000000001</b>
           <E units="cal/mol">0.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>NH:1.0 NO:1</reactants>
      <products>H:1 N2O:1.0</products>
    </reaction>

    <!-- reaction 0003    -->
    <reaction duplicate="yes" reversible="yes" id="0003">
      <equation>NH2 + NO [=] N2 + H2O</equation>
      <rateCoeff>
        <Arrhenius>
           <A>1.300000E+13</A>
           <b>-1.25</b>
           <E units="cal/mol">0.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>NO:1 NH2:1.0</reactants>
      <products>N2:1.0 H2O:1</products>
    </reaction>

    <!-- reaction 0004    -->
    <reaction duplicate="yes" reversible="yes" negative_A="yes" id="0004">
      <equation>NH2 + NO [=] N2 + H2O</equation>
      <rateCoeff>
        <Arrhenius>
           <A>-2.800000E+10</A>
           <b>-0.55000000000000004</b>
           <E units="cal/mol">0.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>NO:1 NH2:1.0</reactants>
      <products>N2:1.0 H2O:1</products>
    </reaction>

    <!-- reaction 0005    -->
    <reaction reversible="yes" type="threeBody" id="0005">
      <equation>2 O + M [=] O2 + M</equation>
      <rateCoeff>
        <Arrhenius>
           <A>1.200000E+11</A>
           <b>-1</b>
           <E units="cal/mol">0.000000</E>
        </Arrhenius>
        <efficiencies default="1.0">AR:0.83 </efficiencies>
      </rateCoeff>
      <reactants>O:2.0</reactants>
      <products>O2:1.0</products>
    </reaction>

    <!-- reaction 0006    -->
    <reaction reversible="yes" id="0006">
      <equation>N + NO [=] N2 + O</equation>
      <rateCoeff>
        <Arrhenius>
           <A>2.700000E+10</A>
           <b>0</b>
           <E units="cal/mol">355.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>NO:1 N:1.0</reactants>
      <products>N2:1.0 O:1</products>
    </reaction>

    <!-- reaction 0007    -->
    <reaction reversible="yes" id="0007">
      <equation>N + O2 [=] NO + O</equation>
      <rateCoeff>
        <Arrhenius>
           <A>9.000000E+06</A>
           <b>1</b>
           <E units="cal/mol">6500.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>O2:1 N:1.0</reactants>
      <products>O:1 NO:1.0</products>
    </reaction>

    <!-- reaction 0008    -->
    <reaction reversible="yes" id="0008">
      <equation>N2O + O [=] N2 + O2</equation>
      <rateCoeff>
        <Arrhenius>
           <A>1.400000E+09</A>
           <b>0</b>
           <E units="cal/mol">10810.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>N2O:1.0 O:1</reactants>
      <products>N2:1.0 O2:1</products>
    </reaction>

    <!-- reaction 0009    -->
    <reaction reversible="yes" id="0009">
      <equation>N2O + O [=] 2 NO</equation>
      <rateCoeff>
        <Arrhenius>
           <A>2.900000E+10</A>
           <b>0</b>
           <E units="cal/mol">23150.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>N2O:1.0 O:1</reactants>
      <products>NO:2.0</products>
    </reaction>

    <!-- reaction 0010    -->
    <reaction reversible="yes" type="falloff" id="0010">
      <equation>N2O (+ M) [=] N2 + O (+ M)</equation>
      <rateCoeff>
        <Arrhenius>
           <A>7.910000E+10</A>
           <b>0</b>
           <E units="cal/mol">56020.000000</E>
        </Arrhenius>
        <Arrhenius name="k0">
           <A>6.370000E+11</A>
           <b>0</b>
           <E units="cal/mol">56640.000000</E>
        </Arrhenius>
        <efficiencies default="1.0">AR:0.625 </efficiencies>
        <falloff type="Lindemann"/>
      </rateCoeff>
      <reactants>N2O:1.0</reactants>
      <products>N2:1.0 O:1</products>
    </reaction>

    <!-- reaction 0011    -->
    <reaction reversible="yes" type="threeBody" id="0011">
      <equation>NO + O + M [=] NO2 + M</equation>
      <rateCoeff>
        <Arrhenius>
           <A>1.060000E+14</A>
           <b>-1.4099999999999999</b>
           <E units="cal/mol">0.000000</E>
        </Arrhenius>
        <efficiencies default="1.0">AR:0.7 </efficiencies>
      </rateCoeff>
      <reactants>O:1 NO:1.0</reactants>
      <products>NO2:1.0</products>
    </reaction>

    <!-- reaction 0012    -->
    <reaction reversible="yes" id="0012">
      <equation>NO2 + O [=] NO + O2</equation>
      <rateCoeff>
        <Arrhenius>
           <A>3.900000E+09</A>
           <b>0</b>
           <E units="cal/mol">-240.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>O:1 NO2:1.0</reactants>
      <products>O2:1 NO:1.0</products>
    </reaction>
  </reactionData>
</ctml>
